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Production of high quality single- or few-layered graphene by solid exfoliation of graphite in the presence of ammonia borane

Lin Liu、Zhitao Xiong、Daqiang Hu 等 5 位作者2013-01-01Chemical Communications

A solid exfoliation method is developed for the synthesis of single- or few-layered (≤5 layers) graphene by ball milling of graphite with ammonia borane. Nearly quantitative yield in which ca. 25% is single-layered graphene can be obtained. We believe that this highly efficient method will offer a facile approach for…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

A facile approach for the fabrication of core–shell PEDOT nanofiber mats with superior mechanical properties and biocompatibility

Lin Jin、Ting Wang、Zhangqi Feng 等 7 位作者2013-01-01Journal of Materials Chemistry B

The development of modern biomedical nanotechnology requires conductive polymeric nanofibers with excellent mechanical and biocompatible properties to meet the needs of practical applications in complex biological systems. In the study, we developed a novel facile method to fabricate poly(3,4-ethylenedioxythiophene) (…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

MnOx–CeOx/CNTs pyridine-thermally prepared via a novel in situ deposition strategy for selective catalytic reduction of NO with NH3

Dengsong Zhang、Lei Zhang、Cheng Fang 等 7 位作者2013-01-01RSC Advances

The nanocomposites of highly-dispersed MnOx and CeOx on carbon nanotubes (CNTs) with a uniform structure are obtained via a novel in situ deposition strategy through a pyridine-thermal method and used for selective catalytic reduction (SCR) of NO with NH3 at low temperature. The influence of calcination temperature an…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

A novel conversion process for waste slag: synthesis of calcium silicate hydrate from blast furnace slag and its application as a versatile adsorbent for water purification

Yasutaka Kuwahara、Shigetaka Tamagawa、Tadahiro Fujitani 等 4 位作者2013-01-01Journal of Materials Chemistry A

Blast furnace slag (BFS), a high volume byproduct resulting from the iron manufacturing industry, was used as a low-cost and abundant precursor for preparing a high-surface-area calcium silicate hydrate. The synthesis of slag-made calcium silicate hydrate (slagCS) was achieved via a facile two-step dissolution–copreci…

Clay minerals and soil interactionsLayered Double Hydroxides Synthesis and ApplicationsPhosphorus and nutrient management

Reversible Solid Oxide Fuel Cell Technology for Green Fuel and Power Production

Nguyen Q. Minh、Mogens Bjerg Mogensen2013-01-01The Electrochemical Society Interface

Sustainable energy system based on the reversible solid oxide fuel cell (RSOFC), which is a device that can operate efficiently in both fuel cell and electrolysis operating modes, is feasible for the future. In the fuel cell mode, an RSOFC functions as a solid oxide fuel cell, generating electricity by electrochemical…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Expanded perlite aggregate characterization for use as a lightweight construction raw material

Atila Gürhan Çelik、Ahmet Mahmut KILIÇ、Gaye Ö. Çakal2013-01-01OpenAlex

Abstract: The purpose of this study is to investigate the use of İzmir (Menderes-Cumaovası) expanded perlite as a construction raw material by determining its characteristic properties, as well as its physical properties at different temperatures (up to 600°C). The perlites, having glassy, porous structure, were found…

Glass properties and applicationsChemical and Physical Properties of MaterialsNanotechnology research and applications

Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites

Deepalekshmi Ponnamma、Kishor Kumar Sadasivuni、Michał Strankowski 等 6 位作者2013-01-01RSC Advances

We report the fabrication of graphene oxide (GO) based polyurethane (PU) nanocomposites by a simple method of mixing and their shape memory properties at different temperatures. Both the polymer and the filler were synthesized in the laboratory by simple and easy methods – PU by pre-polymer method and GO by improved g…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Understanding the defect chemistry of tin monoxide

Jeremy P. Allen、David O. Scanlon、Louis F. J. Piper 等 4 位作者2013-01-01Journal of Materials Chemistry C

Tin monoxide has garnered a great deal attention in the recent literature, primarily as a transparent p-type conductor. However, due to its layered structure (dictated by non-bonding dispersion forces) simulation via density functional theory often fails to accurately model the unit cell. This study applies a PBE0-vdW…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Gold nanoparticle catalysis of the cis–trans isomerization of azobenzene

Geniece L. Hallett-Tapley、Claudio D’Alfonso、Natalia L. Pacioni 等 8 位作者2013-01-01Chemical Communications

Ablated, "pseudo-naked" gold nanoparticles (AuNPs) catalyze the cis-trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism.

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotochromic and Fluorescence ChemistryNanomaterials for catalytic reactions

Isolation and Characterization of Cellulose Whiskers from Kenaf (<i>Hibiscus cannabinus</i> L.) Bast Fibers

Lukmanul Hakim Zaini、Mehdi Jonoobi、Paridah Md Tahir 等 4 位作者2013-01-01Journal of Biomaterials and Nanobiotechnology

Cellulose whiskers were isolated from kenaf (Hibiscus cannabinus L.) bast fibers via sulfuric acid and hydrochloric acid hydrolysis. Raw kenaf bast, NaOH treated, bleached fibers, sulfuric acid whiskers (SAW) and hydrochloric acid whiskers (HClW) morphology, functional groups, crystallinity, and thermal stability were…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Electrospun SiO2 nanofibers as a template to fabricate a robust and transparent superamphiphobic coating

V. Anand Ganesh、Saman Safari Dinachali、Hemant Kumar Raut 等 6 位作者2013-01-01RSC Advances

A one-dimensional morphology of electrospun nanofibers has been used as a template to fabricate a robust and transparent superamphiphobic coating. The template is created by the deposition of a thick layer of SiO2 nanofibers on glass. The developed template (SiO2 nanofibers) is coated with an ultrathin (25 nm) porous…

ZnO doping and propertiesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Designing functionalizable hydrogels through thiol–epoxy coupling chemistry

Nergiz Cengiz、Jingyi Rao、Amitav Sanyal 等 4 位作者2013-01-01Chemical Communications

A novel and modular strategy has been developed for the preparation of reactive and functionalized hydrogels. In this strategy, thiol-epoxy coupling chemistry was employed for the formation of a hydrophilic network. The hydroxyl groups, generated during the coupling process, were then engaged in anchoring a fluorescen…

Advanced Polymer Synthesis and CharacterizationSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Molecularly stabilised ultrasmall gold nanoparticles: synthesis, characterization and bioactivity

Annika Leifert、Yu Pan-Bartnek、Ulrich Simon 等 4 位作者2013-01-01Nanoscale

Gold nanoparticles (AuNPs) are widely used as contrast agents in electron microscopy as well as for diagnostic tests. Due to their unique optical and electrical properties and their small size, there is also a growing field of potential applications in medical fields of imaging and therapy, for example as drug carrier…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Fabrication of (001)-oriented monoclinic WO3 films on FTO substrates

Jin You Zheng、Guang Song、Chang Woo Kim 等 4 位作者2013-01-01Nanoscale

(001)-oriented monoclinic nanorod and microplate WO3 films are fabricated on commercial FTO-coated glass substrates by a rubbing seed layer and a spin-coating seed layer assisted by hydrothermal reactions. The nanorod film obtained by the rubbing seed layer assisted by hydrothermal reactions is more regular and perpen…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Tunable electrochemical properties of fluorinated graphene

Praveen Meduri、Honghao Chen、Jie Xiao 等 7 位作者2013-01-01Journal of Materials Chemistry A

The structural and electrochemical properties of fluorinated graphene have been investigated by using a series of graphene fluorides (CFx, x = 0.47, 0.66, 0.89). Fluorinated graphene exhibited high capacity retentions of 75–81% of theoretical capacity at moderate rates as cathode materials for primary lithium batterie…

Advancements in Battery MaterialsGraphene research and applicationsFiber-reinforced polymer composites

Gas-phase esterification of cellulose nanocrystal aerogels for colloidal dispersion in apolar solvents

Matthieu Fumagalli、F. H. Sánchez、Sonia Molina Boisseau 等 4 位作者2013-01-01Soft Matter

With the goal of an efficient and selective surface hydrophobization for subsequent colloidal dispersion into non-polar media, cellulose nanocrystals (CNCs) were transformed into aerogels of high surface area, prepared by freeze-drying dilute CNC suspensions in mixtures of water and t-BuOH of various compositions. In…

Advanced Cellulose Research StudiesPolysaccharides and Plant Cell WallsAerogels and thermal insulation

Suppression of thermally activated carrier transport in atomically thin MoS2 on crystalline hexagonal boron nitride substrates

Mei Yin Chan、Katsuyoshi Komatsu、Songlin Li 等 11 位作者2013-01-01Nanoscale

We present the temperature-dependent carrier mobility of atomically thin MoS2 field-effect transistors on crystalline hexagonal boron nitride (h-BN) and SiO2 substrates. Our results reveal distinct weak temperature dependence of the MoS2 devices on h-BN substrates. The room temperature mobility enhancement and reduced…

Graphene research and applications2D Materials and ApplicationsAdvanced Memory and Neural Computing

Single-walled carbon nanotube coated antibacterial paper: preparation and mechanistic study

Archana R. Deokar、Lih‐Yuan Lin、Chun‐Chao Chang 等 4 位作者2013-01-01Journal of Materials Chemistry B

Development of carbon nanotubes toward commercial antibacterial applications warrants the understanding of their interaction mechanism with bacterial cells. The antibacterial activity and mechanism of acid-functionalized single-walled carbon nanotube (AFSWCNT) coated paper was assessed for gram-positive Staphylococcus…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsNanotechnology research and applications

Reactivity of metal oxide clusters with hydrogen peroxide and water – a DFT study evaluating the performance of different exchange–correlation functionals

Cláudio M. Lousada、Adam Johannes Johansson、Tore Brinck 等 4 位作者2013-01-01Physical Chemistry Chemical Physics

We have performed a density functional theory (DFT) investigation of the interactions of H2O2, H2O and HO radicals with clusters of ZrO2, TiO2 and Y2O3. Different modes of H2O adsorption onto the clusters were studied. In almost all the cases the dissociative adsorption is more exothermic than molecular adsorption. At…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Porous Shape-Memory Polymers

Keith Hearon、Pooja Singhal、John Horn 等 8 位作者2013-01-01Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

Porous shape memory polymers (SMPs) include foams, scaffolds, meshes, and other polymeric substrates that possess porous three-dimensional macrostructures. Porous SMPs exhibit active structural and volumetric transformations and have driven investigations in fields ranging from biomedical engineering to aerospace engi…

Electrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healingAdvanced Materials and Mechanics