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A Unified Framework for Understanding the Structure and Modifications of Atomically Precise Monolayer Protected Gold Clusters

Ganapati Natarajan、Ammu Anna Mathew、Yuichi Negishi 等 5 位作者2015-11-06The Journal of Physical Chemistry C

Atomically precise monolayer protected clusters are molecules comprising a few-atom cluster core of a noble metal, typically Au or Ag, surrounded by a protective layer of ligands, exhibiting many special optical, electrical, catalytic, and magnetic properties, and are emerging as important materials in biology, medici…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Digital direct electron imaging of energy-filtered electron backscatter diffraction patterns

Stefano Vespucci、Aimo Winkelmann、G. Naresh‐Kumar 等 9 位作者2015-11-06Physical Review B

Electron backscatter diffraction is a scanning electron microscopy technique used to obtain crystallographic information on materials. It allows the nondestructive mapping of crystal structure, texture, and strain with a lateral and depth resolution on the order of tens of nanometers. Electron backscatter diffraction…

Particle Detector Development and PerformanceElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Ln12‐Containing 60‐Tungstogermanates: Synthesis, Structure, Luminescence, and Magnetic Studies

Kai‐Yao Wang、Bassem S. Bassil、Zhengguo Lin 等 11 位作者2015-11-06Chemistry - A European Journal

A new class of hexameric Ln12 -containing 60-tungstogermanates, [Na(H2 O)6 ⊂Eu12 (OH)12 (H2 O)18 Ge2 (GeW10 O38 )6 ](39-) (Eu12 ), [Na(H2 O)6 ⊂Gd12 (OH)6 (H2 O)24 Ge(GeW10 O38 )6 ](37-) (Gd12 ), and [(H2 O)6 ⊂Dy12 (H2 O)24 (GeW10 O38 )6 ](36-) (Dy12 ), comprising six di-Ln-embedded {β(4,11)-GeW10 } subunits was prepar…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Preparation of porous aromatic framework/ionic liquid hybrid composite coated solid-phase microextraction fibers and their application in the determination of organochlorine pesticides combined with GC-ECD detection

Ming‐Xue Wu、Gang Chen、Ping Liu 等 5 位作者2015-11-06The Analyst

A novel hybrid material incorporating porous aromatic frameworks and an ionic liquid, 1-(triethoxy silyl)propyl-3-aminopropyl imidazole hexafluorophosphate, was prepared as solid-phase microextraction coating and employed for the extraction of organochlorine pesticides. Combining the advantages of porous aromatic fram…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Responsive Aqueous Foams Stabilized by Silica Nanoparticles Hydrophobized in Situ with a Conventional Surfactant

Yue Zhu、Xiaomei Pei、Jianzhong Jiang 等 5 位作者2015-11-06Langmuir

In the recent past, switchable surfactants and switchable/stimulus-responsive surface-active particles have been of great interest. Both can be transformed between surface-active and surface-inactive states via several triggers, making them recoverable and reusable afterward. However, the synthesis of these materials…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Heteroepitaxial Cu2O thin film solar cell on metallic substrates

Sung Hun Wee、Po-Shun Huang、Jung‐Kun Lee 等 4 位作者2015-11-06Scientific Reports

Heteroepitaxial, single-crystal-like Cu2O films on inexpensive, flexible, metallic substrates can potentially be used as absorber layers for fabrication of low-cost, high-performance, non-toxic, earth-abundant solar cells. Here, we report epitaxial growth of Cu2O films on low cost, flexible, textured metallic substrat…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Dithiocarbamate RAFT agents with broad applicability – the 3,5-dimethyl-1H-pyrazole-1-carbodithioates

James Gardiner、Ivan Martinez‐Botella、John Tsanaktsidis 等 4 位作者2015-11-06Polymer Chemistry

The RAFT agents offer <italic>Đ</italic> &lt; 1.1 for MAMs, methyl acrylate (MA), <italic>N</italic> , <italic>N</italic> -dimethylacrylamide (DMA) and styrene, and <italic>Đ</italic> &lt; 1.3 for LAMs, vinyl acetate (VAc); versatility and end-group fidelity was proved with synthesis both polyDMA- <italic>block</itali…

Advanced Polymer Synthesis and CharacterizationChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

Work production using the two-way shape memory effect in NiTi and a Ni-rich NiTiHf high-temperature shape memory alloy

K.C. Atli、İbrahim Karaman、R.D. Noebe 等 5 位作者2015-11-06Smart Materials and Structures

The work output capacity of the two-way shape memory effect (TWSME) in a Ni 50.3 Ti 29.7 Hf 20 (at%) high-temperature shape memory alloy (HTSMA) was investigated and compared to that of binary Ni 49.9 Ti 50.1 (at%). TWSME was induced through a training procedure of 100 thermomechanical cycles under different tensile s…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsCreativity in Education and Neuroscience

Surface Charge Transfer Doping of Monolayer Phosphorene via Molecular Adsorption

Yuanyuan He、Feifei Xia、Zhibin Shao 等 5 位作者2015-11-06The Journal of Physical Chemistry Letters

Monolayer phosphorene has attracted much attention owing to its extraordinary electronic, optical, and structural properties. Rationally tuning the electrical transport characteristics of monolayer phosphorene is essential to its applications in electronic and optoelectronic devices. Herein, we study the electronic tr…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Self-Powered, High-Speed and Visible–Near Infrared Response of MoO3–x/n-Si Heterojunction Photodetector with Enhanced Performance by Interfacial Engineering

Chuanxi Zhao、Zhimin Liang、Mingze Su 等 6 位作者2015-11-06ACS Applied Materials & Interfaces

Photodetectors with a wide spectrum response are important components for sensing, imaging, and other optoelectronic applications. A molybdenum oxide (MoO(3-x))/Si heterojunction has been applied as solar cells with great success, but its potential in photodetectors has not been explored yet. Herein, a self-powered, h…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Electron beam and gamma ray irradiated polymer electrolyte films: Dielectric properties

Srinivas Raghu、K. Archana、Sharanappa Chapi 等 5 位作者2015-11-06Journal of Radiation Research and Applied Sciences

In this study, polymer electrolyte films were irradiated with electron beam (EB) and Gamma ray (GR) at 50 and 150 kGy. The induced chemical changes in films due to irradiations have been confirmed from the Fourier Transform Infra red (FT-IR) spectra. The X-ray Diffractometry (XRD) results show that crystallinity decre…

Advanced Battery Materials and TechnologiesConducting polymers and applicationsPolymer Nanocomposite Synthesis and Irradiation

Phase separation of full-Heusler nanostructures in half-Heusler thermoelectrics and vibrational properties from first-principles calculations

Alexander Page、Ctirad Uher、Pierre F. P. Poudeu 等 4 位作者2015-11-06Physical Review B

Previous studies have indicated that the figure of merit ($\mathit{ZT}$) of half-Heusler (HH) alloys with composition $M\mathrm{NiSn}$ ($M\phantom{\rule{0.16em}{0ex}}=\phantom{\rule{0.16em}{0ex}}\mathrm{Ti}$, Zr, or Hf) is greatly enhanced when the alloys contain a nano-scale full-Heusler (FH) $\mathrm{MN}{\mathrm{i}}…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic properties

Smooth Optimal Quantum Control for Robust Solid-State Spin Magnetometry

Tobias Nöbauer、Andreas Angerer、Björn Bartels 等 8 位作者2015-11-06Physical Review Letters

We experimentally demonstrate a simple yet versatile optimal quantum control technique that achieves tailored robustness against qubit inhomogeneities and control errors while requiring minimal bandwidth. We apply the technique to nitrogen-vacancy (NV) centers in diamond and verify its performance using quantum proces…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Atomic Resolution Observation of a Size-Dependent Change in the Ripening Modes of Mass-Selected Au Nanoclusters Involved in CO Oxidation

Kuo‐Juei Hu、Simon R. Plant、Peter Ellis 等 6 位作者2015-11-06Journal of the American Chemical Society

Identifying the ripening modes of supported metal nanoparticles used in heterogeneous catalysis can provide important insights into the mechanisms that lead to sintering. We report the observation of a crossover from Smoluchowski to Ostwald ripening, under realistic reaction conditions, for monomodal populations of pr…

Catalytic Processes in Materials ScienceCatalysis and Oxidation Reactionsnanoparticles nucleation surface interactions

Thermoelectric Properties of Transition Metal Dichalcogenides: From Monolayers to Nanotubes

Kaixuan Chen、Xiaoming Wang、Dong-Chuan Mo 等 4 位作者2015-11-06The Journal of Physical Chemistry C

Thermoelectric material has the unique ability to directly convert waste heat into electricity, and theoretical guidance is an efficient method for exploring high-performance nanostructured thermoelectric materials. By using first-principles method, we systematically present the ballistic thermoelectric properties of…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Designed Synthesis of van der Waals Heterostructures: The Power of Kinetic Control

Matti B. Alemayehu、Matthias Falmbigl、Kim Ta 等 6 位作者2015-11-06Angewandte Chemie International Edition

Selecting specific 2D building blocks and specific layering sequences of van der Waals heterostructures should allow the formation of new materials with designed properties for specific applications. Unfortunately, the synthetic ability to prepare such structures at will, especially in a manner that can be manufacture…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Enhanced Carrier Transport Distance in Colloidal PbS Quantum-Dot-Based Solar Cells Using ZnO Nanowires

Haibin Wang、Victoria González‐Pedro、Takaya Kubo 等 8 位作者2015-11-06The Journal of Physical Chemistry C

Nanostructured solar cells are a promising area of research for the production of low cost devices that may eventually be capable of complementing or even replacing present technologies in the field of solar power generation. The use of quantum dots (QDs) in solar cells has evolved from being simple absorbers in dye-s…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Thermodynamic synthesis of solution processable ladder polymers

Jongbok Lee、Bharath Bangalore Rajeeva、Tianyu Yuan 等 8 位作者2015-11-06Chemical Science

C isotope-enriched product revealed that the main-chain contained less than 1% of unreacted precursory vinyl groups. The rigid conformation of the ladder-type backbone was confirmed by photophysical analysis, while the extended rod-like structure was visualized under scanning tunneling microscope. Excellent solubility…

Organic Electronics and PhotovoltaicsAdvanced Polymer Synthesis and CharacterizationSynthesis and properties of polymers

Smart Mesoporous Nanomaterials for Antitumor Therapy

Marina Martínez‐Carmona、Montserrat Colilla、María Vallet‐Regí2015-11-06Nanomaterials

The use of nanomaterials for the treatment of solid tumours is receiving increasing attention by the scientific community. Among them, mesoporous silica nanoparticles (MSNs) exhibit unique features that make them suitable nanocarriers to host, transport and protect drug molecules until the target is reached. It is pos…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Ligand-Mediated “Turn On,” High Quantum Yield Near-Infrared Emission in Small Gold Nanoparticles

Scott Crawford、Christopher M. Andolina、Ashley M. Smith 等 8 位作者2015-11-06Journal of the American Chemical Society

Small gold nanoparticles (∼1.4-2.2 nm core diameters) exist at an exciting interface between molecular and metallic electronic structures. These particles have the potential to elucidate fundamental physical principles driving nanoscale phenomena and to be useful in a wide range of applications. Here, we study the opt…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis