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XPS Characterization of a Commercial Cu/ZnO/Al 2 O 3 Catalyst: Effects of Oxidation, Reduction, and the Steam Reformation of Methanol

Brian Edward. Goodby、Jeanne E. Pemberton1988-07-01Applied Spectroscopy

X-ray photoelectron spectroscopy (XPS) is used to characterize the surface region of a commercial Cu/ZnO/Al 2 O 3 (33/66/1 wt %) catalyst. A systematic study of the effects of oxidation, reduction, and the steam reformation of methanol on the oxidative state of the Cu component is presented. The Zn XPS features show n…

ZnO doping and propertiesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

The Effect of Alkaline-Etch Pretreatment on the Pitting Corrosion of Wrought Aluminum

Otto Lunder、Kemal Nisancioḡl̄ū1988-07-01CORROSION

Pitting corrosion of aluminum alloys is sensitive to the type of surface treatment used prior to a corrosion test. In particular, significant differences in the pitting behavior are observed between the as-received and etched surfaces of several wrought alloys. It is shown that the as-received surface is generally mor…

Corrosion Behavior and InhibitionAluminum Alloy Microstructure PropertiesConcrete Corrosion and Durability

Oligomeric structure of p21 ras proteins as determined by radiation inactivation.

Eugenio Santos、Ángel R. Nebreda、Theodore Bryan 等 4 位作者1988-07-01Journal of Biological Chemistry

Using radiation inactivation we determined that p21 ras proteins exhibit an oligomeric target size when assayed both structurally and functionally. Similar target sizes of p21 in ras-transformed cells and in purified preparations of the protein suggested that its structure is homo-oligomeric. p21 monomers were destroy…

Cancer-related Molecular PathwaysEnzyme Structure and FunctionMolecular Biology Techniques and Applications

Glyceryl polyphosphazenes: synthesis, properties, and hydrolysis

Harry R. Allcock、Suk-Ky Kwon1988-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGlyceryl polyphosphazenes: synthesis, properties, and hydrolysisHarry R. Allcock and Sukky KwonCite this: Macromolecules 1988, 21, 7, 1980–1985Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://pubs.acs.org…

Flame retardant materials and properties

A new class of cation conductors: polyphosphazene sulfonates

S. Ganapathiappan、Kaimin Chen、Duward F. Shriver1988-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA new class of cation conductors: polyphosphazene sulfonatesS. Ganapathiappan, Kaimin Chen, and D. F. ShriverCite this: Macromolecules 1988, 21, 7, 2299–2301Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https:…

Synthesis and characterization of novel inorganic/organometallic compoundsLanthanide and Transition Metal ComplexesFlame retardant materials and properties

Estimation of the Rh-Rh bond dissociation energy in the (octaethylporphyrinato)rhodium(II) dimer by proton NMR line broadening

Bradford B. Wayland、Virginia L. Coffin、Maria D. Farnos1988-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEstimation of the Rh-Rh bond dissociation energy in the (octaethylporphyrinato)rhodium(II) dimer by proton NMR line broadeningBradford B. Wayland, Virginia L. Coffin, and Maria D. FarnosCite this: Inorg. Chem. 1988, 27, 15, 2745–2747Publication Date (Print):July 1, 1988Publi…

Mass Spectrometry Techniques and ApplicationsPorphyrin and Phthalocyanine ChemistryMolecular spectroscopy and chirality

Benzocyclobutene in polymer synthesis. I. Homopolymerization of bisbenzocyclobutene aromatic imides to form high‐temperature resistant thermosetting resins

Loon‐Seng Tan、Fred E. Arnold1988-07-01Journal of Polymer Science Part A Polymer Chemistry

Abstract A series of new bisbenzocyclobutene‐terminated aromatic imide monomers has been synthesized from the condensation reaction of 4‐aminobenzocyclobutene and the perspective dianhydride in refluxing acetic acid/toluene. The differential scanning calorimetric studies of the foregoing monomers indicated that polyme…

Epoxy Resin Curing ProcessesSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

XPS characterization of ultrafine Si 3 N 4 powders

I. Bertóti、G. Varsányi、G. Mink 等 7 位作者1988-07-01Surface and Interface Analysis

Abstract The mechanical properties of Si 3 N 4 based ceramic bodies are largely controlled by the phases formed on the grain boundaries during sintering. For this reason determination of the state and the chemical composition of the surface of the starting Si 3 N 4 powder is of prime theoretial and practical importanc…

Advanced ceramic materials synthesisSemiconductor materials and devicesIon-surface interactions and analysis

Emission characteristics and photostability of N,N'-bis(2,5-di-tertbutylphenyl)-3,4:9,10-perylenebis(dicarboximide)

El‐Zeiny M. Ebeid、Samy A. El‐Daly、Heinz Langhals1988-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEmission characteristics and photostability of N,N'-bis(2,5-di-tertbutylphenyl)-3,4:9,10-perylenebis(dicarboximide)El Zeiny M. Ebeid, Samy A. El-Daly, and Heinz LanghalsCite this: J. Phys. Chem. 1988, 92, 15, 4565–4568Publication Date (Print):July 1, 1988Publication History…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Determination of initial Sr isotopic compositions of dolostones from the Burlington-Keokuk Formation (Mississippian); constraints from cathodoluminescence, glauconite paragenesis and analytical methods

Jay L. Banner、Gilbert N. Hanson、William J. Meyers1988-07-01Journal of Sedimentary Research

Abstract Regionally extensive, fine-grained dolostones from the Mississippian Burlington-Keokuk Fm. comprise two major generations of dolomite that can be distinguished by their cathodoluminescence, chemical compositions, and times of formation. The petrography and geochemistry of glauconite, the predominant clay mine…

Groundwater and Isotope GeochemistrySoil and Unsaturated FlowClay minerals and soil interactions

Dye sensitization of van der Waals surfaces of tin disulfide photoanodes

B. A. Parkinson1988-07-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDye sensitization of van der Waals surfaces of tin disulfide photoanodesBruce A. ParkinsonCite this: Langmuir 1988, 4, 4, 967–976Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://pubs.acs.org/doi/10.1021/l…

2D Materials and ApplicationsGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Isothermal crystallization of poly(vinylidene fluoride) in the presence of high static electric fields. I. Primary nucleation phenomenon

Hervé Marand、Richard S. Stein、G. M. Stack1988-07-01Journal of Polymer Science Part B Polymer Physics

Abstract Primary nucleation of poly(vinylidene fluoride) (PVF 2 ) γ‐phase crystals from the melt is affected by the presence of an electric field. Crystallization under the electric field is studied by polarized optical microscopy, thermal analysis, and wide‐angle x‐ray diffraction. Preliminary results indicate that t…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesAdditive Manufacturing and 3D Printing Technologies

The resonance Raman and visible absorbance spectra of matrix isolated Mn2 and Mn3

K. Bier、T. L. Haslett、A. D. Kirkwood 等 4 位作者1988-07-01The Journal of Chemical Physics

The resonance Raman spectrum obtained from manganese containing argon matrices previously assigned to the dimer [M.Moskovits, D.P.DiLella, and W.Limm, J. Chem. Phys. 80, 626 (1984)] is shown to belong to a zero order D3h trimer subject to Jahn–Teller distortions. The actual resonance Raman spectra of the dimer in both…

Advanced Chemical Physics StudiesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Novel synthesis of aromatic polyamides by palladium-catalyzed polycondensation of aromatic dibromides, aromatic diamines, and carbon monoxide

Masaru Yoneyama、Masa‐aki Kakimoto、Yoshio Imai1988-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel synthesis of aromatic polyamides by palladium-catalyzed polycondensation of aromatic dibromides, aromatic diamines, and carbon monoxideMasaru Yoneyama, Masaaki Kakimoto, and Yoshio ImaiCite this: Macromolecules 1988, 21, 7, 1908–1911Publication Date (Print):July 1, 198…

Fiber-reinforced polymer compositesN-Heterocyclic Carbenes in Organic and Inorganic ChemistrySynthesis and properties of polymers

Chemical structures and properties of low thermal expansion coefficient polyimides

Shunichi Numata、Noriyuki Kinjo、Daisuke Makino1988-07-01Polymer Engineering and Science

Abstract The relationships, between chemical structures of various aromatic polyimides and their thermal expansion coefficients, were investigated and the properties of low thermal expansion polyimides were elucidated. Such low values were observed for polyimides obtained from pyromellitic dianhydride or 3,3′,4,4′‐bip…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Pathways for carboxylic acid decomposition on titania

K. S. Kim、Mark A. Barteau1988-07-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPathways for carboxylic acid decomposition on titaniaK. S. Kim and M. A. BarteauCite this: Langmuir 1988, 4, 4, 945–953Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://pubs.acs.org/doi/10.1021/la00082a028…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processingElectrochemical Analysis and Applications

Radiation Effect due to Energetic Oxygen Atoms on Conductive Al-Doped ZnO Films

Kikuo Tominaga、Kenji Kuroda、Osamu Tada1988-07-01Japanese Journal of Applied Physics

Al-doped ZnO films were prepared by both RF planar magnetron and RF diode sputterings. The dependence of the ZnO film resistivity on both substrate position and Ar gas pressure was investigated. Energetic oxygen atoms (O atoms) bombarding the film were also observed by time-of-flight apparatus, and the correlation bet…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsPlasma Diagnostics and Applications

Density of states in a-Se from combined analysis of xerographic potentials and transient transport data

M. Abkowitz1988-07-01Philosophical Magazine Letters

A density of states diagram for the mobility gap of a-Se is constructed by self-consistent analyses of time-resolved xerographic residual and dark depletion potentials in both undoped and halogen- and alkali-doped Se films. These are then combined with analyses of transient transport data to reveal additional features…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesAdvanced Semiconductor Detectors and Materials

Chemistry of organosilicon compounds. 240. Pentacoordinate allylsilicates: characterization and highly stereoselective reaction with aldehydes

Mitsuo Kira、Kazuhiko Sato、Hideki Sakurai1988-07-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemistry of organosilicon compounds. 240. Pentacoordinate allylsilicates: characterization and highly stereoselective reaction with aldehydesMitsuo. Kira, Kazuhiko. Sato, and Hideki. SakuraiCite this: J. Am. Chem. Soc. 1988, 110, 14, 4599–4602Publication Date (Print):July 1…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisCatalysis and Oxidation Reactions