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Highly efficient methane reforming over a low‐loading Ru/γ‐Al2O3 catalyst in a Pd‐Ag membrane reactor

David S. A. Simakov、Yuriy Román‐Leshkov2018-01-17AIChE Journal

Natural gas can be reformed to syngas (CH4 + H2O = CO + 3H2), at temperatures above 850°C. Membrane catalytic reformers can provide high CH4 conversions at temperatures below 650°C, by separating H2 from the reactive mixture. Traditional Ni‐based catalysts suffer from low activity at low temperatures and deactivate ra…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingAmmonia Synthesis and Nitrogen Reduction

Polystyrene-block-Poly(ionic liquid) Copolymers as Work Function Modifiers in Inverted Organic Photovoltaic Cells

Jong Baek Park、Mehmet Işık、Hea Jung Park 等 6 位作者2018-01-17ACS Applied Materials & Interfaces

Interfacial layers play a critical role in building up the Ohmic contact between electrodes and functional layers in organic photovoltaic (OPV) solar cells. These layers are based on either inorganic oxides (ZnO and TiO 2 ) or water-soluble organic polymers such as poly[(9,9-dioctyl-2,7-fluorene)- alt -(9,9-bis(3′-( N…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

Nanoprecipitation for Poorly Water-Soluble Drugs

Tuong Ngoc-Gia Nguyen、Van-Thanh Tran、Wei Duan 等 5 位作者2018-01-17Current Drug Metabolism

BACKGROUND: More than 60% of the active pharmaceutical ingredients, which are classified as Biopharmaceutics Classification System class II. The limited solubility of these drug may lead to low therapeutic effects. METHODS: Nanoprecipitation presents some advantages because it is a straightforward method with low-cost…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

PENGARUH PENAMBAHAN BATU KARANG SEBAGAI SUBSTITUSI AGREGAT HALUS DALAMPEMBUATAN PAVING BLOCK

Edy Gardjito、Agata Iwan Candra、Yosef Cahyo2018-01-17UKaRsT

AbstractMaterial exploitation, especially the use of sand as the main component of concrete, needs to be reduced. The purpose of this research is to find out the value of compressive strength from the addition of rocks to achieve compressive strength according to the standard mix design of paving blocks. This research…

Material Selection and PropertiesGeotechnical and construction materials studiesWaste Management and Recycling

Efficiency relationship between initiation of HNS-IV and nanosecond pulsed laser-driven flyer plates of layered structure

Wei Guo、Lizhi Wu、Nianbai He 等 7 位作者2018-01-17Laser and Particle Beams

Abstract Three types of multilayer flyer energy conversion elements (MFECEs) through integrating different laser pulse absorption/ablation layer of nano-film materials into a laser-driven flyer plates between thermal barrier of alumina and transparent substrate have been investigated in this study. The relationships a…

Diamond and Carbon-based Materials ResearchEnergetic Materials and CombustionLaser-induced spectroscopy and plasma

Control Method for Optimal Dynamic Performance of DTC-Based PMSM Drives

Yu Wang、Liang Geng、Wenjuan Hao 等 4 位作者2018-01-17IEEE Transactions on Energy Conversion

The direct torque control system has excellent dynamic performance of electromagnetic torque; however, the dynamic performance of the speed is affected by the proportional-integral parameters of the speed closed loop. Hence, a control method which can realize the optimal dynamic performance of the speed is investigate…

Electric Motor Design and AnalysisSensorless Control of Electric MotorsMagnetic Properties and Applications

Effect of TiO 2 Coating on Morphology of Active Phase on Sulfided CoMo/Al 2 O 3 Hydrotreating Catalysts

Thanh Tung Nguyen、Kazunari Imai、Jianglong Pu 等 4 位作者2018-01-17Energy & Fuels

A series of CoMo catalysts supported on various Al 2 O 3 supports added with TiO 2 were prepared to investigate the addition effect of TiO 2 on formation of an active phase on sulfided CoMo/Al 2 O 3 catalyst. The catalytic activity tests were carried out with hydrodesulfurization (HDS) of 4,6-dimethyldibenzothiophene,…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions

A Stable Room‐Temperature Luminescent Biphenylmethyl Radical

Xin Ai、Yingxin Chen、Yuting Feng 等 4 位作者2018-01-17Angewandte Chemie

Abstract There is only one family of room‐temperature luminescent radicals, the triphenylmethyl radicals, to date. Herein, we synthesize a new stable room‐temperature luminescent radical, (N‐carbazolyl)bis(2,4,6‐tirchlorophenyl)methyl radical (CzBTM), which has improved properties compared to the triphenylmethyl radic…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Phosphorus‐nitrogen compounds. Part 39. Syntheses and Langmuir‐Blodgett thin films and antimicrobial activities of N/N and N/O spirocyclotriphosphazenes with monoferrocenyl pendant arm

Nuran Asmafiliz、Mehmet Civan、Arda Özben 等 7 位作者2018-01-17Applied Organometallic Chemistry

The Cl substitution reactions of the N/N (1‐3) and N/O (4 and 5) spirocyclic monoferrocenylphosphazenes with 1,4‐dioxa‐8‐azaspiro[4,5]decane (DASD) produce the mono‐ (1a‐5a), geminal‐ (1b‐5b) and tetrakis‐DASD‐substituted ferrocenylspirocyclotriphosphazenes (1c‐5c). The mono‐ and geminal‐DASD‐substituted phosphazenes…

Metal complexes synthesis and propertiesFlame retardant materials and propertiesFerrocene Chemistry and Applications

On the Sustainability and Progress of Energy Neutral Mineral Processing

Frederik Reitsma、Peter Woods、Martin Fairclough 等 23 位作者2018-01-17Sustainability

A number of primary ores such as phosphate rock, gold-, copper- and rare earth ores contain considerable amounts of accompanying uranium and other critical materials. Energy neutral mineral processing is the extraction of unconventional uranium during primary ore processing to use it, after enrichment and fuel product…

Radioactive element chemistry and processingExtraction and Separation ProcessesGraphite, nuclear technology, radiation studies

Zeroth-Order-Mode Circular Microstrip Antenna With Patch-Like Radiation Pattern

Chaoqun Zhang、Jian‐Qiang Gong、Yuanxin Li 等 4 位作者2018-01-17IEEE Antennas and Wireless Propagation Letters

A zeroth-order-mode circular microstrip patch antenna is presented, consisting of two axial symmetrical semi-circulars and pins, which are in essential two composite right/lefthanded metamaterial unit cells. The patch-like radiation pattern was achieved for the zeroth-order mode by modifying the equivalent magnetic cu…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Three-dimensional cross-linking composite of graphene, carbon nanotubes and Si nanoparticles for lithium ion battery anode

Suyun Tian、Guannan Zhu、Yanping Tang 等 8 位作者2018-01-17Nanotechnology

Abstract Various graphene-based Si nanocomposites have been reported to improve the performance of active materials in Li-ion batteries. However, these candidates still yield severe capacity fading due to the electrical disconnection and fractures caused by the huge volume changes over extended cycles. Therefore, we h…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Phase microstructure evaluation and microwave dielectric properties of (1–x)Mg0.95Ni0.05Ti0.98Zr0.02O3–xCa0.6La0.8/3TiO3 ceramics

Abdul Manan、Zahid Ullah、Arbab Safeer Ahmad 等 7 位作者2018-01-17Journal of Advanced Ceramics

All the compositions in the (1−x)Mg0.95Ni0.05Ti0.98Zr0.02O3–xCa0.6La0.8/3TiO3 (0 ≤ x ≤ 0.2) series were fabricated using solid state sintering route. Mg0.95Ni0.05Ti0.98Zr0.02O3 possessed excellent microwave dielectric properties with ε r ≈ 17.1, Q u f0 ≈ 195855 GHz, and τ f ≈ -46 ppm/°C. τ f was tuned through zero by…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Double‐Emulsion‐Templated Anisotropic Microcapsules for pH‐Triggered Release

Bomi Kim、Sangmin Lee、Shin‐Hyun Kim2018-01-17Advanced Materials Interfaces

Abstract Biocompatible microcapsules with a function of pH‐triggered release are promising for the site‐specific release of bio‐actives in the human body. In this work, smart microcapsules with three distinct configurations of membranes are produced to control the rate of pH‐triggered release. The microcapsules are pr…

Advanced Polymer Synthesis and CharacterizationInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

KIX domain of AtMed15a, a Mediator subunit of Arabidopsis, is required for its interaction with different proteins

Vinay Kumar、Mohd Waseem、Nidhi Dwivedi 等 6 位作者2018-01-17Plant Signaling & Behavior

Med15 is an important subunit of Mediator Tail module and is characterized by a KIX domain present towards amino terminal. In yeast and metazoans, Med15 KIX domain has been found to interact with various transcription factors regulating several processes including carbohydrate metabolism, lipogenesis, stress response…

DNA Repair MechanismsPhotosynthetic Processes and MechanismsEnzyme Structure and Function

Emulsion Polymerization Mechanism

A.N. El-hoshoudy2018-01-17InTech eBooks

Emulsion polymerization is a polymerization process with different applications on the industrial and academic scale. It involves application of emulsifier to emulsify hydrophobic polymers through aqueous phase by amphipathic emulsifier, then generation of free radicals with either a water or oil soluble initiators. I…

Advanced Polymer Synthesis and CharacterizationInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

Performance evaluation of fixed‐bed, millistructured, and metallic foam reactor channels for CO2 methanation

Alain Bengaouer、Julien Ducamp、Isabelle Champon 等 4 位作者2018-01-17The Canadian Journal of Chemical Engineering

Abstract Power‐to‐gas technologies, combining hydrogen produced by water electrolysis with carbon dioxide to produce substitute natural gas (SNG), can support the increased penetration of renewable electricity sources. However, the technical and economic feasibility of these technologies requires the conversion effici…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Improving the Electrochemical Performance of Ni‐Rich LiNi0.8Co0.1Mn0.1O2 by Enlarging the Li Layer Spacing

Kang Wu、Guofeng Jia、Xuehui Shangguan 等 10 位作者2018-01-17Energy Technology

Abstract Ni‐rich cathode materials have high capacities but exhibit serious capacity attenuation. Therefore, a strategy for modifying a LiNi0.8Co0.1Mn0.1O2 cathode material by Na doping of the Li+ sites is proposed to improve its electrochemical performance. In this work, Li1−xNaxNi0.8Co0.1Mn0.1O2 (x=0, 0.01, 0.03) ma…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

High-Speed Spectroscopic Transient Absorption Imaging of Defects in Graphene

Kai‐Chih Huang、Jeremy McCall、Pu Wang 等 7 位作者2018-01-17Nano Letters

Graphene grain boundaries (GBs) and other nanodefects can deteriorate electronic properties. Here, using transient absorption (TA) microscopy we directly visualized GBs by TA intensity increase due to change in density of state. We also observed a faster decay due to defect-accelerated carrier relaxation in the GB are…

Graphene research and applicationsSpectroscopy Techniques in Biomedical and Chemical ResearchIntegrated Circuits and Semiconductor Failure Analysis

Dimensionality Driven Enhancement of Ferromagnetic Superconductivity in URhGe

D. Braithwaite、Dai Aoki、Jean‐Pascal Brison 等 7 位作者2018-01-17Physical Review Letters

In most unconventional superconductors, like the high-T_{c} cuprates, iron pnictides, or heavy-fermion systems, superconductivity emerges in the proximity of an electronic instability. Identifying unambiguously the pairing mechanism remains nevertheless an enormous challenge. Among these systems, the orthorhombic uran…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research