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Surfactant free RGO/Pd nanocomposites as highly active heterogeneous catalysts for the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage

Pinxian Xi、Fengjuan Chen、Guoqiang Xie 等 10 位作者2012-01-01Nanoscale

In this study, monodisperse palladium (Pd) nanoparticles on reduced graphene oxide (RGO) surfaces were successfully prepared by a "wet" and "clean" method in aqueous solution. Without any surface treatment, Pd nanoparticles are firmly attached to the RGO sheets. These RGO/Pd nanocomposites exhibited catalytic activity…

Hydrogen Storage and MaterialsBoron and Carbon Nanomaterials ResearchAmmonia Synthesis and Nitrogen Reduction

Blue emitting gold nanoclusters templated by poly-cytosine DNA at low pH and poly-adenine DNA at neutral pH

Thomas Kennedy、James L. MacLean、Juewen Liu2012-01-01Chemical Communications

Blue fluorescent gold nanoclusters were prepared in the presence of poly-cytosine DNAs at low pH and poly-adenine at neutral pH using citrate as the reducing agent; various buffer conditions affecting the synthesis have been explored.

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Significant enhancement of blue emission and electrical conductivity of N-doped graphene

Tran Van Khai、Han Gil Na、Dong Sub Kwak 等 7 位作者2012-01-01Journal of Materials Chemistry

Nitrogen (N)-doped graphene with different atomic percentages (2.3–4.7 at%) of N has been synthesized by thermal annealing of reduced graphene oxide (RGO) in ammonia gas for different times. The effects of annealing time on the structure, electrical and optical properties of N-doped graphene have been systematically i…

Graphene research and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

A facile route for nitrogen-doped hollow graphitic carbon spheres with superior performance in supercapacitors

Fangwei Ma、Hui Zhao、Liping Sun 等 10 位作者2012-01-01Journal of Materials Chemistry

A novel template-free approach to prepare nitrogen-doped hollow carbon microspheres with graphitic carbon shells (NHGCSs) was reported. The obtained NHGCSs by the direct pyrolysis of solid melamine–formaldehyde (MF) resin spheres exhibit excellent capacitance performance. The specific capacitance reaches 306 F g−1 at…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Magnetism in gold nanoparticles

Gareth L. Nealon、Bertrand Donnio、Romain Gréget 等 6 位作者2012-01-01Nanoscale

Gold nanoparticles currently elicit an intense and very broad research activity because of their peculiar properties. Be it in catalysis, optics, electronics, sensing or theranostics, new applications are found daily for these materials. Approximately a decade ago a report was published with magnetometry data showing…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Microfluidic synthesis of multifunctional Janus particles for biomedical applications

Shikuan Yang、Feng Guo、Brian Kiraly 等 7 位作者2012-01-01Lab on a Chip

Multifunctional Janus particles have a variety of applications in a wide range of fields. However, to achieve many of these applications, high-throughput, low-cost techniques are needed to synthesize these particles with precise control of the various structural/physical/chemical properties. Microfluidics provides a u…

Innovative Microfluidic and Catalytic Techniques InnovationMicro and Nano RoboticsPickering emulsions and particle stabilization

Improving the Magnetic Resonance Imaging Contrast and Detection Methods with Engineered Magnetic Nanoparticles

Jing Huang、Xiaodong Zhong、Li‐Ya Wang 等 5 位作者2012-01-01Theranostics

Engineering and functionalizing magnetic nanoparticles have been an area of the extensive research and development in the biomedical and nanomedicine fields. Because their biocompatibility and toxicity are well investigated and better understood, magnetic nanoparticles, especially iron oxide nanoparticles, are better…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Current perspectives of nanoparticles in medical and dental biomaterials

Mohamed Ibrahim2012-01-01Journal of Biomedical Research

Nanotechnology is gaining tremendous impetus due to its capability of modulating metals into their nanosize, which drastically changes the chemical, physical and optical properties of metals. Nanoparticles have been introduced as materials with good potential to be extensively used in biological and medical applicatio…

Bone Tissue Engineering MaterialsNanoparticles: synthesis and applicationsNanotechnology research and applications

Fabrication of antibacterial silver nanoparticle—sodium alginate–chitosan composite films

Shilpa Sharma、Pallab Sanpui、Arun Chattopadhyay 等 4 位作者2012-01-01RSC Advances

A new and simple ecofriendly method for the synthesis of silver nanoparticles (Ag NPs) using a natural biopolymer, sodium alginate as both reducing and stabilizing agent is reported. The synthesized NPs were characterized using UV-Vis spectroscopy, transmission electron microscopy (TEM) and selected area electron diff…

Nanoparticles: synthesis and applicationsQuantum Dots Synthesis And PropertiesNanocomposite Films for Food Packaging

High capacity carbon dioxide adsorption by inexpensive covalent organic polymers

Hasmukh A. Patel、Ferdi Karadaş、Ali Canlier 等 8 位作者2012-01-01Journal of Materials Chemistry

Efficient CO2 scrubbing without a significant energy penalty remains an outstanding challenge for the fossil fuel-burning industry where aqueous amine solutions are still widely used. Porous materials have long been evaluated for next generation CO2 adsorbents. Porous polymers, robust and inexpensive, show promise as…

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture TechnologiesCovalent Organic Framework Applications

Macroporous ‘bubble’ graphene film via template-directed ordered-assembly for high rate supercapacitors

Cheng‐Meng Chen、Qiang Zhang、Chun‐Hsien Huang 等 10 位作者2012-01-01Chemical Communications

A three-dimensional bubble graphene film, with controllable and uniform macropores and tailorable microstructure, was fabricated by a facile hard templating strategy and exhibit extraordinary electrochemical capacitance with high rate capability (1.0 V s(-1)).

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Cyborg cells: functionalisation of living cells with polymers and nanomaterials

Rawil Fakhrullin、Alsu I. Zamaleeva、Renata T. Minullina 等 5 位作者2012-01-01Chemical Society Reviews

Living cells interfaced with a range of polyelectrolyte coatings, magnetic and noble metal nanoparticles, hard mineral shells and other complex nanomaterials can perform functions often completely different from their original specialisation. Such "cyborg cells" are already finding a range of novel applications in are…

Bone Tissue Engineering MaterialsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Energy storage in residential and commercial buildings via Liquid Organic Hydrogen Carriers (LOHC)

Daniel Teichmann、Katharina Stark、Karsten Müller 等 6 位作者2012-01-01Energy & Environmental Science

This contribution proposes the usage of Liquid Organic Hydrogen Carriers (LOHC) for the establishment of a decentralised energy storage network. Due to the continually increasing amount of renewable energy within the power grid, in particular in countries of the European Union, a huge demand for storage capacities dev…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Plasticity of metal nanowires

Christopher R. Weinberger、Wei Cai2012-01-01Journal of Materials Chemistry

The mechanisms of plasticity in metal nanowires with diameters below 100 nm are reviewed. At these length scales, plasticity in face-centered-cubic metals subjected to uniaxial loading is dominated by dislocation nucleation from free surfaces, which has been studied extensively by molecular dynamics. These simulations…

Microstructure and mechanical propertiesMetal and Thin Film Mechanicsnanoparticles nucleation surface interactions

Surfactant-assisted synthesis of CeO2 nanoparticles and their application in wastewater treatment

He Li、Guofeng Wang、Fei Zhang 等 6 位作者2012-01-01RSC Advances

The stable and crystalline phase of pure nanostructured CeO2 with various morphologies has been directly synthesized using a cationic surfactant (cetyltrimethylammonium bromide, CTAB) and cerium chloride (CeCl3·6H2O) at room temperature by a new, simple, and green chemical precipitation method. Thorough structural cha…

Catalytic Processes in Materials ScienceNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

Benzothiazolium-functionalized tetraphenylethene: an AIE luminogen with tunable solid-state emission

Na Zhao、Zhiyong Yang、Jacky W. Y. Lam 等 11 位作者2012-01-01Chemical Communications

Melding a benzothiazolium unit with tetraphenylethene generates a new hemicyanine luminogen with aggregation-induced emission characteristics; the luminogen exhibits crystochromism and its solid-state emission can be repeatedly tuned from yellow or orange to red by grinding-fuming or grinding-heating processes due to…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Supersensitive detection of explosives by recyclable AIE luminogen-functionalized mesoporous materials

Dongdong Li、Jianzhao Liu、Ryan T. K. Kwok 等 6 位作者2012-01-01Chemical Communications

Mesoporous SBA-15 functionalized with aggregation-induced emission (AIE) luminogens serves as an efficient and recyclable fluorescent sensor for the detection of picric acid (PA), with a quenching constant of up to 2.5 × 10(5) M(-1) in a water solution, presenting a new model for the supersensitive detection of explos…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Understanding the formation of CuS concave superstructures with peroxidase-like activity

Weiwei He、Huimin Jia、Xiaoxiao Li 等 9 位作者2012-01-01Nanoscale

Copper sulfide (CuS) concave polyhedral superstructures (CPSs) have been successfully prepared in an ethanolic solution by a simple solvothermal reaction without the use of surfactants or templates. Two typical well defined, high symmetry CuS concave polyhedrons, forming a concave truncated cuboctahedron and icosahedr…

Electrochemical sensors and biosensorsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Influence of pH on the fluorescence properties of graphene quantum dots using ozonation pre-oxide hydrothermal synthesis

Feng Yang、Meilian Zhao、Baozhan Zheng 等 6 位作者2012-01-01Journal of Materials Chemistry

Recent research into graphene-based materials is largely focused on graphene quantum dots (GQDs) and their optical properties. A facile method has been developed to extract GQDs from reduced graphene oxide (RGO) by the ozonation pre-oxide method. The as-prepared GQDs, which were 2–5 nm in diameter, exhibited strong fl…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Fluorescent carbon nanodots conjugated with folic acid for distinguishing folate-receptor-positive cancer cells from normal cells

Yanchao Song、Wen Shi、Wei Chen 等 5 位作者2012-01-01Journal of Materials Chemistry

In this work, an efficient approach for targeting and detecting cancer cells has been developed through the design of the assembly of fluorescent carbon nanodots and folic acid (C-dots–FA), which is endocytosible by the overexpressed folate receptor (FR) molecule. The fluorescent C-dots were prepared by a facile micro…

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications