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Synthesis and properties of polypropylene/layered double hydroxide nanocomposites with different LDHs particle sizes

Lei Qiu、Yanshan Gao、Peng Lu 等 5 位作者2018-01-18Journal of Applied Polymer Science

ABSTRACT In order to investigate whether the particle sizes of inorganic additives in polymer have an influence on the flame‐retardant and other properties of the polymer, five types of Mg3Al–CO3 layered double hydroxide (LDHs) with particle diameters of 80–100, 200–350, 500–550, 550–600, and 700–900 nm were synthesiz…

Flame retardant materials and propertiesLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers

Large-area synthesis and photoelectric properties of few-layer MoSe 2 on molybdenum foils

Zenghui Wu、Guòan Tai、Xufeng Wang 等 6 位作者2018-01-18Nanotechnology

Abstract Compared with MoS 2 and WS 2 , selenide analogs have narrower band gaps and higher electron mobilities, which make them more applicable to real electrical devices. In addition, few-layer metal selenides have higher electrical conductivity, carrier mobility and light absorption than the corresponding monolayer…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Synthesis and Properties of Dithiafulvenyl Functionalized Spiro[fluorene-9,9′-xanthene] Molecules

Min Wu、Juan Li、Ruqin Zhang 等 9 位作者2018-01-18Organic Letters

Two spiroannulated molecular structures with dithiafulvenyl units functionalized at the 2,2',7,7'- (SFX-DTF1) and 2,3',6,'7- (SFX-DTF2) positions of a spiro[fluorene-9,9'-xanthene] core were synthesized. Studies revealed the hole mobility was significantly influenced by the dithiafulvenyl functionalized positions in t…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchOrganic Chemistry Cycloaddition Reactions

Polarization control using passive and active crossed graphene gratings

Jian Wei You、Nicolae C. Panoiu2018-01-18Optics Express

Graphene gratings provide a promising route towards the miniaturization of THz metasurfaces and other photonic devices, chiefly due to remarkable optical properties of graphene. In this paper, we propose novel graphene nanostructures for passive and active control of the polarization state of THz waves. The proposed d…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

All Roads Lead to TiO2: TiO2-Rich Surfaces of Barium and Strontium Titanate Prepared by Hydrothermal Synthesis

Lawrence A. Crosby、Bor-Rong Chen、Robert M. Kennedy 等 7 位作者2018-01-18Chemistry of Materials

Through high-resolution electron microscopy, the surface structure of barium titanate and strontium titanate nanoparticles are found to be terminated by a TiO 2 double layer. These results confirm prior observations of TiO 2 -rich surface reconstructions on strontium titanate nanoparticles made hydrothermally at high…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Ferroelectrics, multiferroics and artifacts: Lozenge-shaped hysteresis and things that go bump in the night

J. F. Scott、Jonathan Gardner2018-01-18Materials Today

This review summarizes dielectric studies and related experiments on ferroelectrics and multiferroics about which there has been considerable controversy in the literature, sometimes at unusually impolite and unprofessional levels. In addition it focuses attention on a new anomalous phenomenon – that of ferroelectric…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

“Deceived” Concentrated Immobilized Cells as Biocatalyst for Intensive Bacterial Cellulose Production from Various Sources

Nikolay Stepanov、Елена Ефременко2018-01-18Catalysts

A new biocatalyst in the form of Komagataeibacter xylinum B-12429 cells immobilized in poly(vinyl alcohol) cryogel for production of bacterial cellulose was demonstrated. Normally, the increased bacteria concentration causes an enlarged bacterial cellulose synthesis while cells push the polysaccharide out to pack them…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesEnzyme Production and Characterization

Flowerlike Organic–Inorganic Coating Responsible for Extraordinary Corrosion Resistance via Self-assembly of an Organic Compound

Wail Al Zoubi、Young Gun Ko2018-01-18ACS Sustainable Chemistry & Engineering

Organic–inorganic coating has been desirable for practical applications in electrochemistry and analytical science. Up to this investigation, a report of a “flowerlike” structure made from organic components has been rarely reported. Here, we proposed a novel strategy to fabricate the flowerlike hybrid coating through…

Electrocatalysts for Energy ConversionCorrosion Behavior and InhibitionFuel Cells and Related Materials

Embedded Multireference Coupled Cluster Theory

David J. Coughtrie、Robin Giereth、Daniel Kats 等 5 位作者2018-01-18Journal of Chemical Theory and Computation

Internally contracted multireference coupled cluster (icMRCC) theory is embedded within multireference perturbation theory (MRPT) to calculate energy differences in large strongly correlated systems. The embedding scheme is based on partitioning the orbital spaces of a complete active space self-consistent field (CASS…

Advanced Chemical Physics StudiesMagnetism in coordination complexesMolecular Junctions and Nanostructures

Tunable superconductivity by electrochemical intercalation in TaS2

Naihui Wang、Mengzhu Shi、Chao Shang 等 7 位作者2018-01-18New Journal of Physics

The controllable manipulation of materials properties has always attracted broad interests since there exists the possibility to identify the relationship between different electronic states, and even discover new states. Here we report the electrochemical intercalation of cetyltrimethylammonium (CTA + ) into 2H–TaS 2…

2D Materials and ApplicationsMolecular Junctions and NanostructuresIron-based superconductors research

Hydrothermal Synthesis of Hybrid Rod‐Like Hollow CoWO4/Co1−xS for High‐Performance Supercapacitors

Jinhua Ge、Jihuai Wu、Jia Dong 等 8 位作者2018-01-18ChemElectroChem

Abstract A rod‐like hollow cobalt tungstate/non‐stoichiometric cobalt sulfide (CoWO4/Co1−xS) hybrid is successfully grown in situ on nickel foam through a simple two‐step hydrothermal process. Owing to the unique hollow structure, the as‐synthesized CoWO4/Co1−xS hybrid electrode possesses a large surface area and deli…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Capped Polyoxometalate Pillars between Metal–Organic Layers for Transferring a Supramolecular Structure into a Covalent 3D Framework

Yujie Wang、Yangyang Zhou、Hongguo Hao 等 9 位作者2018-01-18Inorganic Chemistry

Two robust metal–organic frameworks (MOFs), {H 4 [Ni(π-H 2 O) 2 ] 2 [Ni(rt-H 2 O) 2 ] 8 Ni 4 (Tri) 24 }[V IV W 12 O 40 ] 2 ·24H 2 O ( 1 ) and {H[Ni(π-O) 2 ] 2 [Ni(rt-H 2 O) 2 ] 8 Ni 4 (Tri) 24 }[V IV W 10 V V 2 O 40 V 2 ][V IV W 9 V V 3 O 40 V IV 2 ]·24H 2 O ( 2 ) (Tri = 1,2,4-triazole), composed of polyoxometalates (…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Diversified Photo/Electronic Functions Based on a Simple Chalcone Skeleton: Effects of Substitution Pattern and Molecular Packing

Xiao Cheng、Zhao‐Yang Wang、Baolei Tang 等 9 位作者2018-01-18Advanced Functional Materials

Abstract Structurally simple chalcone derivatives 1–2 are prepared and their diversified emission behaviors are deeply investigated. Two polymorphs (1G: λem = 536 nm, Φf = 0.08, τ = 1.81 ns; 1O: λem = 573 nm, Φf = 0.19, τ = 10.82 ns) with distinctively different emission behaviors are constructed by finely controlling…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Comparative Study of the Characteristics of Green and Brown Coconut Fibers for the Development of Green Composites

María Guadalupe Lomelí-Ramírez、Raúl Rodríguez Anda、K. G. Satyanarayana 等 5 位作者2018-01-18BioResources

The growing consumption of tender coconut water in Brazil has resulted in a generation of green husk, which in turn has led to pollution, as it takes eight to ten years to degrade. With the objective of finding applications for these fibers, the characterization of their chemical composition, tensile properties, and s…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Josephson Thermal Memory

Claudio Guarcello、Paolo Solinas、Alessandro Braggio 等 5 位作者2018-01-18Physical Review Applied

The authors discuss a fast memory application based on thermal hysteresis in a magnetically driven superconducting quantum interference device (SQUID). Their theoretical exploration of the coherent thermal transport in an inductive temperature-biased SQUID reveals appreciable bistability of electrode temperature in th…

Physics of Superconductivity and MagnetismThermal properties of materialsThermal Radiation and Cooling Technologies

Controlling Sulfur Vacancies in TiS 2– x Cathode Insertion Hosts via the Conversion of TiS 3 Nanobelts for Energy-Storage Applications

Casey G. Hawkins、Luisa Whittaker‐Brooks2018-01-18ACS Applied Nano Materials

The electronic properties of titanium(IV) sulfide (TiS 2 ) have been scrutinized for many decades due to its strong tendency toward nonstoichiometry with either titanium excess or sulfur deficiency in its crystal structure. Here, the systematic solid-state transformation of TiS 3 to TiS 2– x nanobelts as a means to co…

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

Catalytic Properties of 3D Graphene-Like Microporous Carbons Synthesized in a Zeolite Template

Petr Sazama、Jana Pastvová、Cristina Rizescu 等 13 位作者2018-01-18ACS Catalysis

The inherent properties of a single atomic carbon layer in graphene offer opportunities for the creation of catalytically active centers tailored on a molecular level on a support with high thermal stability and very high specific surface area. We demonstrate that organization of the two-dimensional system of the carb…

Advancements in Battery MaterialsGraphene research and applicationsCovalent Organic Framework Applications

Wideband Frequency Scanning Spoof Surface Plasmon Polariton Planar Antenna Based on Transmissive Phase Gradient Metasurface

Hongya Chen、Hua Ma、Yongfeng Li 等 7 位作者2018-01-18IEEE Antennas and Wireless Propagation Letters

A novel design of spoof surface plasmon polariton (SSPP) planar antenna is proposed based on the wave vector modulation of transmissive phase gradient metasurface (TPGM). The antenna consists of TPGM placed a certain distance above SSPP guided wave structure, exhibiting the directional radiation property according to…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Polystyrene recycling processes by dissolution in ethyl acetate

Rafael Ferraz Cella、Guilherme Davi Mumbach、Karina Luzia Andrade 等 8 位作者2018-01-18Journal of Applied Polymer Science

ABSTRACT This study evaluated the thermal, morphological, chemical, and mechanical properties of virgin and recycled polystyrene. The recycling process was carried out by dissolution of polystyrene (extruded and crystal) in ethyl acetate, followed by two processes for solvent removal: vaporization by direct contact wi…

Polymer crystallization and propertiesRecycling and Waste Management TechniquesPolymer Science and PVC