Materials Literature
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Molecular dynamics simulations on the Kremer-Grest bead-spring model of polymer melts are used to study the effect of spherical nanoparticles on chain diffusion. We find that chain diffusivity is enhanced relative to its bulk value when polymer-particle interactions are repulsive and is reduced when polymer-particle i…
Using ab initio thermodynamics we compile a phase diagram for the surface of Fe3O4(001) as a function of temperature and oxygen pressures. A hitherto ignored polar termination with octahedral iron and oxygen forming a wavelike structure along the [110] direction is identified as the lowest energy configuration over a…
A novel fabrication process was developed to create high aspect ratio (>10:1) carbon posts, all-carbon suspended bridges and wires, self-organized bunches of carbon posts, and carbon plates supported by carbon beams. The structures are all made from a two-step pyrolysis process with SU-8 photoresist as the starting ma…
One of the weakest components of modern transient simulation software is the transformer model. Many opportunities exist to improve the simulation of its complicated behaviors, which include magnetic saturation of the core, frequency-dependency, capacitive coupling, and topologically correctness of core and coil struc…
The limiting inclination angle (slip angle), for which a two-dimensional water drop may be at equilibrium on a chemically heterogeneous surface, is exactly calculated for a variety of cases. The main conclusion is that, in the cases studied, the contact angles at the upper and lower contact line do not always simultan…
Electron probe microanalysis (EPMA) of accessory minerals such as monazite, xenotime, and thorite for minor- and trace-element concentrations and geochronology, requires consideration of beam irradiation effects (increasing heat and charge) as higher current densities and lengthy counting times are employed, and requi…
When a thin glassy film is strained uniaxially, a shear deformation zone (SDZ) can be observed. The ratio of the thickness of the SDZ to that of the undeformed film is related to the maximum extension ratio, lambda, which depends on the entanglement molecular weight, M(e). We have measured lambda as a function of film…
ABSTRACT: The addition of plasticizers increases the flexibility and workability of films based on biopolymers. However, the use of some plasticizers cause undesirable results, such as the migration of these additives out the film or crystallization during shelf life. Thus, the aim of this study was to evaluate the ef…
Several common sources of discharges activity occurring on generators have been replicated in the laboratory under well-controlled conditions. Each source was evaluated individually and recorded with a phase resolved acquisition system and with a spectrum analyzer. The dominant features of each respective phase resolv…
Bionanoparticles, such as the cowpea mosaic virus, can stabilize oil droplets in aqueous solutions by self-assembly at liquid interfaces. Subsequent cross-linking of the bionanoparticles transforms the assemblies into robust membranes that have covalent inter-bionanoparticle connections. The resulting membranes are na…
There is growing interest in developing bio-based products and innovative process technologies that can reduce the dependence on fossil fuel and move to a sustainable materials basis. Biodegradable bio-based nanocomposites are the next generation of materials for the future. Renewable resource-based biodegradable poly…
Uniform gold hollow nanospheres with tunable interior-cavity sizes were fabricated by using Co nanoparticles as sacrificial templates and varying the stoichiometric ratio of starting material HAuCl4 over the reductants. The formation of these hollow nanostructures is attributed to two subsequent reduction reactions: t…
This is the first review of titanium dioxide‐zirconium dioxide (TiO2‐ZrO2) mixed oxides, which are frequently employed as catalysts and catalyst supports. In this review many details pertaining to the synthesis of these mixed oxides by various conventional and nonconventional methods and their characterization by seve…
A concise review is given of the progress made in the field of partial discharges (PD) at DC voltage. Although ample reference will be made to work of other authors in this field, the paper will concentrate on the progress that was made at Delft University of Technology over a period of 14 years in three PhD projects.…
Partial discharge (PD) detection, measurement and classification constitute an important tool for quality assessment of insulation systems utilized in HV power apparatus and cables. The patterns obtained with PD detectors contain characteristic features of the source/class of the respective partial discharge process i…
Functionalization of carbon nanotubes (CNTs) is important for enhancing deposition of metal nanoparticles in the fabrication of supported catalysts. A facile approach for oxidizing CNTs is presented using a sonochemical method to promote the density of surface functional groups. This was successfully employed in a pre…
We examine the shape memory effect in polymer networks intended for biomedical, and specifically cardiovascular, applications. The polymers were synthesized by photopolymerization from a tert-butyl acrylate monomer with a diethyleneglycol diacrylate crosslinker. Three-point flexural tests were used to systematically i…
We present a study on the electronic behavior of films of as-prepared and purified single-walled carbon nanotubes (SWNTs) and demonstrate the important role that chemical functionalization plays in modifying their electronic properties, which in turn throws further light on the mechanism of action of SWNT-based sensor…
Metamaterials (MTMs), which are formed by embedding inclusions and material components in host media to achieve composite media that may be engineered to have qualitatively new physically realizable response functions that do not occur or may not be easily available in nature, have raised a great deal of interest in r…
Metalloporphyrins are exceedingly useful building blocks for the design and synthesis of molecularly based solids. The use of hydrogen bonding or metal ion coordination provides a wide range of framework solids. Using various polyfunctionalized porphyrins, we have created porous solids that are thermally robust and th…