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Influence of lignin content on photodegradation in wood/HDPE composites under UV weathering

Kantima Chaochanchaikul、Krishnan Jayaraman、Vichai Rosarpitak 等 4 位作者2011-11-03BioResources

The aim of this work was to examine the influence the lignin component of wood on the photodegradation of high-density polyethylene (HDPE) in wood/HDPE (WPE) composites. The neat HDPE and wood/HDPE composites were prepared using a twin screw extruder followed by an injection moulder. The lignin content was varied from…

Wood Treatment and PropertiesNanocomposite Films for Food PackagingNatural Fiber Reinforced Composites

Band gap in graphene induced by vacuum fluctuations

O. V. Kibis、Oleksandr Kyriienko、I. A. Shelykh2011-11-03Physical Review B

The electrons in undoped graphene behave as massless Dirac fermions. Therefore, graphene can serve as a unique condensed-matter laboratory for the study of various relativistic effects, including quantum electrodynamics (QED) phenomena. Although theoretical models describing electronic properties of graphene have been…

Graphene research and applicationsQuantum and electron transport phenomenaQuantum Electrodynamics and Casimir Effect

Biodegradable Polymers Derived From Amino Acids

Wahid Khan、Muthupandian Saravanan、Shady Farah 等 5 位作者2011-11-03Macromolecular Bioscience

In the past three decades, the use of polymeric materials has increased dramatically for biomedical applications. Many α-amino acids derived biodegradable polymers have also been intensely developed with the main goal to obtain bio-mimicking functional biomaterials. Polymers derived from α-amino acids may offer many a…

biodegradable polymer synthesis and propertiesGraphene and Nanomaterials ApplicationsBiopolymer Synthesis and Applications

Surface Faceting Dependence of Thermal Transport in Silicon Nanowires

Frédéric Sansoz2011-11-03Nano Letters

Surface faceting on sidewalls is ubiquitously observed during crystal growth of semiconductor nanowires. However, predicting the thermal transport characteristics of faceted nanowires relevant to thermoelectric applications remains challenging. Here, direct molecular dynamics simulations show that thermal conductivity…

Advanced Thermoelectric Materials and DevicesNanowire Synthesis and ApplicationsThermal properties of materials

Tuning Size Scale and Crystallinity of PCL Electrospun Fibres via Solvent Permittivity to Address hMSC Response

Vincenzo Guarino、Valentina Cirillo、Paola Taddei 等 5 位作者2011-11-03Macromolecular Bioscience

The effect of solvent permittivity on the fibre morphology of PCL electrospun membranes for tissue engineering applications is studied. Morphological results indicate that polar solvents with higher permittivity are able to promote the formation of sub-micrometric fibres, while apolar solvents yield microfibres with a…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Self‐Healing of Chemical Gels Cross‐Linked by Diarylbibenzofuranone‐Based Trigger‐Free Dynamic Covalent Bonds at Room Temperature

Keiichi Imato、Masamichi Nishihara、Takeshi Kanehara 等 6 位作者2011-11-03Angewandte Chemie

Mit Diarylbibenzofuranon-Einheiten quervernetzte Polymere wurden durch Polyaddition synthetisiert. Der Bindungsaustausch der Gele und ihre makroskopische Selbstheilung wurden an Luft bei Raumtemperatur im Dunkeln erreicht. Die makroskopische Verbindung komplett getrennter Teile war erfolgreich (siehe Bild).

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingSupramolecular Self-Assembly in Materials

Electrical resistance measurement methods and electrical characterization of poly(3,4‐ethylenedioxythiophene)‐coated conductive fibers

Tariq Bashir、Lars Fast、Mikael Skrifvars 等 4 位作者2011-11-03Journal of Applied Polymer Science

Abstract Textile fibers and yarns of high conductivity, and their integration into wearable textiles for different electronic applications, have become an important research field for many research groups throughout the world. We have produced novel electrically conductive textile yarns by vapor‐phase polymerization (…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Silk‐Based Nanocomplexes with Tumor‐Homing Peptides for Tumor‐Specific Gene Delivery

Keiji Numata、Aneta J. Mieszawska‐Czajkowska、Laura A. Kvenvold 等 4 位作者2011-11-03Macromolecular Bioscience

Nanoscale complexes of recombinant silk molecules containing THPs with DNA are designed as less cytotoxic and highly target-specific gene carriers. Genetically engineered silk proteins containing poly(L-lysine) domains to interact with pDNA and the THP to bind to specific tumorigenic cells for target-specific pDNA del…

RNA Interference and Gene DeliveryAntimicrobial Peptides and ActivitiesSilk-based biomaterials and applications

Chemically Isolated Graphene Nanoribbons Reversibly Formed in Fluorographene Using Polymer Nanowire Masks

Woo-Kyung Lee、Jeremy T. Robinson、Daniel Gunlycke 等 7 位作者2011-11-03Nano Letters

We demonstrated the fabrication of graphene nanoribbons (GNRs) as narrow as 35 nm created using scanning probe lithography to deposit a polymer mask(1-3) and then fluorinating the sample to isolate the masked graphene from the surrounding wide band gap fluorographene. The polymer protected the GNR from atmospheric ads…

Graphene research and applicationsMolecular Junctions and NanostructuresNanowire Synthesis and Applications

A Photothermoelectric Effect in Graphene

Denis M. Basko2011-11-03Science

A curious response of graphene to light and heat may be useful for optoelectronic applications.

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced Memory and Neural Computing

Non-equilibrium cluster states in colloids with competing interactions

Tian Hui Zhang、Jan Klok、R. Hans Tromp 等 5 位作者2011-11-03Soft Matter

Cluster formation and gelation are studied in a colloidal model system with competing short-range attractions and long-range repulsions. In contrast to predictions by equilibrium theory, the size of clusters spontaneously formed at low colloidal volume fractions decreases with increasing strength of the short-range at…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Molecular Structure Encodes Nanoscale Assemblies: Understanding Driving Forces in Electrostatic Self-Assembly

Immanuel Willerich、Franziska Gröhn2011-11-03Journal of the American Chemical Society

Supramolecular nanoparticles represent a key field in recent research as their synthesis through self-assembly is straightforward and they often can respond to external triggers. A fundamental understanding of structure-directing factors is highly desirable for a targeted structure design. This contribution demonstrat…

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsDendrimers and Hyperbranched Polymers

Click Chemistry Finds Its Way into Covalent Porous Organic Materials

Thierry Müller、Stefan Bräse2011-11-03Angewandte Chemie International Edition

Click the CMPs and POPs: The Huisgen 1,3-dipolar cycloaddition reaction can be used to generate covalent porous organic materials such as conjugated microporous polymers (CMPs) and porous organic polymers (POPs). A triazole-linked network based on complementary tetrahedral monomers has been prepared by means of click…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesCovalent Organic Framework Applications

Role of Five-fold Twin Boundary on the Enhanced Mechanical Properties of fcc Fe Nanowires

J.-Y. Wu、Shijo Nagao、Jianying He 等 4 位作者2011-11-03Nano Letters

The role of 5-fold twin boundary on the structural and mechanical properties of fcc Fe nanowire under tension is explored by classical molecular dynamics. Twin-stabilized fcc nanowire with various diameters (6-24 nm) are examined by tension tests at several temperatures ranging from 0.01 to 1100 K. Significant increas…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsMicrostructure and Mechanical Properties of Steels

Stable fluorescent gold nanoparticles for detection of Cu 2+ with good sensitivity and selectivity

Yongming Guo、Zhuo Wang、Huawu Shao 等 4 位作者2011-11-03The Analyst

A simple and one-pot method for the synthesis of water-soluble, red-emitting, highly fluorescent gold nanoparticles has been reported using 11-mercaptoundecanoic acid (11-MUA) as the protecting group. We found that the fluorescent gold nanoparticles could selectively detect copper ions in aqueous solution, with a limi…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Residual Strain Dependence on Matrix Structure in RHQ-Nb3Al Wires by Neutron Diffraction Measurement

Xinzhe Jin、Tatsushi Nakamoto、Takayoshi Ito 等 10 位作者2011-11-03arXiv

We prepared three types of non-Cu RHQ-Nb3Al wire samples with different matrix structures: an all-Ta matrix,a composite matrix of Nb and Ta with a Ta inter filament, and an all-Nb matrix. Neutron diffraction patterns of the wire samples were measured at room temperature in J-PARC "TAKUMI". To obtain residual strains o…

Materials ScienceSuperconductivity

Phase stability and physical properties of Ta5Si3 compounds from first-principles calculations,

Xiaoma Tao、Philippe Jund、Catherine Colinet 等 4 位作者2011-11-03arXiv

We present a study of the thermodynamic and physical properties of Ta5Si3 compounds by means of density functional theory based calculations. Among the three different structures (D8m, D8l, D88), the D8l structure (Cr5B3-prototype) is the low temperature phase with a high formation enthalpy of -449.20kJ/mol, the D8m s…

Materials Science

Self-assembly into magnetic Co 3 O 4 complex nanostructures as peroxidase

Jiefu Yin、Huaqiang Cao、Yuexiang Lu2011-11-03Journal of Materials Chemistry

Here we reported on the synthesis and characterization of Co3O4 gillyflower-like nanostructures (termed as CGN) with peroxidase-like activity via an L-arginine-assisted hydrothermal synthesis approach. The CGN were characterized by a wide range of physicochemical characterization techniques. The temperature-dependence…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

Composites of Ultrahigh‐Molecular‐Weight Polyethylene with Graphene Sheets and/or MWCNTs with Segregated Network Structure: Preparation and Properties

Penggang Ren、Ying‐Ying Di、Qian Zhang 等 6 位作者2011-11-03Macromolecular Materials and Engineering

Abstract UHMWPE/MWCNT and UHMWPE/GNS composites with a segregated network are prepared. TEM and SEM images indicate that the conducting fillers are distributed on the UHMWPE surface and form a segregated conducting network. The percolation threshold of UHMWPE/GNS composites is ≈0.25 wt% and that of UHMWPE/MWCNT compos…

Carbon Nanotubes in CompositesGraphene research and applicationsConducting polymers and applications