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Oxidative Dehydrogenation on Nanocarbon: Insights into the Reaction Mechanism and Kinetics via in Situ Experimental Methods

Wei Qi、Pengqiang Yan、Dang Sheng Su2018-02-15Accounts of Chemical Research

Sustainable and environmentally benign catalytic processes are vital for the future to supply the world population with clean energy and industrial products. The replacement of conventional metal or metal oxide catalysts with earth abundant and renewable nonmetallic materials has attracted considerable research intere…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Fully resolved numerical simulations of fused deposition modeling. Part I: fluid flow

Huanxiong Xia、Jiacai Lu、Sadegh Dabiri 等 4 位作者2018-02-15Rapid Prototyping Journal

Purpose This paper aims to present a first step toward developing a comprehensive methodology for fully resolved numerical simulations of fusion deposition modeling (FDM). Design/methodology/approach A front-tracking/finite volume method previously developed for simulations of multiphase flows is extended to model the…

Surface Modification and SuperhydrophobicityAdditive Manufacturing and 3D Printing TechnologiesManufacturing Process and Optimization

Efficient Unassisted Overall Photocatalytic Seawater Splitting on GaN-Based Nanowire Arrays

Xiangjiu Guan、Faqrul A. Chowdhury、Nick Pant 等 6 位作者2018-02-15The Journal of Physical Chemistry C

Large-scale, clean, efficient, and sustainable hydrogen production from water is one of the major goals in solar-to-fuel conversion as the sun and water represent the two most abundant and geographically balanced free resources available on earth. Considering that most of the liquid water available on the earth’s surf…

Advanced Photocatalysis TechniquesAdvanced biosensing and bioanalysis techniquesGa2O3 and related materials

Dysprosium-doped ZBLAN fiber laser tunable from 28 μm to 34 μm, pumped at 17 μm

Matthew R. Majewski、Robert I. Woodward、Stuart D. Jackson2018-02-15Optics Letters

We demonstrate a mid-infrared dysprosium-doped fluoride fiber laser with a continuously tunable output range of 573 nm, pumped by a 1.7 μm Raman fiber laser. To the best of our knowledge, this represents the largest tuning range achieved to date from any rare-earth-doped fiber laser and, critically, spans the 2.8-3.4…

Glass properties and applicationsPhotonic Crystal and Fiber OpticsSolid State Laser Technologies

Probing α−RuCl3 Beyond Magnetic Order: Effects of Temperature and Magnetic Field

Stephen M. Winter、Kira Riedl、David A. S. Kaib 等 5 位作者2018-02-15Physical Review Letters

Recent studies have brought α-RuCl_{3} to the forefront of experimental searches for materials realizing Kitaev spin-liquid physics. This material exhibits strongly anisotropic exchange interactions afforded by the spin-orbit coupling of the 4d Ru centers. We investigate the dynamical response at finite temperature an…

Perovskite Materials and ApplicationsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Role of growth factors and biomaterials in wound healing

Farshad Zarei、Maryam Soleimaninejad2018-02-15Artificial Cells Nanomedicine and Biotechnology

Wound healing is a biological complex process that involves several cell types under the control and regulation of several growth factors and cytokines. There have been efforts to study the therapeutic effects of granulocyte-macrophage colony-stimulating factor, platelet-derived growth factor, transforming growth fact…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

A Scalable Laplace Approximation for Neural Networks

Hippolyt Ritter、Aleksandar Botev、David Barber2018-02-15UCL Discovery (University College London)

We leverage recent insights from second-order optimisation for neural networks to construct a Kronecker factored Laplace approximation to the posterior over the weights of a trained network. Our approximation requires no modification of the training procedure, enabling practitioners to estimate the uncertainty of thei…

Model Reduction and Neural NetworksAdversarial Robustness in Machine LearningMachine Learning in Materials Science

Microemulsion Assisted Assembly of 3D Porous S/Graphene@g‐C 3 N 4 Hybrid Sponge as Free‐Standing Cathodes for High Energy Density Li–S Batteries

Juan Zhang、Jinyi Li、Wenpeng Wang 等 7 位作者2018-02-15Advanced Energy Materials

Abstract A 3D porous sulfur/graphene@g‐C 3 N 4 (S/GCN) hybrid sponge, which can be directly applied as a free‐standing cathode for Li–S batteries, is realized via a microemulsion assisted assembly approach. In this strategy, the interior oil emulsion droplets serve as soft templates to form pores to accommodate sulfur…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesMXene and MAX Phase Materials

Application of graphene-based flexible antennas in consumer electronic devices

Alessandra Scidà、Samiul Haque、Emanuele Treossi 等 8 位作者2018-02-15Materials Today

We describe the fabrication and characterization of Near-Field Communication (NFC) devices based on highly flexible, carbon-based antennas composed of stacked graphene multilayers. This material features a high value of conductivity (4.20 * 10 5 S/m) comparable to monocrystalline graphite, but is much more flexible an…

Antenna Design and AnalysisGraphene research and applicationsEnergy Harvesting in Wireless Networks

A Method of Suppressing Higher Order Modes for Improving Radiation Performance of Metasurface Multiport Antennas Using Characteristic Mode Analysis

Feng Han Lin、Zhi Ning Chen2018-02-15IEEE Transactions on Antennas and Propagation

A method is proposed to suppress the unwanted higher order modes (HOMs) of the metasurfaces in multiport antenna systems for improving the radiation performances using characteristic mode analysis (CMA). The proposed method is to control the modal currents under consideration by loading the unit cells of the metasurfa…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks

Miguel I. Gonzalez、Matthew T. Kapelewski、Eric D. Bloch 等 10 位作者2018-02-15Journal of the American Chemical Society

Purification of the C 8 alkylaromatics o -xylene, m -xylene, p -xylene, and ethylbenzene remains among the most challenging industrial separations, due to the similar shapes, boiling points, and polarities of these molecules. Herein, we report the evaluation of the metal–organic frameworks Co 2 (dobdc) (dobdc 4– = 2,5…

Metal-Organic Frameworks: Synthesis and ApplicationsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Synthesis of a Helical Bilayer Nanographene

Paul J. Evans、Jiangkun Ouyang、Ludovic Favereau 等 7 位作者2018-02-15Angewandte Chemie International Edition

A rigid, inherently chiral bilayer nanographene has been synthesized as both the racemate and enantioenriched M isomer (with 93 % ee) in three steps from established helicenes. This folded nanographene is composed of two hexa-peri-hexabenzocoronene layers fused to a [10]helicene, with an interlayer distance of 3.6 Å a…

Graphene research and applicationsFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic Compounds

Plasmon Waveguiding in Nanowires

Hong Wei、Deng Pan、Shunping Zhang 等 8 位作者2018-02-15Chemical Reviews

Nanowires supporting propagating surface plasmons can function as nanowaveguides to realize the light guiding with field confinement beyond the diffraction limit, providing fundamental building blocks for nanophotonic integrated circuits. This review covers the recent developments of plasmon waveguiding in nanowires,…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic and Optical Devices

High-performance graphdiyne-based electrochemical actuators

Chao Lü、Ying Yang、Jian Wang 等 12 位作者2018-02-15Nature Communications

Abstract Electrochemical actuators directly converting electrical energy to mechanical energy are critically important for artificial intelligence. However, their energy transduction efficiency is always lower than 1.0% because electrode materials lack active units in microstructure, and their assembly systems can har…

Advanced Sensor and Energy Harvesting MaterialsAdvanced Memory and Neural ComputingConducting polymers and applications

Amyloid Polymorphism in the Protein Folding and Aggregation Energy Landscape

Jozef Adamčík、Raffaele Mezzenga2018-02-15Angewandte Chemie International Edition

Protein folding involves a large number of steps and conformations in which the folding protein samples different thermodynamic states characterized by local minima. Kinetically trapped on- or off-pathway intermediates are metastable folding intermediates towards the lowest absolute energy minima, which have been post…

Protein Structure and DynamicsAlzheimer's disease research and treatmentsEnzyme Structure and Function

Lanthanum-Doped Hafnium Oxide: A Robust Ferroelectric Material

Uwe Schroeder、Claudia Richter、Min Hyuk Park 等 13 位作者2018-02-15Inorganic Chemistry

Recently simulation groups have reported the lanthanide series elements as the dopants that have the strongest effect on the stabilization of the ferroelectric non-centrosymmetric orthorhombic phase in hafnium oxide. This finding confirms experimental results for lanthanum and gadolinium showing the highest remanent p…

Semiconductor materials and devicesMXene and MAX Phase MaterialsFerroelectric and Negative Capacitance Devices

A low cost and high performance polymer donor material for polymer solar cells

Chenkai Sun、Fei Pan、Haijun Bin 等 9 位作者2018-02-15Nature Communications

The application of polymer solar cells requires the realization of high efficiency, high stability, and low cost devices. Here we demonstrate a low-cost polymer donor poly[(thiophene)-alt-(6,7-difluoro-2-(2-hexyldecyloxy)quinoxaline)] (PTQ10), which is synthesized with high overall yield of 87.4% via only two-step rea…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces

Phase shift of oscillatory magnetoresistance in a double-cross thin film structure of La0.3Pr0.4Ca0.3MnO3 via strain-engineered elongation of electronic domains

H. S. Alagoz、Bhagwati Prasad、Jae‐Chun Jeon 等 6 位作者2018-02-15Physical review. B./Physical review. B

The subtle balance between the competing electronic phases in manganites due to complex interplay between spin, charge, and orbital degrees of freedom could allow one to modify the properties of electronically phase separated systems. In this paper, we show that the phase shift in the oscillatory magnetoresistance $\e…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Polymer matrices for porphyrin nanorods incorporation. Artificial light harvesting applications

N. Mongwaketsi、Noluthando Mayedwa、N. Matinise 等 6 位作者2018-02-15Journal of Porphyrins and Phthalocyanines

This contribution is focused on the supramolecular approach in exploration of aggregates formation by two different porphyrins wherein self-assembly plays an important role. Spectroscopic and microscopic studies usually provide information on investigations regarding the effects of various parameters on the fabricatio…

Carbon Nanotubes in CompositesPorphyrin and Phthalocyanine ChemistryFullerene Chemistry and Applications

Fast and controlled fabrication of porous graphene oxide: application of AFM tapping for mechano-chemistry

Liangyong Chu、Alexander V. Korobko、Marcel Bus 等 6 位作者2018-02-15Nanotechnology

Abstract This paper describes a novel method to fabricate porous graphene oxide (PGO) from GO by exposure to oxygen plasma. Compared to other methods to fabricate PGO described so far, e.g. the thermal and steam etching methods, oxygen plasma etching method is much faster. We studied the development of the porosity wi…

Graphene research and applicationsForce Microscopy Techniques and ApplicationsNanopore and Nanochannel Transport Studies