Materials Literature
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Abstract The atomic structure of dioctahedral 2:1 phyllosilicate edge surfaces was calculated using pseudopotential planewave density functional theory. Bulk structures of pyrophyllite and ferripyrophyllite were optimized using periodic boundary conditions, after which crystal chemical methods were used to obtain init…
The chemical strategies offered by combining sol-gel processes together with the templated growth of inorganic or hybrid networks involving self-assembly with surfactant mesophases or organogels, and with external solicitations allows us, through an intelligent and tuned coding, to develop innovative materials having…
We have performed theoretical studies of the bulk modulus of M2AlC, where M=Ti, V, Cr by means of ab initio total energy calculations using the projector augmented wave methods. Our estimated equilibrium volume and the lattice parameters (c/a) agree well (within ±2% and ±0.06%, respectively) with experimental data. Th…
Rutting is a primary reason of premature deterioration of asphalt highway pavements. Pavements constructed with polymer and other modifiers are showing improved performance. The virgin asphalt and modified asphalt binders and mixes used on several test sections of the I-55 highway rehabilitation project in northern Mi…
Stagnation flow studies form a key research area in numerous applications dealt with industry. When a fluid approaches a solid boundary, it undergoes severe deceleration along the axis of impingement. We present the experimental findings of the effects of stagnation point on polymeric flow systems. While coating metal…
Apparent viscosity, ηa, and first normal stress coefficient, ψ1, of six different concentrations of cross-linked waxy maize (CWM), 3.5-5 % w/w, and tapioca, 2.8-4 % w/w, starch dispersions (SDs) showed power law relationships with shear rate, ̇γ , and increased with starch concentration. In both ηa and ψ1, volume frac…
The intention of the paper is to illustrate the ability of the Brownian dynamics simulation technique applied to mesoscale polymer models in order to reproduce light scattering experiments of dilute polymer solution under flow. After suitable parameterization of a real polymeric system, polystyrene solved in a oligost…
A new mechanism is proposed to explain the slow conductance fluctuations in the conductance-gate voltage plot observed in the nanotube electron resonators. It is found that the slow conductance fluctuation is an intrinsic quantum interference phenomenon and exists in all metallic nanotube resonators except zigzag ones…
The non-linear electrical behavior of zinc oxide, used to practical advantage in surge arresters on distribution power systems, has been replicated in epoxy resin, which has been filled with an appropriate volume fraction of this intrinsically semi-conducting material. Comparison has been made with epoxy resin contain…
Abstract Quantum dots (2–5 nm) of copper and copper/palladium mixtures are found to be good catalysts for Suzuki cross‐coupling. The catalysts are applicable to a wide range of iodo‐ and bromoaryl substrates, and give moderate yields using chloroaryl substrates. Cluster activity and stability is found to depend strong…
A novel method has been used to synthesize rare earth oxide nanoparticles. Sm and Nd hydride nanoparticles were first produced by a hydrogen plasma−metal reaction. The evaporation rate of Sm is about three times that of Nd. Nd 2 O 3 nanoparticles were then directly synthesized from the passivation of Nd hydride nanopa…
Abstract Diarylethenes having a fluorescent indole ring as the aryl group 1a and 2a were synthesized. Upon alternate irradiation with 366 nm and visible (λ > 480 nm) light, 1a underwent reversible photocyclization reactions to produce closed-ring isomer 1b. The fluorescence intensity also reversibly changed alo…
This paper describes a simple and reliable method of improving the surface insulation strength of a spacer used in vacuum. The method is to roughen the spacer surface to an average roughness R/sub a/ higher than 1 or 2 /spl mu/m. The material of the spacer examined is SiO/sub 2/, PMMA, PTFE or Al/sub 2/O/sub 3/ and th…
For more than 25 years, various techniques have been introduced for the nondestructive measurement of the space charge distribution in solid dielectrics. All these techniques can be classified into a set of three methods: (i) the thermal method, (ii) the pressure-wave-propagation method and (iii) the electro-acoustic…
Abstract Commercially available biodegradable aliphatic polyesters, i.e., high molecular weight poly(ϵ‐caprolactone) (PCL) and polylactide (PLA), were melt blended with a well‐known natural and biodegradable polysaccharide: starch either as corn starch granules or as thermoplastic corn starch after plasticization with…