Materials Literature
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The relaxation behavior of poly(ethylene oxide) (PEO), intercalated in montmorillonite, a naturally occurring mica-type silicate, was studied by differential scanning calorimetry (DSC) and thermally stimulated dielectric depolarization (or thermally stimulated current, TSC). The materials were synthesized by melt or s…
The x-ray scattering from relaxed heteroepitaxial layers with the misfit dislocations randomly distributed at the interface between the layer and the substrate is analyzed theoretically and experimentally. The profiles of the x-ray-diffraction peaks and the reciprocal space maps of the intensity are measured and simul…
The orientation distribution of a textured polycrystalline material has been traditionally determined from a few individual pole figures of lattice planes hkl, measured by x-ray or neutron diffraction. A new method is demonstrated that uses the whole diffraction spectrum, rather than extracted peak intensities, by com…
Second harmonic generation in gallium-lanthanum-sulphide (Ga:La:S) and germanium sulphide + Ga:La:S glasses is investigated. It is shown that microcrystals of Ga:La:S and α phase of gallium-sulphide (α-Ga2S3), whose presence in the glass matrix is revealed by energy dispersive spectroscopy and x-ray diffraction analys…
We report on the observation of spin echo signals at the generalized Rabi frequency of a strongly driven two level system. The results are obtained for a radio-frequency transition of the nitrogen-vacancy center in diamond. A physical picture of the experiment is given in terms of the dressed-state basis, and the echo…
Nuclear magnetic resonance of Si29 is used to study structural properties of porous silicon and siloxene. Evidence for changes in the chemical shift of porous silicon due to quantum confinement could not be observed. A hydride phase exhibiting a chemical shift of −75 ppm versus tetramethyl silane (TMS) is found in bot…
Electron spin resonance (ESR) spectra at X-band microwave frequencies are reported for dopant ions in (CGGO), (SGGO), (LGGO) and (LGS). The ESR measurements identify two distinct sites for in CGGO and SGGO and a single site in LGGO and LGS characterized by spin S = 3/2 for ions in the ground state. In CGGO a sharp lin…
Mixed sesquioxides (x = 0.10, 0.20, 0.60, 1.00, 1.60 and 1.80) in the cubic (C) phase were obtained by precipitation and subsequent sintering. Cubic and were transformed into monoclinic (B) phases at 1400 K and 1600 K respectively. The transformation is reconstructive in character. All of the structures were refined u…
The ground-state electronic structures of ferromagnetic and antiferromagnetic perovskite in the ideal cubic phase have been investigated using the ab initio periodic Hartree - Fock approach. The system is a wide-gap insulator. The antiferromagnetic phase is correctly predicted to be the more stable (0.07 eV per Mn ato…
Zuwachs bei den Komplexen zweiwertiger 4f‐Elemente Waren bisher Eu II ‐Yb II ‐ und Sm II ‐Komplexe bekannt, so wurde nun erstmals auch ein Tm II ‐Komplex zugänglich. Die intensiv grüne Titelverbindung wurde durch Reaktion von TmI 3 mit Tm in Dimethoxyethan hergestellt. Der lichtempfindliche Komplex hat eine pentagonal…
The Jaccard theory of the electrical properties of ice includes a parameter , which relates the change in configurational entropy to the configuration vector . We show by an analytic mean-field type of calculation that , where a is the oxygen - oxygen separation. The Jaccard theory is then fully compatible with the ex…
Surface deformations appear in chalcogenide glasses when irradiated by scanned or pulsed electron beams accelerated at 10–30 kV. The deformation consists of a central expansion which accompanies peripheral depressions, and the scale is typically micrometer. The deformation seems to be produced by electrostatic force a…
(Ba,Sr)TiO3 films on a LaNiO3 underlayer were prepared by radio-frequency magnetron sputter deposition. The onset of crystallization of the films occurred at a deposition temperature (Td) as low as 200 °C. Good crystallinity was observed at Td⩾350 °C. A moderate high dielectric constant (εr∼170–250) of the films was o…
Using Monte Carlo simulations, we study the phase behaviour of systems with a short-ranged repulsive `shoulder' potential. In analogy to systems with a short-ranged attractive interaction, the shoulder potential leads to an isostructural solid - solid phase transition. We show that the range of interactions for which…
A theory for stable bubble oscillations in high pressure sound fields is presented. It is based on the strong influence of the surface tension on the dynamics of small bubbles and takes into account rectified diffusion and the resonancelike response of small bubbles to very strong acoustic pressure amplitudes. This th…
A technique of carbon film synthesis based on an electrochemical process was developed. A solution of acetylene in liquid ammonia was employed as the electrolyte. Films were deposited at the metallic anode. Two types of films were produced. Films of type I are transparent and fragile, whereas those of type II are blac…
Mass transport through surface electromigration strongly affects the stability and morphology of metal surfaces. Here the problem is treated within a continuum theory which takes full account of the nonlocal coupling between the electromagnetic bulk potential and the surface evolution. Key results of the numerical sol…
A textbook for the advanced undergraduate or graduate student beginning a serious study of X-ray crystallography. It will be of interest both to those intending to become professional crystallographers and to those physicists, chemists, biologists, geologists, metallurgists and others who will use it as a tool in thei…
Eine starke Excitonkopplung , die zur Aufspaltung der Soret‐Bande führt, und nur geringe spektroskopische Änderungen bezüglich der Q‐Bande deuten auf die senkrechte Anordnung der beiden Porphyrinringe im Dimer 1 hin. Diese Verbindung sowie die analogen linearen Tri‐ und Tetramere entstehen durch oxidative Kupplung des…
We examine the density-functional theory of macroscopic insulators, obtained in the large-cluster limit or under periodic boundary conditions. For polar crystals, we find that the two procedures are not equivalent. In a large-cluster case, the exact exchange-correlation potential acquires a homogeneous ``electric fiel…