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Analysis of cellular microstructures in Al–Fe–Si alloy

W. B. Hutchinson2000-11-01Materials Science and Technology

Experiments have been carried out on a commercial aluminium alloy rolled to foils with various high rolling reductions. Attention was focused on the formation of cells during deformation. Microstructures were examined in the SEM using electron backscatter diffraction (EBSD) and oriented imaging microscopy techniques.…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesMetallurgy and Material Forming

Stability of Cu2Ln2O5 Compounds - Comparison, Assessment and Systematics

K. P. Jayadevan、Κ. T. Jacob2000-11-01High Temperature Materials and Processes

Phase diagram studies show that at ambient pressure only one ternary oxide, Cu 2 Ln 2 O s , is stable in the ternary systems Cu-Ln-O (Ln = Tb, Dy, Ho, Er, Tm, Yb, Lu) at high temperatures. The crystal structure of Cu 2 Z,rc 2 0 5 can be described as a zig-zag arrangement of one-dimensional Cu 2 O s chains parallel to…

Catalytic Processes in Materials ScienceAdvanced Condensed Matter PhysicsCopper-based nanomaterials and applications

Near-surface chemistry in Zr2Fe and ZrVFe studied by means of x-ray photoemission spectroscopy: A temperature-dependent study

Janez Kovač、O. Sakho、Paolo Manini 等 4 位作者2000-11-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The near-surface atomic composition and the character of chemical bond in two nonevaporable gettering alloys have been investigated via core level (Zr 3d, Fe 2p, V 2p, O 1s, C 1s) photoemission. The samples have been measured in UHV after in-air fracturing and various annealing steps (up to 850 °C). For T>400 °…

Metal and Thin Film MechanicsFusion materials and technologiesNuclear Materials and Properties

Infrared Study of ZrO 2 Surface Sites Using Adsorbed Probe Molecules. 2. Dimethyl Ether Adsorption

Feng Ouyang、Shuiliang Yao2000-11-01The Journal of Physical Chemistry B

The properties of two types of surface OH species, terminal (t) and bridged (b), as well as corresponding vacant sites on ZrO 2 at 573 K have been studied using dimethyl ether (DME) adsorption as an IR molecular probe. On the dehydroxylated ZrO 2 surface, the molecularly adsorbed CH 3 OCH 3 species was dissociated mod…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Consolidation of Eutectic Powder of Al 2 O 3 –GdAlO 3

Mamoru Omori、Toshinori Isobe、Toshio Hirai2000-11-01Journal of the American Ceramic Society

A eutectic solid of Al 2 O 3 –GdAlO 3 was prepared by arc discharge and crushed to a eutectic powder of 3–125 μm. The powder was consolidated by the spark plasma system (SPS). The consolidated powder duplicated the eutectic structure: Al 2 O 3 and GdAlO 3 were joined to each crystal. There were no flaws such as cracks…

Advanced ceramic materials synthesisAdvanced materials and compositesMicrowave Dielectric Ceramics Synthesis

Scale Dissolver Application: Production Enhancement and Formation-Damage Potential

M. M. Jordan、G. M. Graham、K. S. Sorbie 等 6 位作者2000-11-01SPE Production & Facilities

Summary Sulfate scale dissolvers have been applied downhole for many years to remove barium and mixed sulfate scale deposits from the wellbore and from the near-wellbore formation. As well as dissolving mineral scales, these corrosive materials also have the potential to cause some degree of formation damage by the di…

Hydraulic Fracturing and Reservoir AnalysisDrilling and Well EngineeringCalcium Carbonate Crystallization and Inhibition

Structures and Magnetic Properties of Ruthenium(II,III) Pivalate Cation Dimers Axially Coordinated by Pyridyl Nitronyl Nitroxide Radicals through Their Pyridyl Nitrogen Atoms

Yasuyoshi Sayama、Makoto Handa、Masahiro Mikuriya 等 5 位作者2000-11-01Bulletin of the Chemical Society of Japan

Abstract Adduct complexes of ruthenium(II,III) pivalate dimer with pyridyl nitronyl nitroxide radicals, [Ru2(O2CCMe3)4(L)2]X (L = 2-(3-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide (m-nitpy) and 2-(4-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide (p-nitpy); X = BF4 an…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Thermal Expansion Characteristics of Alumina–Magnesia and Alumina–Spinel Castables in the Temperature Range 800°–1650°C

Yung‐Chao Ko、Jinn Tsang Lay2000-11-01Journal of the American Ceramic Society

The thermal expansion of Al 2 O 3 –MgO castables containing 5.5 wt% MgO and 1.36 wt% CaO and Al 2 O 3 –spinel castables containing 20 wt% spinel having 95 wt% Al 2 O 3 and 1.7 wt% CaO was measured in the temperature range of 800–1650°C by dilatometry. A sharp increase in expansion from around 1425° to 1525°C, followed…

Advanced ceramic materials synthesisAdvanced materials and compositesMicrowave Dielectric Ceramics Synthesis

The effects of PC‐PMMA block copolymer on the compatibility and interfacial properties of PC/SAN blends

Eunah Kang、J. H. Kim、Chang Keun Kim 等 5 位作者2000-11-01Polymer Engineering and Science

Abstract Block copolymers of polycarbonate (PC) and polymethylmethacrylate (PMMA), PCb‐PMMA, were examined as compatibilizers for blends of PC with styrene‐co‐acrylonitrile (SAN) copolymer. PC‐b‐PMMA was added to blends of PC with SAN containing various amounts of AN. The average diameter of the dispersed particles wa…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Stress Corrosion Cracking Caused by Passive Film-Induced Tensile Stress

Haiyang Lu、Ke Gao、L.J. Qiao 等 5 位作者2000-11-01CORROSION

α-Ti foil with a protective layer formed on one side was deflected as a result of corrosion in a methanol (CH3OH) solution containing 0.6 mol/L potassium chloride (KCl) because of tensile stresses generated at or near the metal passive film interface. Transmission electron microscopy (TEM) observations showed that the…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Sensory Measurements of the Main Mechanical Parameters of Knitted Fabrics

D. Alimaa、T. Matsuo、Masaru Nakajima 等 4 位作者2000-11-01Textile Research Journal

Mechanical parameters such as bending rigidity, thickness, compressibility, and coef ficient of friction are measured by a sensory method for a series of plain and rib weft knitted structures made from cashmere and polyester textured yarns. The values estimated by the sensory method are found to be in fairly good agre…

Mechanical Behavior of CompositesTextile materials and evaluationsErgonomics and Musculoskeletal Disorders

Immersion Plating of Copper on Porous Silicon in Various Solutions

Yukio H. Ogata、Junji Sasano、Jacob Jorné 等 6 位作者2000-11-01physica status solidi (a)

The mechanism of immersion plating of copper on porous silicon is studied. Copper metal is deposited on the surface of porous silicon at a rest potential in aqueous solution. It is shown that presence of chloride ions in copper sulfate solution inhibits the metal deposition, whereas the deposition is possible in cupro…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Solid-State Microcellular Acrylonitrile-Butadiene-Styrene Foams

Ross E. Murray、John E. Weller、Vipin Kumar2000-11-01Cellular Polymers

Microcellular ABS foams are a novel family of materials with the potential to significantly reduce material costs in a number of applications that currently use solid polymer. ABS foams were produced using carbon dioxide in a solid-state process. Solubility and diffusivity of CO 2 in ABS was measured, and the latter w…

biodegradable polymer synthesis and propertiesPickering emulsions and particle stabilizationPolymer Foaming and Composites

Production of fine powder from silk by radiation

Hidefumi Takeshita、Kazushige Ishida、Youichi Kamiishi 等 5 位作者2000-11-01Macromolecular Materials and Engineering

Silk fine powder was prepared directly from silk fibers irradiated with an accelerated electron beam (EB). Irradiated silk fibers were well pulverized only by physical crushing using a ball mill without any chemical pretreatment. Silk fibroin fibers were irradiated at ambient temperature in the dose range of 250–1 000…

Insect and Arachnid Ecology and BehaviorSilk-based biomaterials and applicationsSilkworms and Sericulture Research

Mechanism for NO Photooxidation over the Oxygen-Deficient TiO2 Powder under Visible Light Irradiation

Isao Nakamura、Shinichi Sugihara、Koji Takeuchi2000-11-01Chemistry Letters

Abstract The mechanism for the photooxidation of NO over hydrogen plasma-treated TiO2 under visible light irradiation was studied by in situ Fourier transform infrared spectroscopy. It was found that the oxidation of NO over plasma-treated TiO2 under visible light proceeded consecutively as NO → NO2− → NO3−, where the…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Degradation Kinetics of Chlorophyll in Peas as a Function of pH

T. A. RYAN-STONEHAM、Vincent C. H. Tong2000-11-01Journal of Food Science

ABSTRACT: The kinetics of chlorophyll degradation in pea puree were determined in a specially designed reactor with on‐line pH control capability. Without pH control, the pH of the pea puree decreased continuously with heating due to acid formation; the pH was maintained within ±0.1 of the desired value with on‐line p…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

An azobenzene-containing side-on liquid crystal polymer

Min‐Hui Li、P. Auroy、Patrick Keller2000-11-01Liquid Crystals

A new azobenzene-containing side-on LC polymer was synthesized. It shows a nematic phase. Its photochemical properties were characterized in solution and in thin film. The N-I phase transition can be induced upon irradiation in the π-π* absorption region of the polymer.

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

XPS Investigation of X-Ray-Induced Reduction of Metal Ions

Şefik Süzer2000-11-01Applied Spectroscopy

An overview is given on the reduction by X-rays, of Au, Hg, Bl, V, and W metal ions during the XPS analysis of various kinds of samples. The possibility of correlating the ability of the metal ions to undergo X-ray induced reduction with their electrochemical reduction potentials is also highlighted.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Tensile properties of linear low density polyethylene (LLDPE) blown films

Rajendra K. Krishnaswamy、Mark J. Lamborn2000-11-01Polymer Engineering and Science

Abstract Various linear low‐density polyethylene (LLDPE; density ∼ (0.920 g/cm 3 )) resins that encompass those polymerized using Ziegler‐Natta, metallocene, and chromium oxide based catalysts were blown into film at similar process conditions, and the tensile properties of the resulting films were investigated in rel…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Thermodynamics of the R 3 to R 3 c phase transition in the ilmenite-hematite solid solution

R. J. Harrison、Udo Becker、Simon A. T. Redfern2000-11-01American Mineralogist

The thermodynamics of cation ordering in the ilmenite-hematite solid solution (FeTiO 3 )x(Fe 2 O 3 )1-x were re-examined in view of a recent in-situ neutron diffraction study of the R3̅ to R3̅ phase transition. A macroscopic thermodynamic model is developed, in which the excess enthalpy of ordering is described by a f…

Material Dynamics and PropertiesIron oxide chemistry and applicationsX-ray Diffraction in Crystallography