Materials Literature
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This paper describes measurements of the dynamics of hot electron cooling in photoexcited gold nanoparticles (Au NPs) with diameters of ∼3.5 nm, and passivated with either a hexadecylamine or hexadecanethiolate adlayer, using ultrafast transient absorption spectroscopy. Fits of these dynamics with temperature-dependen…
Combined repeated-dose toxicity study of citrate-capped silver nanoparticles (7.9 ± 0.95 nm) with reproduction/developmental toxicity was investigated in rats orally treated with 62.5, 125 and 250 mg/kg, once a day for 42 days for males and up to 52 days for females. The test was performed based on the Organization fo…
The three-dimensional (3D) and two-dimensional (2D) chiral metamaterials (CMMs) have been proved to exhibit circular dichroism and circular conversion dichroism, respectively. The layer-by-layer chiral metamaterials, as a category of 3D CMMs, are expected to show the same properties as bulk 3D structures (e.g. helices…
We measure the Kapitza conductances at Au:Si contacts from 100 to 296 K via time-domain thermoreflectance. Contacts are fabricated by evaporating Au films onto Si substrates. Prior to Au deposition, the Si substrates receive pretreatments in order to modify interfacial properties, i.e., bonding and structural disorder…
Herein we report a detailed 1H and 17O relaxometric investigation of Mn(II) complexes with cyclen-based ligands such as 2-(1,4,7,10-tetraazacyclododecan-1-yl)acetic acid (DO1A), 2,2'-(1,4,7,10-tetraazacyclododecane-1,4-diyl)diacetic acid (1,4-DO2A), 2,2'-(1,4,7,10-tetraazacyclododecane-1,7-diyl)diacetic acid (1,7-DO2A…
Despite the fundamental nature and practical importance of melting, there is still no generally accepted theory of this ubiquitous phenomenon. Even the earliest simulations of melting of hard discs by Alder and Wainwright indicated the active role of collective atomic motion in melting and here we utilize molecular dy…
The phosphoric acid doped conductive polyaniline (PANI) polymer nanocomposites (PNCs) filled with silica nanoparticles (NPs) have been successfully synthesized using a facile surface initiated polymerization method. The chemical structures of the nanocomposites are characterized by Fourier transform infrared (FT-IR) s…
The co-assembly of spherical colloids and surfactant–cyclodextrin microtubes yields a library of dynamic colloid-in-tube structures, including helices. In situ observations of these structures, including their thermo-reversible assembly and disassembly, demonstrate the potential of the interplay between molecular and…
We demonstrate a full-color-capability reflective display using red, green, and blue sub-pixels of polymer-stabilized blue phase liquid crystal (BPLC) with different pitch lengths. Vivid colors originate from three-dimensional BPLC photonic crystalline structure. Surface alignment plays a key role to generate uniform…
Electro-caloric effect in 0.45BaZr0.2Ti0.8O3-0.55Ba0.7Ca0.3TiO3 single crystal has been investigated and electro-caloric coefficient of ∼0.38 K mm/kV has been obtained near the tetragonal-to-cubic phase transition. The value obtained is significantly higher than that for the lead-free ferroelectric materials reported…
The exploration of novel functional carbon polymorphs is an enduring topic of scientific investigations. In this paper, we present simulations demonstrating metastable carbon phases as the result of pressure induced carbon nanotube polymerization. The configuration, bonding, electronic, and mechanical characteristics…
In this work, we explore the thermal properties of hexagonal transition metal dichalcogenide compounds with different average atomic masses but equivalent microstructures. Thermal conductivity values of sputtered thin films were compared to bulk crystals. The comparison revealed a >10 fold reduction in thin fil…
This paper presents an efficient higher-order nonlocal beam theory for the thermal buckling of nanobeams. The displacement field is chosen based on assumptions that the in-plane and transverse displacements consist of bending and shear components, and the shear components of in-plane displacements give rise to the par…
Abstract Metal nanoparticles (MNPs) belong mostly to the engineered type of nanoparticles and have not only unique physical and chemical properties but also different biological actions. In recent years, noble MNPs and their nano-sized agglomerates (collectively referred to as nanoparticles or particles in the subsequ…
We numerically and experimentally investigated dual-band absorption of sandwich-structure metamaterials which include periodic metal coupled rings at the front separated from the metal plane at the back by a dielectric layer. The properties are demonstrated in both GHz and mid-IR regimes of electromagnetic (EM) wave.…
Abstract The mechanisms of stress corrosion cracking (SCC) and hydrogen embrittlement were recently reviewed by Lynch in this journal. The present review, in contrast, focuses on the rate-limiting step of the SCC of low-alloy high-strength steels in water and particularly focuses on the influence of the applied stress…
This work illustrates a strategy for the design of molecularly defined immunotherapies, using a blend of supramolecular peptide self-assembly and active site-directed protein capture.
This letter describes a chain-of-states method that optimizes reaction paths under the sole constraint of equally spaced structures. In contrast to NEB and string methods, it requires no spring forces, interpolation algorithms, or other heuristics to control structure distribution. Rigorous use of a quadratic PES allo…
A combined experimental and theoretical investigation of the electronic structure of the archetypal oxide heterointerface system LaAlO${}_{3}$ on SrTiO${}_{3}$ is presented. High-resolution, hard x-ray photoemission is used to uncover the occupation of Ti $3d$ states and the relative energetic alignment---and hence in…
We demonstrate the use of the micro-Brillouin light scattering (micro-BLS) technique as a local temperature sensor for magnons in a permalloy (Py) thin film and phonons in the glass substrate. When the Py film is uniformly heated, we observe a systematic shift in the frequencies of two thermally excited perpendicular…