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In situ observation of smectic layer reorientation during the switching of a ferroelectric liquid crystal

R. A. M. Hikmet1995-06-01Liquid Crystals

A thin plastic cell containing the ferroelectric liquid crystal ZLI3654 (4 μm) was placed edge-on to a pin-hole collimated horizontal X-ray beam. In this way, the smectic layers were brought into register. Subsequently, triangular voltage waves with various peak (V p) values were applied across the cell and diffractio…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Kinetic Processes in the CVD of SiC from CH3SiCl3-H2 in a Vertical Hot-Wall Reactor

F. Langlais、F. Loumagne、D. Lespiaux 等 5 位作者1995-06-01Journal de Physique IV (Proceedings)

The chemical vapour deposition of SiC-based ceramics from the CH3SiCl3-H2 precursor is investigated on the basis of large scale experimental and theoretical approaches. The use of a vetirtical cylindrical hot-wall LPCVD reactor permits to get a wide isothemal reaction zone with a creeping laminar flow around the subst…

Advanced ceramic materials synthesisSilicon Carbide Semiconductor TechnologiesSemiconductor materials and devices

Corrosion Behavior of Annealed and Hard-Drawn Copper in Soft Tap Water

F. Al-Kharafi、H.M. Shalaby1995-06-01CORROSION

The corrosion behavior of annealed and hard-drawn copper pipes was studied in soft tap water at room temperature. The work was carried out under stagnant and flow conditions on short- and long-term bases using electrochemical techniques. As-received copper pipes did not suffer from pitting regardless of whether the wa…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityDiverse Musicological Studies

Thermal Degradation of Polyphosphazene Homopolymers and Copolymers Prepared by the Anionic Polymerization of Phosphoranimines

Michael L. White、Krzysztof Matyjaszewski1995-06-01Journal of Macromolecular Science Part A

The thermal degradation of poly(bis-trifluoroethoxyphosphazene), as well as random and block copolymers bearing trifluoroethoxy and alkoxyalkoxy groups synthesized by the anionically initiated polymerization of phosphoranimines, has been investigated by TGA. These studies indicate that the thermal stability of the cop…

Energetic Materials and CombustionFlame retardant materials and propertiesThermal and Kinetic Analysis

An Optical Method for the Determination of the Cholesteric Pitch in Liquid Crystals

Ingo Dierking、Frank Gießelmann、P. Zugenmaier1995-06-01Zeitschrift für Naturforschung A

Abstract Preparation of a cholesteric liquid crystalline phase in planar orienting liquid crystal cells exhibits discontinuous colour changes with temperature when viewed between crossed polarizers. The trans­ mission spectra of such a system can be described by a modified de Vries equation, with the birefringence dis…

Liquid Crystal Research AdvancementsOptical Polarization and EllipsometryMolecular spectroscopy and chirality

X-ray microanalysis of chlorhexidine-treated cells of Saccharomyces cerevisiae

Sarah Hiom、A.C. Hann、J. R. Furr 等 4 位作者1995-06-01Letters in Applied Microbiology

The use of energy dispersive analysis of X-rays (EDAX) to identify and quantify the presence of chlorhexidine diacetate (CHA) within Saccharomyces cerevisiae cells was examined. Chlorine was used as the elemental marker tag. Saccharomyces cerevisiae cells exposed to 1000 micrograms ml-1 CHA took up increasing amounts…

Corrosion Behavior and InhibitionX-ray Spectroscopy and Fluorescence Analysis

Optical absorption studies of γirradiated magnesium phosphate glasses

A. A. Higazy、A. Hussein1995-06-01Radiation effects and defects in solids

The optical absorption is studied as a function of γ-irradiation dose and composition for a series of magnesium phosphate glasses. The optical absorption spectra were measured in the wavelength range from 200 to 1100 nm at different γ-doses in the range from 0.2 to 1.0 Mard. The obtained results are analysed assuming…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsNuclear materials and radiation effects

Electromigration characteristics of TiN barrier layer material

Tao Jiang、N.W. Cheung、Chenming Hu1995-06-01IEEE Electron Device Letters

Electromigration reliability of TiN barrier layer itself has been studied. Our results show no electrically measurable electromigration. Resistance increase and open failure under high density current stress are apparently due to a purely thermally activated process with an activation energy of 1.5 eV. TiN resistance…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

New perturbation theory of diffraction gratings and its application to the study of ghosts

Richard Dusséaux、F. Molinet、Christophe Fauré 等 4 位作者1995-06-01Journal of the Optical Society of America A

A new perturbation method for the diffraction of a plane wave by a grating with periodic imperfections is presented. The originality of the method lies in the fact that the perturbation occurs on a reference profile that is not a plane but a grating. First, the diffraction by a reference grating is treated. At this st…

Photonic Crystals and ApplicationsOptical Coatings and GratingsNear-Field Optical Microscopy

Improvement in Visible Luminescence Properties of Anodized Porous Silicon by Indium Plating

Toshimichi Ito、Toshiyuki Yoneda、Keisuke Furuta 等 5 位作者1995-06-01Japanese Journal of Applied Physics

Luminescence properties of anodically produced porous silicon (PS) have been improved significantly by depositing In metal into micropores. Thin ( ∼300 nm) PS specimens were electrochemically plated in an indium sulfate solution. Observed room-temperature photoluminescence (PL) is very strong in intensity and narrow i…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Investigation of a decagonal Al70Co15Ni15single crystal by means of high-resolution synchrotron X-ray diffraction

M. Kalning、W. Press、S. Kek1995-06-01Philosophical Magazine Letters

X-ray diffraction provides an optimum resolution of about 10−4 Å−1 in reciprocal space. Using synchrotron radiation, very weak diffraction phenomena can be studied with this resolution. Careful examination of the prominent Bragg reflections of a decaprismatic Al70Co15Ni15 needle reveals contributions both from a perfe…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Creation and Recombination of Frenkel Defects in AgBr

K. Funke、T. Lauxtermann、D. Wilmer 等 4 位作者1995-06-01Zeitschrift für Naturforschung A

Abstract Complete ionic conductivity spectra as well as quasielastic and inelastic neutron scattering spectra have been taken of solid silver bromide at various temperatures. High-amplitude vibrational move­ments, essentially of the silver ions, contribute to both kinds of spectra. In particular, a conductivity maximu…

Solid-state spectroscopy and crystallographyX-ray Diffraction in CrystallographyChemical and Physical Properties of Materials

Synthesis and hydrolytic stability of model poly(ester urethane ureas)

Luca Fambri、Amabile Penati、Jan Kolařı́k1995-06-01Die Angewandte Makromolekulare Chemie

Abstract Hydrolysis of poly(ester urethane ureas) (PURUs) is a complex phenomenon which impedes the analysis of the relationships between their composition and hydrolytic stability. Hydrolytic stability of PURUs decreases due to rising (i) polyol acidity, (ii) content of ester groups, (iii) flexibility and (iv) hydrop…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisSynthesis and properties of polymers

Aluminum substitution in goethite in lake ore

L. Carlson1995-06-01Bulletin of the Geological Society of Finland

The extent of substitution of Fe by Al in goethite in 32 lake ore samples collected from 11 lakes in Finland varied between 0 and 23 mol-%. The data indicated a negative relationship between Al-substitution and the particle size of lake ore. Differences in the Al-substitution were apparent between sampling sites, sugg…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMine drainage and remediation techniques

Production of shape memory alloys for microactuation

Dominiek Reynaerts、Jan Peirs、H. Van Brussel1995-06-01Journal of Micromechanics and Microengineering

This paper reports on the development of shape memory alloy based microactuators that can be integrated in teleoperated microsystems for medical applications. The use of shape memory alloys as actuator will increase the performance of micromechanical devices by several orders of magnitude. The paper presents the resul…

Shape Memory Alloy TransformationsInjection Molding Process and PropertiesEngineering Technology and Methodologies

Anchoring strength of a lyotropic nematic liquid crystal

A. M. Ribas、L. R. Evangelista、A. J. Palangana 等 4 位作者1995-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We determine the anchoring strength (W) for a lyotropic liquid crystal in the nematic calamitic phase. The sample holder is a microslide 200 \ensuremath{\mu}m thick (Vitro Dynamics) whose inner surfaces present some grooves introducing an easy axis. The technique used is based on the determination of the critical magn…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationCharacterization and Applications of Magnetic Nanoparticles

Conditional distribution function approach to the theory of the solid–nematic-fluid interface

А. В. Захаров1995-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

A statistical-mechanical theory which takes into account translational-translational, orientational-orientational, and mixed correlations, based upon the method of conditional distribution functions, is applied to calculations of the order parameters and surface free energy of a system composed of interacting ellipsoi…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPhotonic Crystals and Applications

Observation of two charge states of ruthenium in PbTiO3 single crystals

Paul G. Clem、David A. Payne、W. L. Warren1995-06-01Journal of Applied Physics

Two charge states are observed for Ru in doped PbTiO3 crystals using electron paramagnetic resonance (EPR). The two paramagnetic charge states are +3 and +5. The g tensors for the Ru3+ and Ru5+ defects were found to be near axial: g∥≂1.155 and g⊥≂2.188 for the Ru3+ center and ge∥≂2.0045 and ge⊥≂3.959 for the Ru5+ cent…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsSolid-state spectroscopy and crystallography

Effects of Surface Relaxation on Powder Diffraction Patterns of Very Fine Particles

A. C. Nunes、Ding‐Zheng Lin1995-06-01Journal of Applied Crystallography

Calculations of powder diffraction peaks using a model of tiny (diameter a few nm) spherical crystals log normally distributed in size with and without surface relaxation are presented. The calculated peak shapes are more nearly Gaussian than Cauchy (Lorentzian). Surface relaxation can produce small variations in peak…

Magnetic Properties and Synthesis of FerritesMicrowave-Assisted Synthesis and ApplicationsX-ray Diffraction in Crystallography

(3 + 2)-Dimensional superspace approach to the structure of the incommensurate intergrowth compound: (SbS)1.15TiS2

Y. Ren、Auke Meetsma、V. Petřı́ček 等 5 位作者1995-06-01Acta Crystallographica Section B Structural Science

The inorganic misfit-layer compound (SbS)(1.15)TiS2 was prepared by high-temperature reaction of the elements. The structure, determined by single-crystal X-ray diffraction, is described by two interpenetrating incommensurately modulated subsystems. The first subsystem comprises TiS2 sandwiches, with Ti atoms in trigo…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography