Materials Literature
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Optical lifetime of the first mirror is a critical issue for the ITER upper-port-plug core-charge-exchange-spectroscopy diagnostic. A fast shutter is engaged to protect the mirror from depositions between measurements. The prototype shutter will be examined in a test vacuum vessel that is now under development in Fors…
In this paper, a discrete approach for the simulation of the preforming of dry woven reinforcement is proposed. A “unit cell” is built using elastic isotropic shells and axial connectors instead of bars and beams used in previous studies. Shell elements are used to take into account the in-plane shear stiffness and to…
The solubility and ultra solubility of borax decahydrate both in pure and impure solutions have been determined in the temperature range from (0 to 30) °C by means of the conventional polythermal method using the laser technique. The metastable zone width and the apparent nucleation order of borax were calculated. The…
Quick X-ray absorption spectroscopy (XAS) provides quantitative information about the composition of supported metal phases during catalyst activation. Decomposition of SiO2-supported cobalt nitrate in diluted NO leads to the rapid formation of cobalt(II) hydroxynitrates below 100 °C. Their decomposition starts progre…
We report x-ray photon correlation spectroscopy measurements of advective and diffusive dynamics in a dispersion of colloidal particles subjected to homogeneous shear flow in a rotating-disk shear cell. Intensity autocorrelation functions from scattering data collected using homodyne detection respond to the variation…
We have applied 3D-QSAR chemometric tools to analyze the polymerization activity of a series of analogous zirconocene catalysts with different substitution patterns in the cyclopentadienyl rings. The selection of the most stable conformers was performed by means of a conformational analysis of the different catalysts…
Tunability of energy levels and wavefunctions of carriers in colloidal quantum dots (CQDs) has a marked effect on numerous physical aspects, such as Coulomb interactions and charge separation, which in turn has a direct impact on the functioning of CQD-based opto-electronic devices. The electronic properties of CQDs a…
Coumarins C-153, C-480, and C-1 formed 1:2 (guest:host) complexes with a water-soluble cavitand having eight carboxylic acid groups (OA) in aqueous borate buffer solution. The complexes were photoexcited in the presence of electron acceptors (methyl viologen, MV(2+), or TiO(2)) to probe the possibility of electron tra…
Abstract Bagasse whiskers isolated from bleached bagasse pulp were chemically modified with n ‐octadecyl isocyanate in the presence of dibutyltin dilaurate as a catalyst. The modified cellulose whiskers were used in ratios from 2.5 to 15% with polycaprolactone (PCL) polymer to prepare nanocomposite films by a solution…
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Abstract A methacrylate‐based crosslinking hyperbranced polymers have been synthesized through initiator‐fragment incorporation radical polymerization and used for the temperature stable electro‐optic (EO) polymer application. This polymer consists of methyl methacrylate, 2‐metacryloxyethyl isocyanate, and ethylene gl…
Paramagnetic gadolinium(III) complexes are widely used to increase contrast in magnetic resonance (MR) images. Contrast enhancement depends on the concentration of the gadolinium complex and on its relaxivity, an inherent property of the complex. Increased relaxivity results in greater image contrast or the ability to…
Abstract In this work, we prepared polynorbornene dicarboximide (PND)/amine functionalized graphene (AFG) hybrids in N , N ‐dimethylacetamide (DMAc). The AFG was synthesized by modifying graphene oxides (GO) with amine groups. The AFG sheets were well‐dispersed in DMAc and randomly distributed throughout the PND matri…
A key stage in both the use of polymer rods in Split Hopkinson Pressure Bar (SHPB) testing and in establishing the material properties of these rods is the experimental determination of the propagation coefficient. An analytical investigation of the experimental arrangements used to ascertain the propagation coefficie…
Detailed calculations of the attenuation of low-frequency electromagnetic fields and dielectric losses by a dilute suspension of gold colloidal nanoparticles are reported. The attenuation produced by the particles suspended in an aqueous medium of low electrolyte concentration was found to be modest as compared with t…
We investigate a dynamical magnetoelectric effect due to a magnetic resonance in helical spin structures through the coupling between magnetization and electric polarization via a spin current mechanism. We show that the magnon has both the dynamical magnetic moment $\Delta M^\omega$ and the electric moment $\Delta P^…
In recent years, there has been a growing interest in the studies involving the interactions of fluorophores with plasmonic nanostructures or nanoparticles. These interactions lead to several favorable effects such as increase in the fluorescence intensities, increased photostabilities, and reduced excited-state lifet…
Dendrimers crosslinked with a photochromic diarylethene (blue in picture) were labeled with the fluorescent dye Cy3 (red) for reversible fluorescence photoswitching. If the obtained nanoclusters are irradiated with UV light, the Cy3 fluorescence is quenched by the diarylethene in its ring-closed form, whereas upon irr…
In this work we demonstrate progress in the colloidal synthesis of amphiphilic CdTe nanocrystals stabilized by thiolated PEG oligomers with the aim of facilitating cellular uptake of the particles. High-boiling, good coordinating solvents such as dimethylacetamide and dimethylformamide accelerate the growth of the nan…
The quality of foaming products (such as beer and shampoo) and the performance of industrial processes that harness foam (such as the froth flotation of minerals or the foam fractionation of proteins) depend upon foam stability. In this study, experiments are performed to study the effect of environmental humidity on…