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Collective and Individual Plasmon Resonances in Nanoparticle Films Obtained by Spin-Assisted Layer-by-Layer Assembly

Chaoyang Jiang、Sergiy Markutsya、Vladimir V. Tsukruk2003-12-30Langmuir

Nanoscale uniform films containing gold nanoparticle and polyelectrolyte multilayer structures were fabricated by the using spin-assembly or spin-assisted layer-by-layer (SA-LbL) deposition technique. These SA-LbL films with a general formula [Au/(PAH-PSS)nPAH]m possessed a well-organized microstructure with uniform s…

Polymer Surface Interaction StudiesNear-Field Optical MicroscopyMolecular Junctions and Nanostructures

Stability and electronic structure of AlN nanotubes

Mingwen Zhao、Yueyuan Xia、Dongju Zhang 等 4 位作者2003-12-30Physical review. B, Condensed matter

We predict the stability and electronic structure of aluminum nitride nanotubes based on calculations using density functional theory. The lower strain energy required in order to wrap up an AlN graphitic sheet into a tube and good thermal stability indicate the possibility for the formation of AlN nanotubes. All the…

MXene and MAX Phase MaterialsGaN-based semiconductor devices and materialsBoron and Carbon Nanomaterials Research

Predicted absence of ferromagnetism in manganese-doped diamond

Steven C. Erwin、C. Stephen Hellberg2003-12-30Physical review. B, Condensed matter

We use density-functional theoretical methods to examine the recent prediction, based on a mean-field solution of the Zener model, that diamond doped by Mn (with spin $S=5/2)$ would be a dilute magnetic semiconductor that remains ferromagnetic well above room temperature. Our findings suggest this to be unlikely, for…

ZnO doping and propertiesDiamond and Carbon-based Materials ResearchHigh-pressure geophysics and materials

Unexpected scaling of the performance of carbon nanotube Schottky-barrier transistors

Stefan Heinze、M. Radosavljević、J. Tersoff 等 4 位作者2003-12-30Physical review. B, Condensed matter

We show that carbon nanotube Schottky-barrier transistors exhibit scaling that is qualitatively different than conventional transistors. The performance depends in an unexpected way on both the thickness and the dielectric constant of the gate oxide. Experimental measurements and theoretical calculations for ambipolar…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchCarbon Nanotubes in Composites

Boehmite Derived γ-Alumina System. 1. Structural Evolution with Temperature, with the Identification and Structural Determination of a New Transition Phase, γ‘-Alumina

Gianluca Paglia、Craig E. Buckley、Andrew L. Rohl 等 8 位作者2003-12-30Chemistry of Materials

Variations in the structure of gamma-alumina (γ-Al 2 O 3 ), derived from well-crystalline boehmite, calcined at various temperatures in air were investigated. Consistent distribution of cation coordination, ∼69% octahedral and ∼31% tetrahedral, was observed for material calcined between 500 and 900 °C. Gamma alumina w…

Advanced ceramic materials synthesisMicrowave Dielectric Ceramics SynthesisFerroelectric and Piezoelectric Materials

New Heterogeneous Polyoxometalate Based Mesoporous Catalysts for Hydrogen Peroxide Mediated Oxidation Reactions

Maxym V. Vasylyev、Ronny Neumann2003-12-30Journal of the American Chemical Society

Inorganic-organic hybrid mesoporous materials were prepared by cocrystallization of a "sandwich" type polyoxometalate, [ZnWZn2(H2O)2(ZnW9O34)2]12-, and branched tripodal organic polyammonium salts, tris[2-(trimethylammonium)ethyl]-1,3,5-benzenetricarboxylate or 1,3,5-tris[4-(N,N,N-trimethylammoniumethylcarboxyl)phenyl…

Polyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions

Facile Synthesis and Characterization of Novel Mesoporous and Mesorelief Oxides with Gyroidal Structures

Bozhi Tian、Lanying Li、Leonid A. Solovyov 等 12 位作者2003-12-30OpenAlex

In this paper, we bring forward an effective strategy, solvothermal postsynthesis, to prepare ordered mesoporous silica materials with highly branched channels. Structural characterizations indicate that the titled mesoporous materials basically have the cubic double gyroidal (space group Ia-3d) structure with small f…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications

Creep Resistant Magnesium Alloys for Powertrain Applications

Mihriban Pekguleryuz、Ali Arslan Kaya2003-12-30OpenAlex

Abstract Creep resistant magnesium alloys are candidate materials for automotive powertrain applications. Since the 90's, a number of new creep‐resistant magnesium alloy systems have been investigated and developed. These are for the most part based on rare‐earth, alkaline earth, and silicon additions. This paper give…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesAluminum Alloy Microstructure Properties

Noninvasive Imaging of Quantum Dots in Mice

Byron Ballou、B. Christoffer Lagerholm、Lauren A. Ernst 等 5 位作者2003-12-30OpenAlex

Quantum dots having four different surface coatings were tested for use in in vivo imaging. Localization was successfully monitored by fluorescence imaging of living animals, by necropsy, by frozen tissue sections for optical microscopy, and by electron microscopy, on scales ranging from centimeters to nanometers, usi…

Advanced biosensing and bioanalysis techniquesAdvanced Biosensing Techniques and ApplicationsQuantum Dots Synthesis And Properties

A General Chemical Route to Polyaniline Nanofibers

Jiaxing Huang、Richard B. Kaner2003-12-30OpenAlex

Uniform polyaniline nanofibers readily form using interfacial polymerization without the need for templates or functional dopants. The average diameter of the nanofibers can be tuned from 30 nm using hydrochloric acid to 120 nm using perchloric acid as observed via both scanning and transmission electron microscopy. W…

Electrochemical sensors and biosensorsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Understanding Magnesium Corrosion—A Framework for Improved Alloy Performance

Guang‐Ling Song、Andrej Atrens2003-12-30OpenAlex

Abstract The purpose of this paper is to provide a succinct but nevertheless complete mechanistic overview of the various types of magnesium corrosion. The understanding of the corrosion processes of magnesium alloys builds upon our understanding of the corrosion of pure magnesium. This provides an understanding of th…

Magnesium Alloys: Properties and Applications

Stability of pre-tilt angle and polar anchoring strength and its impact on the performance of liquid crystal devices

Ruiqing Ma、Robert G. Lindquist、Daniel F. Acquard2003-12-29Optics Express

: In this paper, the optical performance degradation of a liquid crystal (LC) cell due to the instability of pre-tilt angle and polar anchoring strength of the alignment surface of liquid crystal devices is explored. Under accelerated thermal treatment, changes in both the pre-tilt angle and polar anchoring strength a…

Semiconductor Lasers and Optical DevicesPhotonic and Optical DevicesLiquid Crystal Research Advancements

Dielectric and spectral properties of DMAAS ferroelectric crystals doped with chromium

V. Kapustianik、Z. Czapla、R. Tchukvinskyi 等 7 位作者2003-12-29physica status solidi (a)

This paper presents the results of investigations of the dielectric and spectral properties of NH2(CH3)2Al(SO4)2 × 6 H2O crystals doped with chromium. In particular, it is shown that the dopant noticeably changes the temperature of ferroelectric phase transition and corresponding thermal dipole relaxation with a criti…

Solid-state spectroscopy and crystallographyLiquid Crystal Research AdvancementsNonlinear Optical Materials Research

Observation of backflow in the switch-on dynamics of a hybrid aligned nematic

S. A. Jewell、J. R. Sambles2003-12-29Applied Physics Letters

The optical convergent-beam technique is used to measure, in 0.3 ms steps, the response of the director in a 4.6-μm-thick ZLI-2293 filled hybrid aligned nematic cell when a 10 kHz, 7 Vrms ac voltage is applied to the cell. The total time taken for the reorientation process is 2.4 ms, with backflow observed during the…

Spectroscopy and Quantum Chemical StudiesNonlinear Dynamics and Pattern FormationLiquid Crystal Research Advancements

Crossover of Microscopic Dynamics in Metallic Supercooled Liquid Observed by NMR

Lilong Li、Jan Schroers、Yue Wu2003-12-29Physical Review Letters

Nuclear magnetic resonance is used to characterize local atomic motions in the glassy and supercooled liquid states of the bulk metallic glass system ${\mathrm{P}\mathrm{d}}_{43}{\mathrm{N}\mathrm{i}}_{10}{\mathrm{C}\mathrm{u}}_{27}{\mathrm{P}}_{20}$. The temperature dependence of the Knight shift reveals that certain…

Material Dynamics and PropertiesTheoretical and Computational PhysicsMetallic Glasses and Amorphous Alloys

Mixed Transition‐Metal—Lanthanide Complexes at Higher Oxidation States: Heteronuclear CeIV–MnIV Clusters

Anastasios J. Tasiopoulos、Ted A. O’Brien、Khalil A. Abboud 等 4 位作者2003-12-29Angewandte Chemie

Gutes Rad ist billig: Eine neue Familie gemischter CeIV-MnIV-Cluster mit Ce:Mn-Verhältnissen zwischen 3:2 und 1:6 wurde hergestellt. Das Bild zeigt den Kern des CeMn6-Komplexes (Ce grün, Mn blau, O rot). Alle Verbindungen weisen antiferromagnetische Wechselwirkungen zwischen den MnIV-Ionen auf.

Magnetism in coordination complexesInorganic Chemistry and MaterialsNanocluster Synthesis and Applications

Micrometer‐Sized Hexagonal Tubes Self‐Assembled by a Cyclic Peptide in a Liquid Crystal

Steve Leclair、Pierre Baillargeon、Rachid Skouta 等 6 位作者2003-12-29Angewandte Chemie

Gelöst in einer nematischen flüssigkristallinen Phase können starre scheibenförmige Makrolactame hexagonale Röhren bilden. Computermodelle (siehe Bild, O rot, N blau, C grau, H weiß), Raman- und IR-Mikrospektroskopie bringen eine hierarchische Selbstorganisation des Peptids in der flüssigkristallinen Phase zum Vorsche…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsLipid Membrane Structure and Behavior

Effects of some ionic substitutions on sintering, structure and humidity sensitivity of MgCu ferrite

N. Rezlescu、E. Rezlescu、Corina Sava 等 5 位作者2003-12-29physica status solidi (a)

The effect of Y3+, La3+, Ga3+, Ti4+ and Nb5+ ions on the physical properties of stoichiometric Mg0.5Cu0.5Fe2O4 ferrite is investigated. The substitutions partially replace the Fe3+ ions and the chemical formula of the investigated ferrites is Mg0.5Cu0.5Fe2−xMe3x/nO4, where Me = Y, La, Ga, Ti and Nb, x = 0 and 0.2, and…

Magneto-Optical Properties and ApplicationsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites