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Spectral and thermal study of cured tetrafunctional epoxy-ester-amide polymeric framework

Jignesh P. Patel、P. H. Parsania2013-12-10Designed Monomers & Polymers

Tetrafunctional epoxy resin of bisphenol-C (EBCF) has been cured by various bisamic acids of anhydrides (tetrahydrophthalic anhydride, tetrachlorophthalic anhydride, and tertrabromophthalic anhydride) and diamines (4,4′-diaminodiphenylsulfone, 4,4′-diaminodiphenylether, and 4,4′-diaminodiphenyl methane) at 120 °C. Cur…

Polymer composites and self-healingEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Synthesis, Crystal Structure and Antitumor Activities of a New Cobalt-containing Tungstoantimonate Na9[{Na(H2O)2}3{Co(H2O)}3(α-B-SbW9O33)2]·28H2O

Rongxin Tan、Cheng Wang、Shuxin Cui 等 6 位作者2013-12-10Journal of Macromolecular Science Part A

A new cobalt-containing tungstoantimonate Na9[{Na(H2O)2}3{Co(H2O)}3(α-B-SbW9O33)2] · 28H2O 1 has been synthesized and characterized by elemental analysis, Infrared spectrum, UV-visible spectra, thermal gravimetric analysis and single-crystal X-ray analysis. Compound 1 crystallizes in monoclinic crystal system, space g…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Effect of DyF3 on the corrosion behavior of hot‐pressed Nd–Fe–B permanent magnets

Ralph Sueptitz、Simon Sawatzki、Martina Moore 等 6 位作者2013-12-10Materials and Corrosion

The grain boundary diffusion process (GBDP) with DyF 3 is a promising method to obtain excellent magnetic properties in Nd–Fe–B permanent magnets. Compared to conventionally prepared (Dy,Nd)–Fe–B magnets the overall content of the precious heavy rare earth Dy is reduced. Thus, the GBDP with DyF 3 is highly attractive…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Effects of Catalyst Concentration on the Morphology and Mechanical Properties of Polyisobutylene-based Thermoplastic Polyurethanes

Xinyu Wei、Priyank N. Shah、Kristóf Bagdi 等 5 位作者2013-12-10Journal of Macromolecular Science Part A

We studied the morphology and mechanical properties of a series of polyisobutylene-based thermoplastic polyurethanes (TPUs) with the same composition, but synthesized with tin (II) 2-ethylhexanoate catalyst concentrations ranging from 0.04 to 1 mol% relative to 4,4′-methylenebis(phenyl isocyanate) (MDI). All of the TP…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Spatially-Resolved Ultrafast Optical Spectroscopy of Polymer-Grafted Residues on CVD Graphene

Guannan Yu、Xinfeng Liu、Guichuan Xing 等 9 位作者2013-12-10The Journal of Physical Chemistry C

A recent report proved that polymer residues become grafted to graphene despite the efforts to clean the surface by thermal annealing [Lin, Y.-C., et al. Nano Lett. 2012, 12, 414]. Such residues inevitably originate from the photoresist (e.g., poly(methyl methacrylate) (PMMA)) used for graphene transfer and device pro…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Modulated fluorescence properties in fluorophore-containing gold nanorods@mSiO2

Xuejiao Tian、Jia Guo、Ye Tian 等 5 位作者2013-12-10RSC Advances

The influencing factors and mechanism of fluorescence enhancement or quenching in mesoporous nanocarriers consisting of gold nanorod cores and mesoporous silica shells (GNR@mSiO2) with controlled thicknesses were investigated. Mesoporous silica can act as a tool to change the distance between the fluorophores and GNRs…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Identification of Partial Discharge Location Using Probabilistic Neural Networks and the Fuzzy C-means Clustering Approach

Ju-Chu Hsieh、Cheng Chi Tai、Ming‐Shou Su 等 4 位作者2013-12-10Electric Power Components and Systems

This article proposes an approach for location of partial discharge sources in the power cable and gas-insulated load break switches using a probabilistic neural networks and the fuzzy C-means clustering approach. Three different defect positions are designed in the power cable and gas-insulated load break switches. T…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrical Fault Detection and Protection

Bilayers in nanoparticle-doped polar mesogens

Alexander Lorenz、Deña M. Agra-Kooijman、Natalie Zimmermann 等 6 位作者2013-12-10Physical Review E

Structures of the mesophases of five members of the 4-n-alkyl-4'-cyanobiphenyl homologous series (4-n-butyl-4'-cyanobiphenyl to 4-n-octyl-4'-cyanobiphenyl) doped with milled BaTiO_{3} nanoparticles were investigated by x-ray scattering. Clear solutions of each of the 4-n-alkyl-4'-cyanobiphenyls were first prepared in…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSurfactants and Colloidal Systems

A Mechanism for TiO2 Formation on Stepped TiN(001) from First-Principles Calculations

Minki Hong、Donghwa Lee、Simon R. Phillpot 等 4 位作者2013-12-10The Journal of Physical Chemistry C

The adsorption of O 2 on the TiN(001) stepped surface and the consequent formation of surface oxide have been characterized using first-principles calculations. The adsorption and dissociation of O 2 on both the flat and the stepped surface are predicted to be spontaneous. Compared with the flat surface, however, the…

Catalytic Processes in Materials ScienceMetal and Thin Film MechanicsMXene and MAX Phase Materials

Thermal conductivity and thermal stability enhancement of ethylene propylene diene methylene with carbon nanotube

Xiubin Zhang、Haiyan Zhang、Lin Jin 等 5 位作者2013-12-10Journal of Reinforced Plastics and Composites

In this article, the ethylene propylene diene methylene rubber composites filled with pretreated multi-walled carbon nanotubes were prepared by a double-roll milling dispersion method. The thermal and mechanical properties of the composites were measured and evaluated. The morphology of pretreated multi-walled carbon…

Carbon Nanotubes in CompositesThermal properties of materialsTribology and Wear Analysis

The morphing properties of a vascular shape memory composite

Pedro Cortes、John Charles Terzak、George D. Kubas 等 5 位作者2013-12-10Smart Materials and Structures

This work investigates the fabrication, experimentation, testing, and modeling of shape memory composites consisting of two-way shape memory alloy (SMA) tubes embedded in a shape memory polymer (SMP) matrix. The hybrid system here investigated is thermally activated via internal transport of thermal fluids through the…

Polymer composites and self-healingShape Memory Alloy TransformationsDielectric materials and actuators

Resistance of composite materials based on BaCeO3 against the corrosive effects of carbon dioxide and water vapour at intermediate fuel cell operating temperatures

Richard Gaweł、Kazimierz Przybylski、Massimo Viviani2013-12-10Journal of Thermal Analysis and Calorimetry

The objective of this work is to analyse the chemical stability of BaCe0.85Y0.15O3−δ –Ce0.85Y0.15O2−δ (BCY15–YDC15) composite materials at 600 °C and to compare the aforementioned chemical stability with that of pure BCY15. The composite powders were obtained by mixing together powders of BCY15 and YDC15 in the follow…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Plasmon-enhanced catalysis of photo-induced charge transfer from TCNQF 4 − to TCNQF 4 2−

Jing Wang、Weiqing Xu、Jinxia Wu 等 6 位作者2013-12-10Journal of Materials Chemistry C

The transformation from Ag-TCNQF <sub>4</sub> to Ag <sub>2</sub> -TCNQF <sub>4</sub> <italic>via</italic> photo-induced charge transfer under Au nanoparticles catalysis was monitored by Raman spectroscopy.

Porphyrin and Phthalocyanine ChemistryTransition Metal Oxide NanomaterialsOrganic and Molecular Conductors Research

Analysis of Cartilage-Polydioxanone Foil Composite Grafts

Brian J. F. Wong、James S. Kim2013-12-10Facial Plastic Surgery

This study presents an analytical investigation into the mechanical behavior of a cartilage-polydioxanone (PDS) plate composite grafts. Numerical methods are used to provide a first-order, numerical model of the flexural stiffness of a cartilage-PDS graft. Flexural stiffness is a measure of resistance to bending and i…

Osteoarthritis Treatment and MechanismsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Solid State 13C and 2H NMR Investigations of Paramagnetic [Ni(II)(acac)2L2] Complexes

Anders Lennartson、L. U. Christensen、Christine J. McKenzie 等 4 位作者2013-12-10Inorganic Chemistry

Nine structurally related paramagnetic acetylacetonato nickel(II) complexes: [Ni(acac)2] and trans-[Ni(acac)2(X)2]nH/D2O, X = H2O, D2O, NH3, MeOH, PMePh2, PMe2Ph, or [dppe]1/2, n = 0 or 1, dppe = 1,2-bis(diphenylphosphino)ethane, as well as cis-[Ni(F6-acac)2(D2O)2], F6-acac = hexafluoroacetylonato, have been character…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Sub-20 nm sandwich-structured NaGdF4:Yb/Tm@NaLuF4:Yb/Tm@NaYF4 nanocrystals for in vivo upconversion luminescence/computed tomography imaging

Jiwei Shen、Jianing Wang、DeLing KONG 等 4 位作者2013-12-10RSC Advances

Sub-20 nm sandwich-structured NaGdF4:Yb/Tm@NaLuF4:Yb/Tm@NaYF4 nanocrystals were fabricated for in vivo upconversion luminescence and computed tomography imaging.

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesAtomic and Subatomic Physics Research

Effect of modified nanofillers on fire retarded high-density polyethylene/wood composites

Zvonimir Katančić、Ljerka Kratofil Krehula、Anita Ptiček Siročić 等 5 位作者2013-12-10Journal of Composite Materials

In this study fire retarded HDPE/WF composites based on high density polyethylene (HDPE) and wood flour (WF) were investigated. Polymer and WF ratio was kept at 70/30 while concentration of fire retardant was 20 mass %. Ammonium polyphosphate and aluminum hydroxide were used as fire retardants. To diminish the influen…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFlame retardant materials and properties

Viscoelastic properties of syntactic foam reinforced with short sisal fibers

Ali Kadkhoda Ghamsari、Ephraim Zegeye、Eyassu Woldesenbet2013-12-10Journal of Composite Materials

Application of natural fibers has attracted a great deal of attention among the composite research community in the past couple of decades. In this study, sisal fiber was utilized in fabrication of syntactic foam to improve the mechanical properties. Four sets of samples with different volume fractions of sisal fibers…

Natural Fiber Reinforced CompositesCellular and Composite StructuresBamboo properties and applications

RSM Optimization of Plasma Initiated Grafting of Acrylic Acid onto Polypropylene Nonwoven

Aminoddin Hajı、Ahmad Mousavi Shoushtari、Majid Abdouss2013-12-10Journal of Macromolecular Science Part A

In this paper, the process of grafting of acrylic acid on the surface of polypropylene nonwoven using oxygen plasma treatment is studied and optimized. The response surface methodology (RSM) involving D-optimal criterion was used for the modeling and optimization of the process. The effect of plasma treatment time, pl…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Strengthening Mechanisms in MLCCs: Residual Stress Versus Crack Tip Shielding

Wade R. Lanning、Christopher L. Muhlstein2013-12-10Journal of the American Ceramic Society

Failure by fracture is a serious problem with multilayer ceramic capacitors (MLCCs), and the interior electrodes are known to strengthen MLCCs. Historically, it has been assumed that the dominant strengthening mechanism is crack tip shielding via direct crack tip‐electrode interactions. However, we have found that res…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisSemiconductor materials and devices