Materials Literature
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Infrared absorption spectra between 50 and 350 cm−1 have been obtained of argon matrices containing UO3 and UO2. The frequencies of all three expected low-frequency vibrational modes of U16O3 have been identified and measured (±0.1 cm−1): ?3(A1)=186.2, ?5(B1)=211.6, and ?6(B2)=151.5 cm−1. The effects of 18O-substituti…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structure of cofacial dicopper hexyldiporphyrin-7Marcos H. Hatada, A. Tulinsky, and C. K. ChangCite this: J. Am. Chem. Soc. 1980, 102, 23, 7115–7116Publication Date (Print):November 5, 1980Publication History Published online1 May 2002Published inissue…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTResponse of Catalyst Surface Concentrations to Forced Concentration Oscillations in the Gas Phase. The NO, CO, O2 System over Pt-AluminaL. Louis Hegedus, Charles C. Chang, David J. McEwen, and Elaine M. SloanCite this: Ind. Eng. Chem. Fundamen. 1980, 19, 4, 367–373Publicatio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdenum(V) tetraphenylporphyrin complexes revisited. Preparation and characterization of oxohydroxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V), O = Mo(TPP)OHHenry J. Ledon, Michel C. Bonnet, Yves Brigandat, and Francois VaresconCite this: Inorg. Chem. 1980, 19, 11,…
A scanning electron microscope investigation has been conducted on selected line-pipe steels that had been exposed to the hydrogen sulfide in the British Petroleum test. The results show that: (1) Hydrogen induced blister cracking initiates at elongated manganese sulfide inclusions confirming the findings of other wor…
Abstract In its present state this model should be effective as an aid in analyzing and optimizing cure cycles for vulcanizing articles. It is clearly necessary to have accurate thermo-physical data when simulating the SOC in thick articles. Additional improvements could be realized by more careful treatment of the he…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn efficient, high conversion photoinduced emulsion polymerization. Magnetic field effects on polymerization efficiency and polymer molecular weightNicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, and Chen-Ho TungCite this: J. Am. Chem. Soc. 1980, 102, 24, 7391–7393Publicat…
Young's modulus at room temperature and the fracture surface energy, up to 1200°C, were determined for boron carbide specimens with 0 to 15% porosity. Sonic modulus measurements indicated that the Young's modulus decreased as porosity increased in a manner characteristic of the cylindrical pore model. The fracture sur…
Abstract Interactions of lime, phosphorus (P), and zinc (Zn) in two coarse‐textured Ultisols from southeastern Nigeria were examined by means of factorial soil incubation and phosphate sorption experiments. In both soils, liming reduced exchangeable aluminum (Al) saturation from 45% to < 5% at pH 5.0 and soil solut…
The structure and inhibitive properties of benzotriazole on copper, copper-based alloys, silver, and other metals.
Kinetic studies on the thermal and oxidative decomposition of untreated cellulosic insulation have been carried out with thermal analytical techniques (TGA and DSC) to provide input parameters for smoldering studies of this material. In dry nitrogen, the weight loss proceeds in one overall step that follows a diffusio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExcess entropies and related quantities in glass-forming liquidsV. P. PrivalkoCite this: J. Phys. Chem. 1980, 84, 24, 3307–3312Publication Date (Print):November 1, 1980Publication History Published online1 May 2002Published inissue 1 November 1980https://pubs.acs.org/doi/10.…
Abstract— Carotenoid to porphyrin singlet‐singlet energy transfer has been observed in a new covalently linked carotenoid‐porphyrin ester. Nuclear magnetic resonance studies reveal that the relatively high energy transfer efficiency (˜ 25%) is a result of a stacked conformation in which the 26 π electron carotenoid ch…
The hydrogen storage compound LaNi 5 is an exchange-enhanced Pauli paramagnet with susceptibility chi (LaNi 5 )=4.6*10 -6 EMU g -1 . Hydrogen absorption leads to a decrease of the susceptibility of chi (LaNi 5 H 6.0 )=1.3*10 -6 EMU g -1 . This decrease is usually covered by a strong irreversible increase of surface ma…
Chemical and greenhouse studies were conducted to show that exchange acidity Y1, determined by titration of 125 ml of N KC1 soil extract (soil:N KC1 = 100:250) with 0.1 N NaOH, was a useful, realistic measure of aluminum toxicity potential in acid Andosols from northeastern Japan. Twenty-eight soil samples consisted o…
Based on accurate X-ray diffraction intensity data collected from spherically shaped single crystals, net atomic charges and electron density distributions have been studied for MnO, Mn2SiO4, Mg2Si2O6, LiAlSi2O6 and CaMgSi2O6. Examination of various procedures for determining atomic charges in a given structure has le…
The formation of chemically coprecipitated barium ferrite was studied using differential thermal analysis, static magnetic measurements, X‐ray analysis, and ferromagnetic resonance measurements. The investigation showed that the formation process of coprecipitated BaFe 12 O 19 differs significantly from that of conven…
It is shown that the infrared absorption band at 1230 cm−1, observed under certain conditions of oxygen precipitation in silicon, is the LO mode of SiO2. The LO mode, which is normally infrared inactive, becomes infrared active under the condition of polarization of small (&lt;0.36 μm) platelets in an appropriate…
Cross sections for electron capture from inner shells by fully stripped ions are calculated and compared with data for $K$-shell vacancy production. A procedure for inclusion of the relativistic effect is developed, and the scheme of calculations is illustrated through sample evaluations of electron-capture cross sect…
CaCI2.4H20, P2~/c, a = 6. 1387 (9), b = 7. 6669 (12), c -: 8 . 9014 (3 7) A, fl= 111.00(3) ° , V= 391 /k 3, Z = 2, d x = 1-55 Mg m -3. The Ca atoms are surrounded by two CI atoms and four water mole- cules. The cohesion between the CaCI2.4H20 oc- tahedra is achieved by hydrogen bonds. The final R value is 0.046.