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Materials Viewpoint of Organic Superconductors

Hatsumi Mori2006-05-12Journal of the Physical Society of Japan

Since the first discovery of an organic superconductor, TMTSF 2 PF 6 (TMTSF = tetramethyltetraselenafulvalene) with the superconducting transition temperature ( T c )=0.9 K under 12 kbar, by the suppression of spin density wave (SDW) state, approximately 120 organic superconductors have been found. Among them, the hig…

Organic and Molecular Conductors ResearchMagnetism in coordination complexesN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Experimental demonstration of a left-handed metamaterial operating at100GHz

Mutlu Gökkavas、Kaan Güven、İrfan Bulu 等 8 位作者2006-05-12Physical Review B

The existence of a left-handed (LH) transmission band in a bulk composite metamaterial (CMM) around $100\phantom{\rule{0.3em}{0ex}}\mathrm{GHz}$ is demonstrated experimentally. The CMM consists of stacked planar glass layers on which periodic patterns of micron-scale metallic wires and split-ring resonators are fabric…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesAntenna Design and Analysis

High-pressure x-ray diffraction study of Ta4AlC3

Bouchaib Manoun、Surendra K. Saxena、T. El‐Raghy 等 4 位作者2006-05-12Applied Physics Letters

Using a synchrotron radiation source and a diamond anvil cell, we measured the pressure dependence of the lattice parameters of a recently discovered phase, Ta4AlC3. This phase adopts a hexagonal structure with the space group P63∕mmc; at room conditions, the a and c parameters are 3.087(5) and 23.70(4)Å, respectively…

MXene and MAX Phase MaterialsMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

Electronic Phases in an Organic Conductor α-(BEDT-TTF)2I3: Ultra Narrow Gap Semiconductor, Superconductor, Metal, and Charge-Ordered Insulator

Naoya Tajima、Shigeharu Sugawara、Masafumi Tamura 等 5 位作者2006-05-12Journal of the Physical Society of Japan

We review the transport phenomena in an organic conductor α-(BEDT-TTF) 2 I 3 . It exhibits various types of transport depending on the circumstance in which it is placed. Under the ambient pressure, it is a charge-ordered insulator below 135 K. When high hydrostatic pressures are applied, it changes to a new type of n…

Perovskite Materials and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Dielectric Response of the Charge Ordered State in Quasi-One-Dimensional Organic Conductors

F. Ya. Nad、P. Monçeau2006-05-12Journal of the Physical Society of Japan

We present a survey of the recent experimental results which provide the evidence for the formation in quasi-one-dimensional (Q1D) conductors of a charge ordered (CO) state corresponding to an electronic 4 k F charge density wave. The main attention is paid to the study of the dielectric response of Q1D organic compou…

N-Heterocyclic Carbenes in Organic and Inorganic ChemistryMagnetism in coordination complexesOrganic and Molecular Conductors Research

Quantum distortion caused by magneto-elastic coupling for antiferromagnetic tetrahedral cluster of spin-1/2

Ikumi Honda、Kiyosi Terao2006-05-12arXiv

We study the effects of magneto-elastic coupling on the degenerate ground spin-state of the antiferromagnetic Heisenberg model on a regular tetrahedron of spin-1/2. When displacement of spin is considered as a classical variable, the degeneracy is lifted through the distance dependence of exchange coupling, i.e., a ki…

Materials Sciencecond-mat.other

Structural and magnetic properties of CoPt mixed clusters

Luc Favre、Véronique Dupuis、Estela Bernstein 等 10 位作者2006-05-12arXiv

In this present work, we report a structural and magnetic study of mixed Co58Pt42 clusters. MgO, Nb and Si matrix can be used to embed clusters, avoiding any magnetic interactions between particles. Transmission Electron Microscopy (TEM) observations show that Co58Pt42 supported isolated clusters are about 2nm in diam…

cond-mat.otherMaterials Science

Aggregation-enhanced luminescence and vibronic coupling of silole molecules from first principles

Shiwei Yin、Qian Peng、Zhigang Shuai 等 6 位作者2006-05-12Physical Review B

Aggregate formation in molecular solids usually quenches the luminescence, a piece of bad news for molecular electronic devices. However, siloles present extremely high luminescent efficiency in solid state as well as in aggregation, but have almost no luminescence in solution. By employing a first-principles calculat…

Photochemistry and Electron Transfer StudiesLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes Research

One-Pot Synthesis of New-Phase AgInSe2 Nanorods

Meng T. Ng、Chris Boothroyd、Jagadese J. Vittal2006-05-12Journal of the American Chemical Society

AgInSe2 nanorods with a previously unknown orthorhombic phase isostructural to AgInS2 have been prepared by the thermolysis of [(PPh3)2AgIn(SeC{O}Ph)4] in a mixture of oleylamine (OA) and dodecanethiol (DT) at 185 degrees C. A systematic study indicates that the ratio of surfactants is crucial for obtaining both monod…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+

Cai‐Feng Wang、Jing-Lin Zuo、Bart M. Bartlett 等 6 位作者2006-05-12Journal of the American Chemical Society

Reaction of [(Me3tacn)Cu(H2O)2]2+ (Me3tacn = N,N',N' '-trimethyl-1,4,7-triazacyclononane) with [TpFe(CN)3]- (Tp- = hydrotris(pyrazolyl)borate) in a mixture of ethanol and acetonitrile affords the pentanuclear cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+. Single-crystal X-ray analysis reveals a trigonal bipyramidal structure f…

Organic and Molecular Conductors ResearchLanthanide and Transition Metal ComplexesMagnetism in coordination complexes

Insights into the Fracture Mechanisms and Strength of Amorphous and Nanocomposite Carbon

Maria Fyta、Ioannis N. Remediakis、P. C. Kelires 等 4 位作者2006-05-12Physical Review Letters

Tight-binding molecular dynamics simulations shed light into the fracture mechanisms and the ideal strength of tetrahedral amorphous carbon and of nanocomposite carbon containing diamond crystallites, two of the hardest materials. It is found that fracture in the nanocomposites, under tensile or shear load, occurs int…

Advanced materials and compositesHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

A simple Lattice Model for hysteresis loops with exchange bias

Eduard Vives、Xavier Illa、Antoni Planes2006-05-12arXiv

A simple lattice model that allows hysteresis loops with exchange bias to be reproduced is presented. The model is based on the metastable Random Field Ising model, driven by an external field, with synchronous local relaxation dynamics. The key ingredient of the model is that a certain fraction $f$ of the exchange co…

Materials Science

Shifting donor-acceptor photoluminescence in N-doped ZnO

Takayuki Makino、A. Tsukazaki、A. Ohtomo 等 5 位作者2006-05-12arXiv

We have grown nitrogen-doped ZnO films grown by two kinds of epitaxial methods on lattice-matched ScAlMgO$_4$ substrates. We measured the photoluminescence (PL) of the two kinds of ZnO:N layers in the donor-acceptor-pair transition region. The analysis of excitation-intensity dependence of the PL peak shift with a flu…

Materials ScienceMesoscale and Nanoscale Physics

How ripples turn into dots: modeling ion-beam erosion under oblique incidence

Sebastian Vogel、Stefan J. Linz2006-05-12arXiv

Pattern formation on semiconductor surfaces induced by low energetic ion-beam erosion under normal and oblique incidence is theoretically investigated using a continuum model in form of a stochastic, nonlocal, anisotropic Kuramoto-Sivashinsky equation. Depending on the size of the parameters this model exhibits hexago…

cond-mat.stat-mechMaterials Science

Theoretical Aspects of Charge Ordering in Molecular Conductors

Hitoshi Seo、Jaime Merino、Hideo Yoshioka 等 4 位作者2006-05-12Journal of the Physical Society of Japan

Theoretical studies on charge ordering phenomena in quarter-filled molecular (organic) conductors are reviewed. Extended Hubbard models including not only the on-site but also the inter-site Coulomb repulsion are constructed in a straightforward way from the crystal structures, which serve for individual study on each…

N-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganic and Molecular Conductors ResearchMagnetism in coordination complexes

Domain wall dynamics in expanding spaces

F. J. Cao、E. Zamora-Sillero、N. R. Quintero2006-05-12arXiv

We study the effects on the dynamics of kinks due to expansions and contractions of the space. We show that the propagation velocity of the kink can be adiabatically tuned through slow expansions/contractions, while its width is given as a function of the velocity. We also analyze the case of fast expansions/contracti…

nlin.PSMaterials Science

Computer Simulations of Carbon Nanostructures under Pressure

Maria G. Fyta、Pantelis C. Kelires2006-05-12arXiv

Several interesting phenomena are observed when materials are put under pressure. The goal is to achieve modification and control over their mechanical and electronic (conduction) properties. Within this spirit, we have recently focused our attention into how carbon nanostructures respond to hydrostatic pressure. We p…

Materials Science

Multiphase region of helimagnetic superlattices at low temperature in an extended six-state clock model

D. C. Lovelady、H. M. Harper、I. E. Brodsky 等 4 位作者2006-05-12arXiv

The variety of magnetic phases observed in rare-earth heterostructures at low temperatures \cite{Jehan}, such as Ho/Y, may be elucidated by an ANNNI-like model Hamiltonian. In previous work modelling bulk Ho \cite{Seno}, such a Hamiltonian with a one-dimensional parameter space produced a single multiphase point. In c…

cond-mat.stat-mechMaterials Science

Temperature-Dependent Soft X-ray Photoemission and Absorption Studies of Charge Disproportionation in La1-xSrxFeO3

Hiroki Wadati、Akira Chikamatsu、Ryuji Hashimoto 等 10 位作者2006-05-12Journal of the Physical Society of Japan

We have measured the temperature dependence of the photoemission and x-ray absorption spectra of La$_{1-x}$Sr$_x$FeO$_3$ (LSFO) epitaxial thin films with $x=0.67$, where charge disproportionation ($3{Fe}^{3.67+}\to 2{Fe}^{3+}+ {Fe}^{5+}$) resulting in long-range spin and charge ordering is known to occur below $T_{CD}…

Advanced Condensed Matter PhysicsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Phase transitions and domain structures in strained pseudocubic (100)SrTiO3thin films

Yulan Li、Samrat Choudhury、J. H. Haeni 等 13 位作者2006-05-12Physical Review B

The mutual interactions between a structural transition and a ferroelectric transition are analyzed for different strain states in a pseudocubic (100) $\mathrm{Sr}\mathrm{Ti}{\mathrm{O}}_{3}$ film by examining the equilibrium solutions of the total free energy as a function of polarization, strain and structural order…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesMultiferroics and related materials