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A new analytical approach based on asymmetrical flow field-flow fractionation coupled to ultraviolet spectrometry and light scattering detection for SWCNT aqueous dispersion studies

Julien Gigault、Bruno Grassl、Gaëtane Lespès2011-12-20The Analyst

This work demonstrates the potential of asymmetrical flow field-flow fractionation (A4F) coupled to Ultraviolet spectrometry (UV) and multi-angle light scattering (MALS) for the study of single-walled carbon nanotube (SWCNT) dispersion in aqueous solutions containing a surfactant. The results indicate that this techni…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesField-Flow Fractionation Techniques

Moderate sodium has positive effects on shoots but not roots of salt-tolerant barley grown in a potassium-deficient sandy soil

Qifu Ma、R.W. Bell、Ross Brennan2011-12-20Australian Journal of Agricultural Research

In the agricultural lands of south-western Australia, salinity severely affects about 1 million hectares, and there is also widespread occurrence of potassium (K) deficiency. This study investigated whether the effects of sodium (Na) on crop K nutrition vary with plant salt sensitivity. In a glasshouse experiment with…

Soil and Unsaturated FlowPlant nutrient uptake and metabolismClay minerals and soil interactions

Polyoxometalate-directed assembly of water-soluble AgCl nanocubes

Alevtina Neyman、Yifeng Wang、Shelly Sharet 等 8 位作者2011-12-20Chemical Communications

"Out-of-pocket" association of Ag(+) to the tetradentate defect site of mono-vacant Keggin and Wells-Dawson polyoxometalate (POM) cluster-anions is used to direct the formation of water-soluble AgCl nanocubes.

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsAdvanced Nanomaterials in Catalysis

Fabrication of Metal-Semiconductor Interface in Porous Silicon and Its Photoelectrochemical Hydrogen Production

Ilwhan Oh、Joohong Kye、Fengyun Wang2011-12-20Bulletin of the Korean Chemical Society

Porous silicon with a complex network of nanopores is utilized for photoelectrochemical energy conversion. A novel electroless Pt deposition onto porous silicon is investigated in the context of photoelectrochemical hydrogen generation. The electroless Pt deposition is shown to improve the characteristics of the PS ph…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnodic Oxide Films and Nanostructures

Static and Dynamic Plasmon-Enhanced Light Scattering from Dispersions of Polymer-Grafted Silver Nanoprisms in the Bulk and Near Solid Surfaces

Eleftheria Antoniou、Panayiotis Voudouris、Antje Larsen 等 7 位作者2011-12-20The Journal of Physical Chemistry C

Polarized (VV) and depolarized (VH) static (SLS) and dynamic light scattering (DLS) experiments were conducted in dispersions of sterically stabilized silver nanoprisms in three different solvents where strong plasmon-enhanced scattering was observed. In the dilute regime, hydrodynamic sizes obtained from VV and VH we…

Gold and Silver Nanoparticles Synthesis and ApplicationsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

SELF HEALING POTENTIAL OF GREEN NANOCOMPOSITES FROM CRYSTALLINE CELLULOSE

Jitendra Kumar Pandey、Hitoshi Takagi2011-12-20International Journal of Modern Physics B

In plant cell walls, stiff semicrystalline nano dimensional cellulose microfibrils are embedded in a pliable amorphous matrix where the size and shape of the cellulose fibrils are controlled by the dimensions of crystalline regions, providing them a unique structural and physical combination to be applied as load-bear…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Nonequilibrium and Relaxation in Deeply Supercooled Liquid of Isopropylbenzene Obtained through Glass Transition from Vapor-Deposited Glass

Kikujiro Ishii、Hideyuki Nakayama、Ryo Moriyama2011-12-20The Journal of Physical Chemistry B

Change in the light interference in film samples of isopropylbenzene was studied in the supercooled liquid (SCL) state. Samples were originally formed as glass by vapor deposition on a cold substrate and the intensity of laser light reflection from them was monitored as the temperature was raised with a constant rate…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesCultural Heritage Materials Analysis

Influence of the Chain Extender Nature on Adhesives Properties of Polyurethane Dispersions

Elena Orgilés‐Calpena、Francisca Arán‐Aís、Ana M. Torró‐Palau 等 4 位作者2011-12-20Journal of Dispersion Science and Technology

Several waterborne polyurethane adhesives containing different chain extenders were prepared by using the acetone process. Concretely, the polyurethane dispersions were synthesized by the prepolymer method based on three chain extenders: two diols and one diamine: 1,4-butanediol, 1,6-hexanediol and hydrazine. The adhe…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingEpoxy Resin Curing Processes

Experimental evaluation of a shape memory alloy wire actuator with a modulated adaptive controller for position control

P. Senthilkumar、G. N. Dayananda、M. Umapathy 等 4 位作者2011-12-20Smart Materials and Structures

This paper presents an experimental investigation of position control of a shape memory alloy (SMA) wire actuator with adaptive and modulated adaptive controllers. The transfer function model of the SMA wire actuator is determined from the experimental open loop response. Adaptive controllers, namely LMS–GSPI, RLS–GSP…

Shape Memory Alloy Transformations

Encapsulation of manganese(III) complex in NaY nanoporosity for heterogeneous catalysis

Iwona Kuźniarska‐Biernacka、Otilia Rodrigues、M. Alice Carvalho 等 5 位作者2011-12-20Applied Organometallic Chemistry

An encapsulated Mn(III)– salen complex in NaY was synthesized and characterized, and the catalytic behaviour of the complex was evaluated by the oxidation of styrene. The encapsulation was achieved by two different methodologies designated as the flexible ligand method (A) and the method of in situ complex synthesis (…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation Reactions

Experimental and Modeling Analysis of the Thermal Behavior of an Autothermal C3H8Catalytic Partial Oxidation Reformer

Dario Livio、Alessandro Donazzi、Alessandra Beretta 等 5 位作者2011-12-20Industrial & Engineering Chemistry Research

In this work, a spatially resolved sampling technique is applied to characterize the performance of a C 3 H 8 CPO reformer and to compare it with that of a CH 4 reformer. The case of Rh-coated honeycomb catalysts is examined. The axial profiles show that higher temperatures are reached in C 3 H 8 CPO, especially at th…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Palladium/tin bimetallic single-crystalline hollow nanospheres

Xiangwen Liu、Xiaoyang Li、Dingsheng Wang 等 7 位作者2011-12-20Chemical Communications

Hollow Pd/Sn bimetallic nanocrystals were fabricated by a fast one-pot strategy in an oleylamine system. This method produced a fine single crystalline bimetallic hollow nanostructure. The process and influencing factors of the reaction are also discussed in this work. Bimetallic nanoparticles possessing special hollo…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Adsorption of CO2 on a PdO(101) Thin Film

José Antonio Hinojosa、Abbin Antony、Can Hakanoglu 等 5 位作者2011-12-20The Journal of Physical Chemistry C

We investigated the adsorption of CO 2 on PdO(101) using temperature-programmed desorption (TPD) and dispersion-corrected density functional theory calculations (DFT-D3). We find that CO 2 desorbs from PdO(101) in two main TPD peaks (ε 1 and ε 2 ) centered at ∼176 and 120 K and estimate that the average binding energi…

Advanced Chemical Physics StudiesCatalytic Processes in Materials SciencePhase Equilibria and Thermodynamics

Tuning Magnetic and Structural Transitions through Valence Electron Concentration in the Giant Magnetocaloric Gd5–xEuxGe4 Phases

Jinlei Yao、Pengli Wang、Yurij Mozharivskyj2011-12-20Chemistry of Materials

Valence electron concentration is a viable chemical tool to control the crystal structure and magnetism of Gd 5 Ge 4 . A decrease in the valence electron concentration achieved through the substitution of Eu 2+ for Gd 3+ leads to the formation of the interslab Ge–Ge dimers, phase transitions to the Gd 5 Si 2 Ge 2 - an…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsInorganic Chemistry and Materials

Experimental determination of fabric shear by yarn pull-out method

Kadir Bilişik2011-12-20Textile Research Journal

The aim of this study was to determine fabric shear by the yarn pull-out method. For this purpose three fabric types were tested. The fabric width/length ratio and the number of pull-out ends were identified as important test parameters. After the yarn in the fabric was pulled from the top ravel region before the star…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Antifibrotic effect after low‐dose imatinib mesylate treatment in patients with nephrogenic systemic fibrosis: an open‐label non‐randomized, uncontrolled clinical trial

Tina Rask Elmholdt、Niels Henrik Buus、Mette Ramsing 等 4 位作者2011-12-20Journal of the European Academy of Dermatology and Venereology

BACKGROUND: Nephrogenic systemic fibrosis is a disease affecting the connective tissue of the skin and internal organs in patients with renal failure. No effective treatments are available. OBJECTIVES: To investigate if the tyrosine kinase inhibitor, imatinib mesylate was effective in patients with moderate to severe…

Electromagnetic Fields and Biological EffectsLanthanide and Transition Metal ComplexesChemotherapy-induced organ toxicity mitigation

Ingredients of thermal rectification: The case of classical and quantum self-consistent harmonic chains of oscillators

Emmanuel Pereira、Humberto C F Lemos、Ricardo R. Ávila2011-12-20Physical Review E

In order to identify the ingredients of thermal rectification, we analytically investigate the heat flow in the asymmetric classical and quantum self-consistent harmonic chains of oscillators. We confirm the absence of rectification in the classical version of the model, and, for the quantum analog, we show that the c…

Thermal properties of materialsAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

One-step synthesis of a thioester chiral PMO and its use as a catalyst in asymmetric oxidation reactions

Rafael García、Victoria Morales、Teresa Garcés2011-12-20Journal of Materials Chemistry

The study of key aspects for the heterogenization of chiral homogeneous catalysts is addressed in this work. Two different heterogenization routes were evaluated. On the one hand, the immobilization of a tartaric acid derivative (Sharpless catalyst) was accomplished by following a two-step synthesis methodology. In th…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

Learning From Nature: Synthesis and Characterization of Longitudinal Polymer Gradient Materials Inspired by Mussel Byssus Threads

Kai U. Claußen、Reiner Giesa、Thomas Scheibel 等 4 位作者2011-12-20Macromolecular Rapid Communications

Marine mussels use their threads for attachment to any substratum and these biopolymer gradient fibers show an excellent combination of stiff and soft mechanical properties. A straightforward approach for the preparation of macroscopic longitudinal polymer gradient materials on the centimeter scale based on a poly(dim…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesMarine Biology and Environmental Chemistry

UTILIZATION OF RICE HUSK AS RAW MATERIAL IN SYNTHESIS OF MESOPOROUS SILICATES MCM-41

Suyanta Suyanta、Agus Kuncaka2011-12-20Indonesian Journal of Chemistry

The research about synthesis and characterization of MCM-41 from rice husk has been done. Silica (SiO2) was extracted from rice husk by refluxing with 3M hydrochloric solution at 80 °C for 3 h. The acid-leached rice husk was filtered, washed, dried and calcined at 650 °C for 6 h lead the rough powder of rice husk sili…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAerogels and thermal insulation