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Validation and application of an LC-MS/MS method for the determination of cyclic oligomers originating from polyamide 6 and polyamide 66 in food simulant

Oliver Kappenstein、Ingo Ebner、Carina Förster 等 7 位作者2018-03-06Food Additives & Contaminants Part A

Polyamides (PAs) are used in the production of various food contact materials (FCMs) and articles such as kitchen utensils and packaging material. Cyclic oligomers have been identified as potential migrants from PA. This study describes the development, validation and application of a multi-oligomer analytical method…

biodegradable polymer synthesis and propertiesEffects and risks of endocrine disrupting chemicalsMicroplastics and Plastic Pollution

Porous and Transparent Metal‐oxide Electrodes : Preparation Methods and Electroanalytical Application Prospects

Maciej Mierzwa、Emmanuel Lamouroux、Alain Walcarius 等 4 位作者2018-03-06Electroanalysis

Abstract A review on the preparation methods for porous and transparent metal‐oxide electrodes is provided alongside a discussion of existing and possible electrochemical and electroanalytical applications. The elaboration routes include non‐templated particle deposition, template approaches, physical deposition metho…

Electrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsCopper-based nanomaterials and applications

One-pot synthesis of purple benzene-derived MnO2-carbon hybrids and synergistic enhancement for the removal of cationic dyes

Hyemin Kim、Nagahiro Saito2018-03-06Scientific Reports

Abstract MnO2-carbon hybrid (MnO2-C-PBz) was simultaneously synthesized by a one-step solution plasma process (SPP) using a single precursor referred to as “purple benzene”, which was derived from the K+(dicyclohexano-18-crown-6 ether) complex. To clarify the synergistic effects on the cationic dye removal, MnO2-free…

Adsorption and biosorption for pollutant removalGraphene research and applicationsGraphene and Nanomaterials Applications

Effects of Nb and Tempering Time on Carbide Precipitation Behavior and Mechanical Properties of Cr–Mo–V Steel for Brake Discs

Dan Wu、Fuming Wang、Jin Cheng 等 4 位作者2018-03-06steel research international

To improve the performance of the steel for brake discs, like mechanical properties and thermal fatigue resistance, Nb is added to the steel. In this paper, the effects of Nb and tempering time on the microstructure and mechanical properties of the steel have been studied. The investigation of precipitation behaviors…

Brake Systems and Friction AnalysisMechanical stress and fatigue analysisMetal Alloys Wear and Properties

The Role of Extractives and Wood Anatomy in the Wettability and Free Surface Energy of Hardwoods

Agnieszka Jankowska、Piotr Boruszewski、Michał Drożdżek 等 6 位作者2018-03-06BioResources

The main goal of this paper was to clarify to what extent extractives and wood structure determine the surface properties of hardwoods, mainly tropical. The role of wood extractives relative to properties, such as wettability and free surface energy, has been confirmed. The most significant seemed to be cyclohexane ex…

Wood Treatment and PropertiesTextile materials and evaluationsMaterial Properties and Processing

Effect of microtrichia on the interlocking mechanism in the Asian ladybeetle, Harmonia axyridis (Coleoptera: Coccinellidae)

Jiyu Sun、Chao Liu、Bharat Bhushan 等 5 位作者2018-03-06Beilstein Journal of Nanotechnology

The hindwings of beetles are folded under the elytra when they are at rest but are extended during flight, which can provide bioinspiration for the design of deployable micro air vehicles (MAVs). Beetle hindwings must be able to be both securely locked under the elytra and freely extended for flight, depending on the…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsPlant Surface Properties and Treatments

Modulation of functional pendant chains within poly(ethylene glycol) hydrogels for refined control of protein release

Mirae Kim、Chaenyung Cha2018-03-06Scientific Reports

Hydrogels are highly attractive delivery vehicles for therapeutic proteins. Their innate biocompatibility, hydrophilicity and aqueous permeability allow stable encapsulation and release of proteins. The release rates also can be controlled simply by altering the crosslinking density of the polymeric network. However,…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Ordered Mesoporous Titania/Carbon Hybrid Monoliths for Lithium‐ion Battery Anodes with High Areal and Volumetric Capacity

Hwirim Shim、Simon Fleischmann、Marco Zeiger 等 6 位作者2018-03-06Chemistry - A European Journal

Abstract Free‐standing, binder‐free, and conductive additive‐free mesoporous titanium dioxide/carbon hybrid electrodes were prepared from co‐assembly of a poly(isoprene)‐block‐poly(styrene)‐block‐poly(ethylene oxide) block copolymer and a titanium alkoxide. By tailoring an optimized morphology, we prepared macroscopic…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Wear Characteristics and Volume Loss of CAD/CAM Ceramic Materials

Alec D. Zurek、Maria F. Alfaro、Alvin G. Wee 等 7 位作者2018-03-06Journal of Prosthodontics

PURPOSE: In the field of prosthodontics, patients often require complex and extensive restorative care. This can involve the use of dental restorations to restore teeth on both the maxillary and mandibular arch. Current literature has evaluated the wear properties of different dental ceramics against enamel, but studi…

Dental materials and restorationsAdvanced ceramic materials synthesisDental Implant Techniques and Outcomes

Mannich base-connected syntheses mediated by ortho-quinone methides

Petra Barta、Ferenc Fülöp、István Szatmári2018-03-06Beilstein Journal of Organic Chemistry

This article provides an overview about specifically modified Mannich reactions where the process involves an ortho-quinone methide (o-QM) intermediate. The reactions are classified on the basis of the o-QM source followed by the reactant, e.g., the dienophile partner in cycloaddition reactions (C=C or C=N dienophiles…

Photochromic and Fluorescence ChemistryBioactive Compounds and Antitumor AgentsSynthesis of Indole Derivatives

A multicenter post‐marketing evaluation of the Elixir DESolve ® Novolimus‐eluting bioresorbable coronary scaffold system: First results from the DESolve PMCF study

Holger Nef、Jens Wiebe、Niklas Boeder 等 13 位作者2018-03-06Catheterization and Cardiovascular Interventions

OBJECTIVES: To date, experience with bioresorbable scaffolds (BRS) that elute agents other than everolimus is limited. Thus, a post-marketing clinical follow-up study was conducted to evaluate the continued safety and effectiveness of the DESolve® NOVOLIMUS™ Eluting BRS as treatment for patients with stable coronary a…

Coronary Interventions and DiagnosticsElectrospun Nanofibers in Biomedical ApplicationsCardiac and Coronary Surgery Techniques

Fluorocarbon Separation in a Thermally Robust Zirconium Carboxylate Metal–Organic Framework

Darshika K. J. A. Wanigarathna、Jiajian Gao、Bin Liu2018-03-06Chemistry - An Asian Journal

Abstract Fluorocarbons have important applications in industry, but are environmentally unfriendly, and can cause ozone depletion and contribute to the global warming with long atmospheric lifetimes and high global warming potential. In this work, the metal–organic framework UiO‐66(Zr) is demonstrated to have excellen…

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesCovalent Organic Framework Applications

Density of States Broadening in CH3NH3PbI3 Hybrid Perovskites Understood from ab Initio Molecular Dynamics Simulations

Liujiang Zhou、Amanda J. Neukirch、Dayton J. Vogel 等 10 位作者2018-03-06ACS Energy Letters

Lead-halide perovskites are promising materials in optoelectronic devices for their unique properties including direct band gap, strong light absorption, high carrier mobility, and low fabrication cost. Here, by using ab inito molecular dynamics and electronic structure calculations, we report a systematic study on th…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

"Do-It-Yourself" reliable pH-stat device by using open-source software, inexpensive hardware and available laboratory equipment

Jovana Milanović、Predrag Milanović、Rastislav Kragic 等 4 位作者2018-03-06PLoS ONE

In this paper, we present the construction of a reliable and inexpensive pH stat device, by using open-source "OpenPhControl" software, inexpensive hardware (a peristaltic and a syringe pump, Arduino, a step motor…), readily available laboratory devices: a pH meter, a computer, a webcam, and some 3D printed parts. We…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Improving the optical performance of multi-chip LEDs by using patterned phosphor configurations

Xinrui Ding、Chen Qiu、Hui Li 等 7 位作者2018-03-06Optics Express

In order to improve the color uniformity of multi-chip LEDs, a patterned phosphor configuration has been proposed by using pulsing spray process. The patterned phosphor has detached yellow and red phosphor regions matching every single LED chip. Optical performances of different phosphor parameters are experimentally…

Luminescence Properties of Advanced MaterialsGaN-based semiconductor devices and materialsGas Sensing Nanomaterials and Sensors

Mechanism of Gas-Phase Ozonolysis of β-Myrcene in the Atmosphere

Peng Deng、Lingyu Wang、Lingyu Wang 等 5 位作者2018-03-06The Journal of Physical Chemistry A

β-Myrcene is one of the major monoterpenes in the atmosphere. Ozonolysis is one of the oxidation removal processes for myrcene in the atmosphere during the daytime. In this study, the mechanism of myrcene ozonolysis is studied using high-level quantum chemistry calculations and kinetic calculations. The reaction start…

Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Oxa[7]superhelicen: ein π‐erweiterter, helikaler Chromophor auf Hexa‐peri‐hexabenzocoronen‐Basis

D.L. Reger、Philipp Haines、Frank W. Heinemann 等 5 位作者2018-03-06Angewandte Chemie

Abstract Ein neuartiges π‐erweitertes “Superhelicen” auf der Basis von Hexa‐peri‐hexabenzocoronenen wurde mit einem effizienten vierstufigen Syntheseverfahren ausgehend von Diphenylether synthetisiert. Das Helicen wurde durch NMR‐Spektroskopie und Massenspektrometrie in Kombination mit Röntgenstrukturanalyse zweifelsf…

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

Conical structures for highly efficient solar cell applications

Fatma M. H. Korany、Mohamed Farhat O. Hameed、Mohamed Hussein 等 6 位作者2018-03-06Journal of Nanophotonics

Improving solar cell efficiency is a critical research topic. Nowadays, light trapping techniques are a promising way to enhance solar cell performance. A modified nanocone nanowire (NW) is proposed and analyzed for solar cell applications. The suggested NW consists of conical and truncated conical units. The geometri…

Plasmonic and Surface Plasmon ResearchSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Synthesis of phosphorus doped carbon nanotubes using chemical vapor deposition

Fatemeh Mohammadi、Hossein Tavakol2018-03-06Fullerenes Nanotubes and Carbon Nanostructures

Phosphorous-doped carbon nanotubes (PCNTs) was prepared via two-step methodology employing chemical vapor deposition, by using available starting materials and catalyst. First, CNTs was produced from acetylene gas at 750 ºC and then, PCNTs have been prepared with total yield of 44% by recooking of the prepared CNT wit…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

On-chip switchable radially and azimuthally polarized vortex beam generation

Zengkai Shao、Jiangbo Zhu、Yanfeng Zhang 等 5 位作者2018-03-06Optics Letters

Cylindrical vector vortex (CVV) beams, complex light fields that exhibit a vector nature and carry quantized orbital angular momentum (OAM) states, have been widely investigated due to their rich applications. Current technologies to generate CVV beams using individual polarization and spatial phase manipulations suff…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics