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第 157426 / 163740 页 · 当前展示 3,148,501–3,148,520 / 3,274,785 条匹配结果 · 摘要仅作预览

Synthesis, equilibrium and NMR studies of lanthanide(III) complexes of the N-mono(methylamide) and N ′-mono(methylamide) derivatives of diethylenetriamine-N,N,N ′,N ″,N ″-pentaacetic acid†

Lajos Sarka、István Bányai、Ernő Brücher 等 7 位作者2000-01-01Journal of the Chemical Society Dalton Transactions

Two derivative ligands of diethylenetriamine-N,N,N′,N′′,N′′-pentaacetic acid (H5DTPA; H5L1) were synthesized: the symmetric and asymmetric mono(methylamides) DTPA-N′-MA (H4L3) and DTPA-N-MA (H4L4). The protonation constants (log KiH) of L3 and L4 were obtained by pH-potentiometric titration: 10.04, 8.41, 2.73, 1.94 an…

Magnetism in coordination complexesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

The Influence of the Electronic Properties of Passive Films on the Corrosion Resistance of Mo-Ta Alloys A Photoelectrochemical Study

Monica Santamaria、D. Huerta、S. Piazza 等 5 位作者2000-01-01Journal of The Electrochemical Society

Photoelectrochemical experiments have been carried out for characterizing passive films on Mo‐Ta sputtered alloys having different compositions, as well as on pure Mo and Ta metals. Both corrosion layers, formed by simple immersion in solution, and films grown anodically were investigated. The presence of Mo species i…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Nonradiative dynamics of avalanche upconversion inTm:LiYF4

Markus P. Hehlen、A. Kuditcher、Alan Lenef 等 8 位作者2000-01-01Physical review. B, Condensed matter

In this paper we examine nonradiative processes (cross relaxation and energy migration) vital for the generation of blue avalanche emission in ${\mathrm{T}\mathrm{m}:\mathrm{L}\mathrm{i}\mathrm{Y}\mathrm{F}}_{4}$ crystals subjected to radiation near 648 nm. Time-domain and temperature-dependent measurements indicate t…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Role of NO 2 and SO 2 in degradation of limestone

G. C. Allen、A El-Turki、KR Hallam 等 5 位作者2000-01-01British Corrosion Journal

A UNESCO designated World Heritage Site, the city of Bath has many important listed buildings largely constructed of limestone from local quarries. Among present day atmospheric pollutants, SO2 is particularly damaging to calcareous stone, although its levels are decreasing with the use of low sulphur oil and coal, fl…

Gas Sensing Nanomaterials and SensorsCalcium Carbonate Crystallization and InhibitionBuilding materials and conservation

Crystal structures of intermetallic compounds

J. H. Westbrook、R. L. Fleischer2000-01-01Wiley eBooks

Contributors Preface to the 1995 Edition Preface to Reprint Volumes Acronyms Crystal Structure Nomenclature 1 Factors Governing Crystal Structures Pierre Villars 2 Close-Packed Structures Jurgen Hauck and Klaus Mika 3 Body-Centered Cubic Derivative Structures Erwin E. Hellner and Roland Schwarz 4 Wurtzite and Sphaleri…

Magnetic Properties of AlloysMineralogy and Gemology Studies

Self-polyaddition of hydroxyalkyl vinyl ethers

Hongmin Zhang、Eli Ruckenstein2000-01-01Journal of Polymer Science Part A Polymer Chemistry

With tetrahydrofuran as a solvent and pyridium p-toluenesulfonate as a catalyst, the hydroxyalkyl vinyl ethers 2-hydroxyethyl vinyl ether (2E), 4-hydroxybutyl vinyl ether (4B), and 6-hydroxyhexyl vinyl ether (6H) underwent step-growth self-polyaddition, generating polymers with an acetal main-chain structure. The mole…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Determination of activation energy and preexponential factor of thermoset reaction kinetics using differential scanning calorimetry in scanning mode: Influence of baseline shape on different calculation methods

Jérôme Dupuy、Eric Leroy、Abderrahim Maazouz2000-01-01Journal of Applied Polymer Science

Differential scanning calorimetry (DSC) is one of the most used methods for kinetic studies of thermoset cure reactions. The basic assumption made in this technique is the proportionality between the heat generation rate and cure reaction rate. To have access to the heat generation rate that provides information about…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersThermal and Kinetic Analysis

Development of Spherical Crystals of Acetylsalicylic Acid for Direct Tablet-making.

Hajnalka GOCZO、Piroska Szabó‐Révész、Béla Farkas 等 10 位作者2000-01-01Chemical and Pharmaceutical Bulletin

The production of spherical crystals has recently gained great attention due to the fact that the crystal habit (form, surface, size, etc.) can be modified during the crystallization process. Spherical crystals of ASA were developed by non-typical and typical spherical crystallization techniques. The non-typical spher…

Crystallization and Solubility Studies

A study of the blending of ethylene-styrene copolymers differing in the copolymer styrene content: Miscibility considerations

Y. Wilson Cheung、M. J. Guest2000-01-01Journal of Polymer Science Part B Polymer Physics

Blends of two or more ethylene–styrene (ES) copolymers that differed primarily in the comonomer composition of the copolymers were studied. Available thermodynamic models for copolymer–copolymer blends were utilized to determine the criteria for miscibility between two ES copolymers differing in styrene content and al…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

New polymeric biomaterials — phospholipid polymers with a biocompatible surface

Kazuhiko Ishihara2000-01-01Frontiers of Medical & Biological Engineering

New biomedical polymers were designed with attention to the surface of biological membranes, i.e. the surface was completely covered with phospholipid polar groups. The polymers with a phosphorylcholine group, 2-methacryloyloxyethyl phosphorylcholine (MPC) co-polymerized with hydrophobic alkyl group, could interact wi…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

X-Ray diffraction and spectroscopic studies of the light-induced metastable state of a ethylenediamine nitrosyl ruthenium complex

Masaki Kawano、Ayako Ishikawa、Yoshiyuki Morioka 等 6 位作者2000-01-01Journal of the Chemical Society Dalton Transactions

Blue-laser irradiation of a single crystal of the chloride salt of a cationic complex, trans-[Ru(en)2(H2O)(NO)]3+ (en = ethylenediamine), yielded MS1 (a metastable state of end-on type) which is remarkably stable (decay temperature Td = 267 K) compared with MS1 of sodium nitroprusside Na2[Fe(CN)5(NO)] (SNP). No MS2 st…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Numerical Modeling of Deflected Columnar Dendritic Grains Solidified in a Flowing Melt and Its Experimental Verification.

Sei‐Young Lee、S. M. Lee、C. P. Hong2000-01-01ISIJ International

A two-dimensional, coupled, cellular automaton-continuum model was developed to model the evolution of solidification grain structures and the deflection behavior of the columnar dendritic grains solidified in a flowing melt. Al-Cu alloys were solidified on an inclined Cu chill in order to investigate the deflection b…

Solidification and crystal growth phenomena

Lithium NMR in Lithium-Carbon Solid State Compounds

J. Conard、P. Lauginie2000-01-01TANSO

We present in this paper the main results of 7Li NMR on lithium intercalated in graphite, disordered pregraphitic cokes and other allotropic forms of hexagonal C-lattices like C60 and nanotubes. First we present the main parameters accessible by this technique when this new C-Li bonding is obtained, giving to the soli…

Advancements in Battery MaterialsGraphene research and applicationsAdvanced Battery Materials and Technologies

Sustained release of mitomycin-C from poly(DL-lactide)/poly(DL-lactide-co-glycolide) films

Menemşe Gümüşdereliogˇlu、Günday Deniz2000-01-01Journal of Biomaterials Science Polymer Edition

Mitomycin-C (MMC)-loaded poly(DL-lactide) (PLA)/poly(DL-lactide-co-glycolide) (PLGA) films which have different drug loading capacities and thicknesses were prepared by a solvent-evaporation technique. Degradation and release studies were conducted at 37 degrees C in pH 7.4 phosphate buffered saline. The results showe…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesAdvanced Drug Delivery Systems

Improvement of functional properties of jute-based composite by acrylonitrile pretreatment

Abir Saha、Shreya Das、Ratan Kumar Basak 等 5 位作者2000-01-01Journal of Applied Polymer Science

Cyanoethylation of jute fiber in the form of nonwoven fabric was successfully achieved using an acrylonitrile monomer which is said to react with the hydroxyl groups of fiber constituents. The degrees of cyanoethylation to different extents were undertaken by varying the reaction time. An IR study showed that extent o…

Natural Fiber Reinforced CompositesTextile materials and evaluations

G-quartets as a self-assembled scaffold for circular porphyrin arrays

Stefano Masiero、Giovanni Gottarelli、Silvia Pieraccini2000-01-01Chemical Communications

A new lipophilic guanosine carrying a porphyrin chromophore on the ribose moiety has been prepared: evidence is reported for the formation of a supramolecular complex based on G-quartets and containing an array of eight porphyrins.

Photosynthetic Processes and MechanismsMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Surface modification of polymers and improvement of the adhesion between evaporated copper metal film and a polymer. I. Chemical modification of PET

Eun Young Kim、Ju‐Shik Kong、Seung-Kook An 等 4 位作者2000-01-01Journal of Adhesion Science and Technology

To improve the interfacial adhesion between evaporated copper film and poly(ethylene terephthalate) (PET), the surface of PET films was modified by treating with hydrazine monohydrate. The effect of the treatment time in the range of 5-20 min with 80 wt% hydrazine monohydrate at 60 °C on the number of polar groups cre…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Oriented polyoxometalate–polycation multilayers on a carbon substrate

Shaoqin Liu、Zhiyong Tang、Zhenxin Wang 等 6 位作者2000-01-01Journal of Materials Chemistry

In this paper, a new method of fabricating multilayers on a carbon substrate is presented. First, a uniformly charged carbon surface was prepared through molecular design. Then an ultrathin film consisting of layer-pairs of oppositely charged polymeric cationic poly(diallyldimethylammonium chloride) (PDDA) and silicot…

Conducting polymers and applicationsPolymer Surface Interaction StudiesPolyoxometalates: Synthesis and Applications

EXAFS/XANES, chemisorption and IR investigations of colloidal Pt/Rh bimetallic catalysts

K. Siepen、H. B�nnemann、W. Brijoux 等 5 位作者2000-01-01Applied Organometallic Chemistry

Bimetallic Pt/Rh heterogeneous catalysts based on nanoscaled colloids supported on activated charcoal have been shown to exhibit maximum activity in hydrogenation of butyronitrile at a composition of 10 atom% Pt and 90 atom% Rh in the metallic core. This synergetic effect has to be traced back to the special structure…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Rheology in Plastics Quality Control

John M. Dealy、Peter C. Saucier2000-01-01OpenAlex

Rheology in plastics quality control , Rheology in plastics quality control , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی

Rheology and Fluid Dynamics StudiesMaterials Engineering and ProcessingPolymer Science and PVC