Materials Literature
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Recently a new monoclinic phase in the Pb(Zr1−xTix)O3 ceramic system has been reported by Noheda et al.[1] for a composition of x=0.48. In this work, samples with Ti contents x=0.47 and 0.50, which are both tetragonal below their Curie point, have been investigated. In the sample with x=0.50, the tetragonal phase was…
It is known that for creating advanced polyolefin/cement-based composites the polymer surface should be converted into a layer which is compatible with the inorganic component. In this respect, plasma chemistry offers additional solutions to the wet chemistry approach. It has been demonstrated during the last decade t…
High quality MCM-41 silica with thick walls and a very narrow distribution of mesopore size has been synthesized in a relatively short time via ultrasound radiation.
This paper gives theoretical results on spinodal decomposition for the Cahn--Hillard equation. We prove a mechanism which explains why most solutions for the Cahn--Hilliard equation starting near a homogeneous equilibrium within the spinodal interval exhibit phase separation with a characteristic wavelength when exiti…
Here we describe the synthesis and electrochemical polymerisation of 2,5-di(2-thienyl)-3-(3-cyanopropyl)pyrrole, 2,5-di(2-thienyl)-3-(3-cyanopropyl)furan, and 3′-(3-cyanopropyl)-2,2′:5′,2″-terthiophene. We report a synthetic methodology to these important conducting polymer precursor compounds that is facile, convenie…
Factors Affecting Passivation of Cu(Mg) Alloy Films, Lee, Wonhee, Cho, Heunglyul, Cho, Bumseok, Kim, Jioung, Kim, Yong‐Suk, Jung, Woo‐Gwang, Kwon, Hoon, Lee, Jinhyung, Reucroft, P. J., Lee, Chongmu, Lee, Jaegab
The new dodecadentate tripodal ligand trenterpy in the presence of lanthanide triflates leads to the self assembly of homotrinuclear lanthanide complexes.
The magnetic and crystallographic properties of induction-melted SmMn/sub 6-x/Fe/sub x/Ge/sub 6/ compounds, where x is 0, 0.5, 1.0, and 1.5, have been studied using X-ray diffraction and bulk magnetic measurements between 30 and 490 K. All of the samples crystallized in the YCo/sub 6/Ge/sub 6/-type structure with the…
This work presents a comparative study of the compatibilization of four binary blends with slight differences in their chemical structures. The natural polymers chitin (QA) and chitosan (QN) are blended with polyamide 6 (PA6) and polyamide 66 (PA66). The results, obtained using differential scanning calorimetry, infra…
A nickel(II)tetramer with azide and di-2-pyridyl ketone (dpk) of general formula [Ni(dpk·OH)(N3)]4·2H2O (dpk·OH being the deprotonated gem-diol resulting from hydrolysis of dpk) was synthesized and structurally characterised through X-ray single crystal diffraction analysis and IR spectroscopy. The structure consists…
The linear combinations of Gaussian-type orbitals–fitting function (LCGTO-FF) technique is used to study the zero-pressure properties of crystalline uranium dioxide, a prototypical heavy element bearing Mott–Hubbard insulator. The effects of several common approximations are examined: (1) scalar vs. full relativity; (…
We introduced a triode structure with p–n junctions on both sides into single-crystalline bifacial silicon solar cells in order to improve solar cell performance. These fabricated bifacial silicon solar cells have an energy conversion efficiency of 21·3% under front 1 sun illumination (the standard 1 kW/m2 AM 1·5 glob…
Pyrroles fused with bicyclo[2.2.2]octene and bicyclo[2.2.1]heptene frameworks are prepared by a modified Barton–Zard method. Structures of these pyrroles and thermal behaviours of the former pyrroles are studied by X-ray and DSC analyses.
The aims of this study were to characterize certain physicochemical, pharmacokinetic, and enhancement properties of a new macromolecular contrast agent, carboxymethyl hydroxyethyl starch-(Gd-DO3A)(35) [CMHES-(Gd-DO3A)(35)], consisting of a polysaccharide backbone covalently derivatized with multiple macrocyclic chelat…
Corrosion behavior of hot-dip Zn-6%Al-03%Mg alloy coated steel sheets in cyclic corrosion test (CCT) has been investigated.The corrosion resistance was improved with increasing Mg content in the coating layer, and the highest corrosion resistance was observed at 3% Mg. In Zn-6%Al-3%Mg alloy coated steel sheet, the for…
This paper presents the results of investigations on the performance of nonceramic insulators in tropical field conditions. Six different types of 33 kV insulators (silicone rubber, EPDM composite, porcelain, and RTV coated porcelain) were installed at six different test sites exposed to marine, industrial and clean e…
The feasibility of LDPE films containing 0.2 or 0.5% (w/w) hexamethylenetetramine (HMT) as antimicrobial packaging material to inhibit microbial growth on the surface of foods was investigated. As HMT is allowed in Europe to be used as a preservative under certain conditions, and as it is mentioned on the list of addi…
The electrical resistivity and Seebeck coefficient of (R0.9Ca0.1)CoO3 (R = Gd, Sm, Nd, Pr) rapidly decrease with increasing ionic radius of the rare-earth element, and the Seebeck coefficients (p-type) are fairly high at low temperatures and attain low and constant values at high temperatures; (Pr0.9Ca0.1)CoO3 shows t…
The magnetic susceptibility (χ) of 1,6,10,15,19,25,28,32-octa-n-butoxynaphthalocyaninatomanganese(III) tetra-cyanoethanide can be fit to a Curie–Weiss expression with θ = 54 K for T > 150 K, and the χT(T) data are con-sistent with linear chains and can be fit to a Seiden expression for alternating S = 2 and S = 1/2 an…
Recently, the calcined powder of oyster shells has been found to possess antibacterial activity, and has been considered for use as a bactericidal agent. In this study, calcined shell preparations were made from oysters, scallops, clams and roll shells, and their antibacterial activities were compared using total aero…