Materials Literature
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Abstract Number‐ and weight‐average molecular weight of condensation polymers formed by primary molecules carrying different species of functional groups {A i } (i = 1, 2, …, s) are derived by cascade theory. These functional groups are allowed to form multiple junctions of variable multiplicity k . The gel point cond…
Abstract 3,3′‐Dinitrobenzidine was first reacted with excess m ‐chlorophenyl acid to form a monomer with dicarboxylic acid end groups. Two types of aromatic dianhydrides (Pyromellitic diconhydride (PMDA) and 3,3′,4,4′‐sulfonyl diphthalic anhydride) were also reacted with excess 4,4′‐diphenylmethane diisocyanate to for…
When producing (pressing) flax/PP composite panels, several processing parameters have to be considered. This paper describes how these parameters affect some properties of the resulting panel. The multidirectional flax/PP composite panels were made from needle-punched hybrid nonwovens. First the most appropriate proc…
Abstract The varying degree of preferential orientation observed in films of poly(alkylthiophene)s obtained by solution casting from different solvents has been studied quantitatively with X‐ray diffraction. The (uniaxial) orientational distribution function is obtained after some important instrumental corrections th…
The maximum of the color-conferring charge-transfer (CT) band in Prussian Blue (PB) varies with the electrochemically introduced cation M(z+) incorporated (as "supernumerary") for charge neutrality, and the dependence on particular properties of the M(z+) has been sought. With alkali-metal ions, the CT-maximum shifts…
We report results obtained from Monte Carlo simulations investigating mesophase formation in two model systems of hard pear-shaped particles. The first model considered is a hard variant of the truncated Stone-expansion model previously shown to form nematic and smectic mesophases when embedded within a 12-6 Gay-Berne…
The syntheses of two distinctive types of indium complex derived from trimethylindium (InMe(3)) are reported. The first kind has a generalized structural formula [InMe(2)(amak)](2), where (amak)H is an abbreviation for a series of chelating amino alcohol ligands HOC(CF(3))(2)CH(2)NHR, R = (CH(2))(2)OMe (1), Me (2), an…
Computer modeling techniques, which were employed to investigate the effect of water on the reactivity and stability of a SiO 2 nanotube, show that the side of the nanotube is relatively resistant to dissociative chemisorption and silicon dissolution but that the end of the nanotube is highly reactive toward water and…
Azamethine dyes of the merocyanine type [4-(N,N-di-n-butylamino)-2-methylphenyl][2,4-di-keto-3-[N'-(n-hexyl)]-5-cyano-6-methyl-3-pyridinio]-1-azamethine (1) and [4-(N,N-diethylamino)-2-(N'-tert-butylcarboxy)-amidophenyl]-[2,4-diketo-3-[N"-(n-hexyl)]-5-cyano-6-methyl-3-pyridinio]-1-azamethine (2) have been used as surf…
We performed molecular dynamics simulations of water confined to hydrophobic slit nanopores. Two five-site potential models of water were employed: the ST2 model and the TIP5P model. The simulations confirm our previous simulation results on basis of the four-site TIP4P model of water, that is, upon cooling the confin…
Depolymerization of an engineering plastic, poly(2,6-dimethyl-1,4-phenylene oxide) (PPO), was accomplished by using 2,6-dimethylphenol (DMP) under oxidative conditions. The addition of an excess amount of DMP to a solution of PPO in the presence of a CuCl/pyridine catalyst yielded oligomeric products. When PPO (M(n)=1…
Abstract A novel reactive flame retardant, (4‐diethoxyphosphoryloxyphenoxy)(4‐hydroxyphenoxy)cyclotriphosphazene (EPPZ), was prepared and characterized by FTIR, 31 P‐NMR, and 1 H‐NMR analyses. Polyurethanes that contain (aliphatic phosphate)cyclotriphosphazene, with various phosphorus contents, were prepared from EPPZ…
The electron transfer (ET) properties of a series of closely related cobalt porphyrins, [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]cobalt, CoF(28)TPP, [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenyl)porphyrinato]cobalt, CoF(8)TPP, 5,10,15,20-tetrakis(pentafluorophenyl)por…
Abstract In the first part of this series of articles, the relations between the foaming conditions and the microstructure of expanded polystyrene (EPS) were explored. In this part, the effects of the foaming conditions and the microstructure of EPS on impact properties are discussed. Regression analysis was conducted…
Direct templating with lyotropic liquid crystalline phases of nonionic surfactants has now been extended to fabricate mesoporous crystalline oxide semiconductors. ZnO and Cu 2 O films have been prepared on ITO-covered glass substrates by electrochemical deposition from lyotropic liquid crystalline phases with polyoxye…
The influence of the lanthanide ion and the chain length on the thermal properties of bis[2,3,9,10,16,17,23,24-octakis(alkoxy)phthalocyaninato]lanthanide(III) complexes, denoted in the following as [(C n H 2 n +1 O) 8 Pc] 2 Ln, have been investigated. Two series of complexes were considered: a first series in which th…
Biomimetic synthesis of biocompatible ceramic material, calcium hydroxyapatite Ca 10 (PO 4 ) 6 (OH) 2, was performed exclusively inside poly(allylamine)/poly(styrene sulfonate) polyelectrolyte capsules of micron scale. Calcium hydroxyapatite mainly forms on the inner side of the capsule shell resulting in empty compos…
Abstract In this study, processing‐structure relationships in expanded polystyrene (EPS) made using near‐critical carbon dioxide as a physical blowing agent were investigated. In order to investigate the relationship between structure and properties of EPS it was necessary to be able to make samples with a wide range…
Wide-angle X-ray scattering patterns from proteins in solution contain information relevant to the determination of protein fold. At relevant scattering angles, however, these data are weak, and the degree to which they might be used to categorize the fold of a protein is unknown. Preliminary work has been performed a…
Individual and thin bundles of aminopolymer-functionalized single-walled carbon nanotubes (SWNTs) were successfully imaged using high-resolution transmission electron microscopy (HR-TEM). The corresponding electron energy loss spectroscopy (EELS) characterization of the same TEM specimen before and after ex situ therm…