Materials Literature
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The current paper presents the first attempt to recreate the origin of shungite carbon at microscopic level basing on knowledge accumulated by graphene science. The main idea of our approach is that different efficacy of chemical transformation of primarily generated graphene flakes (aromatic lamellae in geological li…
Double-walled carbon nanotubes (DWCNT) are a rather new and unexplored variety of carbon nanotubes. Previously conducted studies established that exposure to a variety of carbon nanotubes produced lung inflammation and fibrosis in mice after pharyngeal aspiration. However, the bioactivity of double-walled carbon nanot…
( Na 0.52 K 0.4425 Li 0.0375 )( Nb 0.86 Ta 0.06 Sb 0.08 ) O 3 powders were synthesized via sol–gel and solid‐state reaction methods as a raw material for the preparation of the ceramics. Dependence of piezoelectric properties and microstructure on sintering temperatures was investigated in this study. Sol–gel‐derived…
Structural foams are a relatively new class of materials with peculiar characteristics that make them very attractive in some energy absorption applications. They are currently used for packaging to protect goods from damage during transportation in the case of accidental impacts. Structural foams, in fact, have suffi…
A physical model of solid–liquid expression from liquid containing plant materials is presented in one‐dimensional (1‐D) formulation. The layer of sliced cellular material is conceptualized as a double porosity system with extraparticle and intraparticle networks for liquid flow. Filtration‐consolidation equations wit…
In monolayer MoS2 optical transitions across the direct bandgap are governed by chiral selection rules, allowing optical valley initialization. In time resolved photoluminescence (PL) experiments we find that both the polarization and emission dynamics do not change from 4K to 300K within our time resolution. We measu…
Light-responsive materials formed by liquid crystalline lipids in water have potential application to drug delivery through inclusion of photochromic additives such as spiropyran. A series of novel analogues of spiropyran (SP) have been synthesized with an SP headgroup that possess a C8 (SP-OC), C12 (SP-L), and C16 (S…
NADPH-dependent acetoacetyl-coenzyme A (acetoacetyl-CoA) reductase (PhaB) is a key enzyme in the synthesis of poly(3-hydroxybutyrate) [P(3HB)], along with β-ketothiolase (PhaA) and polyhydroxyalkanoate synthase (PhaC). In this study, PhaB from Ralstonia eutropha was engineered by means of directed evolution consisting…
We report an exact analytical solution of so-called positron diffusion trapping model. This model have been widely used for the treatment of the experimental data for defect profiling of the adjoin surface layer using the variable energy positron (VEP) beam technique. Hovewer, up to now this model could be treated onl…
Atoms transferred to W(111) and W(110) tip apices from the Au(111) surface during tunneling and approach to mechanical contact experiments in STM are characterized in FIM at room temperature and at 158 K. The different activation energies for diffusion on the (111) and (110) tip planes and the experiment temperature a…
We assess the dependence on substrate dimensionality of the asymptotic scaling behavior of a whole family of equations that feature the basic symmetries of the Kardar-Parisi-Zhang (KPZ) equation. Even for cases in which, as expected from universality arguments, these models display KPZ values for the critical exponent…
We propose a feasible route to engineer one and two dimensional time reversal invariant (TRI) topological superconductors (SC) via proximity effects between nodeless extended s wave iron-based SC and semiconductors with large Rashba spin-orbit interactions. At the boundary of a TRI topological SC, there emerges a Kram…
We demonstrate the existence of topological superconductors (SC) protected by mirror and time reversal (TR) symmetries. D-dimensional (D=1,2,3) crystalline SCs are characterized by 2^(D-1) independent integer topological invariants, which take the form of mirror Berry phases. These invariants determine the distributio…
We introduce and investigate an effective five-band model for $t_{2g}$ and $e_g$ electrons to describe doped cobalt oxides with Co$^{3+}$ and Co$^{4+}$ ions in two-dimensional CoO$_2$ triangular lattice layers, as in Na$_{1-x}$CoO$_2$. The effective Hamiltonian includes anisotropic kinetic energy (due to both direct C…
Drug delivery systems (DDSs) offer efficient and localized drug transportation as well as reduce associated side effects. In order to better understand DDSs, precise observation of drug release and delivery is required. Here, we present a strategy, plasmonic-tunable Raman/fluorescence imaging spectroscopy, to track th…
In this paper, instabilities of the isotropic metallic phase in iron pnictides are investigated. The relevant quartic fermionic interaction terms in the model are identified using phase space arguments. Using the functional integral formalism, a Hubbard-Stratonovich transformation is used to decouple these quartic ter…
In the present study, we aimed to demonstrate that complexation reactions inside an inorganic water-filled nanopore can be enhanced at below the homogeneous nucleation temperature of bulk water (273 K). Using fluorescence experiments, we examined the inclusion complexation of propylamide coumarin 343 (PAC343) with γ-c…
The microscopic p K a of the pyridine N of the phosphate monoester 2‐pyridyl phosphate (MPP) is 2.76, significantly higher than that expected for the leaving group (RO) oxygen of a typical monoester ROPO 3 = . This favours the prototropic equilibrium considered to be the key step in the rapid hydrolysis of a typical m…
ABSTRACT Polymer–polymer materials consist of a thermoplastic matrix and a thermoplastic reinforcement. Recent research activities concentrate on the manufacturing of semi‐finished polymer–polymer materials in other shapes than the commercially available tapes and sheets. In particular, a pellet‐like form provides the…
Abstract Zinc sulfide (ZnS) semiconductor nanocrystals with mercaptoethanol (ME) as a stabilizer (capping agent) were synthesized by coprecipitation method in room temperature using the solution of zinc chloride (ZnCl 2 ) and sodium sulfide (Na 2 S) as starting material. The effect of ME and Na 2 S dropwise addition r…