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Investigation of the primary plasticisers present in polyvinyl chloride (PVC) products currently authorised as food contact materials

Katherine Carlos、Lowri S. de Jager、Timothy H. Begley2018-03-06Food Additives & Contaminants Part A

PVC is a common food contact material that is usually plasticised to increase its flexibility. Phthalates are one class of chemical compounds that are often used as plasticisers in PVC in a wide range of industries. They may be used in packaging materials for foods and can also be found in components of certain food p…

Effects and risks of endocrine disrupting chemicalsMicroplastics and Plastic PollutionPolymer Science and PVC

Ambient Pressure Hard X-ray Photoelectron Spectroscopy for Functional Material Systems as Fuel Cells under Working Conditions

Yasumasa Takagi、Tomoya Uruga、Mizuki Tada 等 5 位作者2018-03-06Accounts of Chemical Research

Conspectus Heterogeneous interfaces play important roles in a variety of functional material systems and technologies, such as catalysis, batteries, and devices. A fundamental understanding of efficient functions at interfaces under realistic conditions is crucial for sophisticated designs of useful material systems a…

Electrocatalysts for Energy ConversionFuel Cells and Related MaterialsMachine Learning in Materials Science

High-Performance Amorphous Indium Gallium Zinc Oxide Thin-Film Transistors Fabricated by Atomic Layer Deposition

Min Hoe Cho、Hyunju Seol、Hoichang Yang 等 7 位作者2018-03-06IEEE Electron Device Letters

This letter reports the fabrication of high-performance amorphous indium gallium zinc oxide (a-IGZO) thin-film transistors (TFTs) via atomic layer deposition at a substrate temperature of 250 °C. The film thickness of In2O3, Ga2O3, and ZnO varied linearly with the number of deposition cycles. The cation composition of…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Ultrastrong Graphene–Copper Core–Shell Wires for High-Performance Electrical Cables

Sang-Jin Kim、Dong Heon Shin、Yong Seok Choi 等 14 位作者2018-03-06ACS Nano

Recent development in mobile electronic devices and electric vehicles requires electrical wires with reduced weight as well as enhanced stability. In addition, since electric energy is mostly generated from power plants located far from its consuming places, mechanically stronger and higher electric power transmission…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsFiber-reinforced polymer composites

Internal Polarization Modulation in Bi 2 MoO 6 for Photocatalytic Performance Enhancement under Visible‐Light Illumination

Yan Chen、Weiyi Yang、Shuang Gao 等 6 位作者2018-03-06ChemSusChem

Abstract A built‐in electric field from polarization inside polar photocatalysts could provide the driving force for photogenerated electrons and holes to move in opposite directions for better separation to improve their photocatalytic performance. The photocatalytic performance of a polar photocatalyst of Bi 2 MoO 6…

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Substantiation of diagnostic parameters for determining the technical condition of transmission assemblies in trucks

Віктор Аулін、A. Hrinkiv、Aleksandr Dykha 等 6 位作者2018-03-06Eastern-European Journal of Enterprise Technologies

We have conducted a selection of diagnostic parameters to control technical condition of the gear box. Development of technical operation of transportation vehicles is aimed at examining and predicting a technical condition with the formation of a rational diagnostic base being a key direction.Solving the tasks in a g…

Technical Engine Diagnostics and MonitoringEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Use of Taguchi approach for synthesis of calcite particles from calcium carbide slag for CO2 fixation by accelerated mineral carbonation

Mahmut Altıner2018-03-06Arabian Journal of Chemistry

This study is focused on the conversion of harmful materials (calcium carbide slag [CCS] and flue gas) into CaCO3 particles through an accelerated mineral carbonation process. The influences of reaction temperature, amount of Na-oleate, solid-to-liquid ratio, and stirring speed on the properties of CaCO3 particles wer…

Concrete and Cement Materials ResearchCalcium Carbonate Crystallization and InhibitionCO2 Sequestration and Geologic Interactions

Improved stability and catalytic activity of graphene oxide/chitosan hybrid beads loaded with porcine liver esterase

Shruthi Sunderrajan、Lima Rose Miranda、Gautam Pennathur2018-03-06Preparative Biochemistry & Biotechnology

Graphene oxide/chitosan and reduced graphene oxide/chitosan (GO/CS and RGO/CS) beads were prepared by precipitation with NaOH. Porcine liver esterase was immobilized on these beads to give GO/CS/E and RGO/CS/E beads. The optimum conditions for the maximum activity of RGO/CS/E beads were pH 8 and 50°C. The stability of…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

Effect of incorporation of blackberry particles on the physicochemical properties of edible films of arrowroot starch

Gislaine Ferreira Nogueira、Farayde Matta Fakhouri、Rafael Augustus de Oliveira2018-03-06Drying Technology

This research work evaluated the physicochemical properties of arrowroot starch films plasticized with glycerol and incorporated directly and by sprinkling with 0, 20, 30, and 40% (blackberry solids mass/biopolymer mass) blackberry particles obtained by spray drying. The films were characterized by thickness, color, w…

Food composition and propertiesNanocomposite Films for Food PackagingMicroencapsulation and Drying Processes

Metal-Free Aqueous Flow Battery with Novel Ultrafiltered Lignin as Electrolyte

Alolika Mukhopadhyay、Jonathan Hamel、Rui Katahira 等 4 位作者2018-03-06ACS Sustainable Chemistry & Engineering

As the number of generation sources from intermittent renewable technologies on the electric grid increases, the need for large-scale energy storage devices is becoming essential to ensure grid stability. Flow batteries offer numerous advantages over conventional sealed batteries for grid storage. In this work, for th…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Bactericidal and Hemocompatible Coating via the Mixed-Charged Copolymer

Xiaoli Fan、Mi Hu、Zhihui Qin 等 10 位作者2018-03-06ACS Applied Materials & Interfaces

Cationic antibacterial coating based on quaternary ammonium compounds, with an efficient and broad spectrum bactericidal property, has been widely used in various fields. However, the high density of positive charges tends to induce weak hemocompatibility, which hinders the application of the cationic antibacterial co…

Polymer Surface Interaction StudiesAntimicrobial Peptides and ActivitiesAntimicrobial agents and applications

Supramolecular Pseudorotaxane Polymers from Biscryptands and Bisparaquats

Terry L. Price、Harry W. Gibson2018-03-06Journal of the American Chemical Society

Five new bis(dibenzo-30-crown-10-based cryptand)s were synthesized, two of which ( 16 and 17 ) had long (12-atom), flexible spacers that led to cooperative complexation of dibenzyl paraquat TFSI ( K ave = 4.36 × 10 5 M –1 for 17•2b ). Self-assembly of 16 and 17 with bisparaquats with similar spacers ( 18, 21, and 23 )…

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsHemoglobin structure and function

Seismic life-cycle cost analysis of ageing highway bridges under chloride exposure conditions: modelling and recommendations

Shivang Shekhar、Jayadipta Ghosh、Jamie E. Padgett2018-03-06Structure and Infrastructure Engineering

Chloride-induced corrosion of highway bridges constitutes a critical form of environmental deterioration and may result in significant escalation of seismic life-cycle costs due to increased fragility during earthquake events. Most of existing literature tends to adopt simplistic uniform area loss assumptions in lieu…

Corrosion Behavior and InhibitionInfrastructure Maintenance and MonitoringConcrete Corrosion and Durability

Diarylboron‐Based Asymmetric Red‐Emitting Ir(III) Complex for Solution‐Processed Phosphorescent Organic Light‐Emitting Diode with External Quantum Efficiency above 28%

Xiaolong Yang、Haoran Guo、Boao Liu 等 7 位作者2018-03-06Advanced Science

Abstract Organic light‐emitting diodes (OLEDs) are one of the most promising technologies for future displays and lighting. Compared with the blue and green OLEDs that have achieved very high efficiencies by using phosphorescent Ir(III) complexes, the red OLEDs still show relatively low efficiencies because of the lac…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Recent progress of pyrimidine derivatives for high-performance organic light-emitting devices

Ryutaro Komatsu、Hisahiro Sasabe、Junji Kido2018-03-06Journal of Photonics for Energy

Pyrimidine is an electron-deficient azaaromatic compound containing two nitrogen atoms at 1, 3-positions that plays a key role as an organic semiconductor or semiconducting material. Because of the high electron-accepting property induced by C═N double bonds and due to its coordination ability, pyrimidine has been inc…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Iron Phthalocyanine Decorated Nitrogen-Doped Graphene Biosensing Platform for Real-Time Detection of Nitric Oxide Released from Living Cells

Huiying Xu、Chong Liao、Yujie Liu 等 5 位作者2018-03-06Analytical Chemistry

Nitric oxide (NO) is a transcellular messenger involved in many physiological and pathological processes, but the real-time detection of NO in biological systems is still challenging due to its rapid diffusion, low concentration, and short half-life. A novel electrochemical sensing platform based on iron phthalocyanin…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

Bandgap Engineering of Stable Lead‐Free Oxide Double Perovskites for Photovoltaics

Qingde Sun、Jing Wang、Wan‐Jian Yin 等 4 位作者2018-03-06Advanced Materials

Abstract Despite the rapid progress in solar power conversion efficiency of archetype organic–inorganic hybrid perovskite CH 3 NH 3 PbI 3 ‐based solar cells, the long‐term stability and toxicity of Pb remain the main challenges for the industrial deployment, leading to more uncertainties for global commercialization.…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Reconfigurable Microfluidic Droplets Stabilized by Nanoparticle Surfactants

Anju Toor、Sean Lamb、Brett A. Helms 等 4 位作者2018-03-06ACS Nano

Interfacial assemblies of nanoparticles can stabilize liquid-liquid interfaces. Due to the interactions between functional groups on nanoparticles dispersed in one liquid and polymers having complementary end-functionality dissolved in a second immiscible fluid, the anchoring of a well-defined number of polymer chains…

Innovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilizationElectrowetting and Microfluidic Technologies

Electronic Circuits Integration in Textiles for Data Processing in Wearable Technologies

Séverine de Mulatier、Mohamed Nasreldin、Roger Delattre 等 5 位作者2018-03-06Advanced Materials Technologies

Abstract To become an integral part of the everyday outfits, wearable electronics are expected to be lightweight, conformable, imperceptible for the user and life‐proof. The prospect of integrating modern technologies in clothes requires electronic circuits in textiles which are able to perform complex computing with…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTactile and Sensory Interactions

Elucidating the Structures of Amyloid Oligomers with Macrocyclic β-Hairpin Peptides: Insights into Alzheimer’s Disease and Other Amyloid Diseases

Adam G. Kreutzer、James S. Nowick2018-03-06Accounts of Chemical Research

Conspectus In the more than a century since its identification, Alzheimer’s disease has become the archetype of amyloid diseases. The first glimpses of the chemical basis of Alzheimer’s disease began with the identification of “amyloid” plaques in the brain in 1892 and extended to the identification of proteinaceous f…

Alzheimer's disease research and treatmentsComputational Drug Discovery MethodsSupramolecular Self-Assembly in Materials