Materials Literature
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A semiempirical method for the evaluation of the barycenter of energy of 4f N-1 5d configurations is presented. The environmental factors affecting the barycenter are given to be the bond volume polarization, fractional covalence of the chemical bond between the central ion and the nearest anion, and presented charge…
Coordination complexes of the ligand H3L [1,3-bis(3-oxo-3-phenylpropionyl)-2-hydroxy-5-methylbenzene] with Cu(II) are reported. Clusters showing various nuclearities or modes of supramolecular organization have been prepared by slightly changing the reaction conditions and have been crystallographically characterized.…
Synthesis and characterization of highly luminescent ZnS-passivated CdS:Mn (CdS:Mn/ZnS) core/shell structured nanocrystals are reported. Mn-doped CdS core nanocrystals are produced ranging from 1.5 to 2.3 nm in diameter with epitaxial ZnS shell of wider band gap via a reverse micelle process. UV irradiation-stimulated…
Abstract Dendritic–linear–dendritic triblock copolymers based on poly(ethylene glycol) (PEG) as the core and dendritic triazine blocks were synthesized. The micellar and aggregation characteristics of the compounds were investigated with NMR and fluorescence spectroscopy. The NMR investigations were carried out in a v…
Novel subphthalocyanine analogues that display strong absorption in the green region have been synthesized by using a boron template cyclotrimerization of maleonitrile derivatives. The spectroscopic properties of these macrocycles indicate that, like subphthalocyanines, they have 14 pi electrons and are aromatic compo…
Functionalization of silver and gold nanoparticles by 12mer-thiolated homo-oligonucleotides, SA and ST (containing only adenine or thymine, respectively), and their hybridization and dehybridization in aqueous dispersions have been described. In addition, ST and SA were self-assembled onto gold films and hybridized wi…
This article reports the study of the effect of relative grafting densities of two polymer chains on solvent-induced self-assembly of mixed poly(methyl methacrylate) (PMMA)/polystyrene (PS) brushes through a combinatorial approach. Gradient-mixed PMMA/PS brushes were synthesized from a gradient-mixed initiator-termina…
Manganese doped nanocrystalline willemite powder phosphors Zn(2-x)Mn(x)SiO(4) (0.1<or=x<or=0.5) have been synthesized by a low-temperature initiated, self-propagating, gas producing solution combustion process. The phosphors have been characterized by using x-ray diffraction (XRD), energy dispersive spectroscopy, scan…
We theoretically investigate exciton states of colloidal nearly spherical ZnO nanocrystals with diameters from $2\phantom{\rule{0.3em}{0ex}}\mathrm{nm}\phantom{\rule{0.5em}{0ex}}\text{to}\phantom{\rule{0.5em}{0ex}}6\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$. The sizes of considered ZnO nanocrystals are chosen to be sligh…
The first total synthesis of (+/-)-pentacycloanammoxic acid/methyl ester (1), an unusual naturally occurring fatty acid from Candidatus Brocadia anammoxidans, has been accomplished by the sequence of reactions shown in Scheme 1. The C20-structure of 1 was assembled with stereocontrol from three building blocks: cycloo…
Abstract: This chapter discusses and reviews the fundamental science and technology behind fabric structure and mechanics. The chapter introduces the extent of knowledge regarding fabric deformations, such as tensile, bending and shearing, and a new kind of testing method based on image analysis to characterize fabric…
The contribution of the dendritic structure in catalysis of ester hydrolysis was investigated with a systematic peptide dendrimer series of increasing generation number (G1-G4) containing a catalytic consensus sequence His-Ser in all branches. A strong positive dendritic effect was observed with up to 100-fold increas…
Pure ceria powders, CeO(2), were synthesized in heptane-microemulsified aqueous solutions of CeCl(3) or Ce(NO(3))(3) stabilized by AOT (sodium bis(2-ethylhexyl) sulfosuccinate), DDAB (di-n-didodecyldimethylammonium bromide), or DDAB + Brij 35 surfactant mixtures. Micellar DTAB (n-dodecyltrimethylammonium bromide) and…
All single crystals possess translational symmetry, and most possess other symmetry elements as well. In this chapter we describe the 32 crystallographic point groups used for single crystals. The seven Curie groups used for textured polycrystalline materials are enumerated in the next chapter. We live in a three-dime…
We present a high-resolution C1s and O1 s x-ray photoemission (XPS) study for condensed films of pi-conjugated organic molecules, namely, of the anhydrides 3,4,9,10-perylene-tetracarboxylic acid dianhydride, 1,4,5,8-naphthalene-tetracarboxylic acid dianhydride, 1,8-naphthalene dicarboxylic acid anhydride, and benzoper…
The dynamics of the domain wall (DW) in a biaxial ferromagnet interacting with a spin-polarized current are described by sine-gordon (SG) equation coupled with Gilbert damping term in this paper. Within our frame-work of this model, we obtain a threshold of the current in the motion of a single DW with the perturbatio…
By using an ultrasoft pseudopotentials method based on the density-functional theory, we have calculated the generalized stacking fault (GSF) energies for the [100](110), $[00\overline{1}](110)$, and $[1\overline{1}1](110)$ slip systems in bcc Fe within the local density approximation (LDA), spin-polarized LDA (LSDA),…
We have developed a dynamic self-consistent field theory, without any adjustable parameters, for unentangled polymer blends under shear. Our model accounts for the interaction between polymers, and enables one to compute the evolution of the local rheology, microstructure and the conformations of the polymer chains un…
We fabricated cantilevers for magnetic force microscopy with carbon nanotube tips coated with magnetic material. Images of a custom hard drive demonstrated 20 nm lateral resolution, with prospects for further improvements.
The ultrafast response of a high-reflectivity GaAs/AlAs Bragg mirror to optical pumping is investigated for all-optical switching applications. Both Kerr and free carrier nonlinearities are induced with 100 fs, 780 nm pulses with a fluence of 0.64 kJ/m^2 and 0.8 kJ/m^2. The absolute transmission of the mirror at 931 n…