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Theoretical Study on Spin Alignments in Ferromagnetic Heterospin Chains with Competing Exchange Interactions: A Generalized Ferrimagnetic System Containing Organic Biradicals in the Singlet Ground State

Kensuke Maekawa、Daisuke Shiomi、Tomoaki Ise 等 5 位作者2005-04-12The Journal of Physical Chemistry B

Spin alignments in heterospin chains are examined from numerical calculations of model spin Hamiltonians. The Hamiltonians of the heterospin chains mimic an open-shell molecular assemblage composed of an organic biradical in a singlet (S = 0) ground state and a doublet (S = 1/2) monoradical, which are coupled by inter…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Surface anchoring effect on the morphology and performance of polymer-dispersed liquid crystal (Invited Paper)

Yi‐Hsin Lin、Hongwen Ren、Yung-Hsun Wu 等 5 位作者2005-04-12Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Surface effects on the phase separation dynamics, morphologies, and electro-optic properties of thin polymer-dispersed liquid crystal (PDLC) cells are investigated. Four types of surface alignment layers were studied: ITO only, Polyimide (PI) without rubbing, homogeneous cell, and 90° twisted nematic (TN) cell. The IT…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsSemiconductor Lasers and Optical Devices

Importance of barrier layers in thermal diodes for energy conversion

Y. Kucherov、Peter L. Hagelstein、V. G. Sevast'yanenko 等 6 位作者2005-04-12Journal of Applied Physics

Very high thermal to electric conversion efficiencies have been reported previously with thermal diode structures in which a thin n-type emitter layer is formed on the hot side of a thick near-intrinsic thermoelectric semiconductor. The figure of merit derived from direct measurements of electrical parameters and heat…

Advanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Effect of Jet Design on Commingling of Glass/Nylon Filaments

R. Alagirusamy、Vinayak Ogale、A. M. Vaidya 等 4 位作者2005-04-12Journal of Thermoplastic Composite Materials

In this study, a computational fluid dynamics (CFD) model is applied to study the airflow patterns inside the commingling jets, for different configurations. The CFD package, FLUENT 6.1, is used to predict the two-dimensional flow field inside a yarn channel. The parameters viz. velocity profile, pressure gradient, an…

Textile materials and evaluations

Mechanism and Nanosize Products of the Sol−Gel Reaction Using Diphenylsilanediol and 3-Methacryloxypropyltrimethoxysilane as Precursors

Se Yun Kim、Saji Augustine、Young Joo Eo 等 6 位作者2005-04-12The Journal of Physical Chemistry B

We use a first-principles calculation and small-angle neutron scattering (SANS) to investigate the mechanism and the nanosize products of the sol-gel reaction with diphenylsilanediol (DPD) and 3-methacryloxypropyltrimethoxysilane (MEMO) precursors in synthesizing a hybrid waveguide material. It is predicted that switc…

Mesoporous Materials and CatalysisAerogels and thermal insulationSilicone and Siloxane Chemistry

Model system for classical fluids out of equilibrium

Marisol Ripoll、M. H. Ernst2005-04-12Physical Review E

A model system for classical fluids out of equilibrium, referred to as a dissipative particles dynamics (DPD) solid, is studied by analytical and simulation methods. The time evolution of a DPD particle is described by a fluctuating heat equation. This DPD solid with transport based on collisional transfer (high-densi…

Material Dynamics and PropertiesTheoretical and Computational PhysicsLattice Boltzmann Simulation Studies

Influence du pH sur les propriétés des sols : l'essai de longue durée des 42 parcelles à Versailles

A. Pernes-Debuyser、D. Tessier2005-04-12Revue des sciences de l eau

Les pratiques de fertilisation et d'amendement peuvent contribuer à modifier profondément les propriétés des sols. Ceci est mis en évidence par le dispositif des 42 parcelles de l'INRA à Versailles qui reçoit chaque année les mêmes traitements depuis 1929. Il présente l'originalité d'être en jachère nue. Les résultats…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

Hemiporphycene from the Expansion of a Corrole Ring

Roberto Paolesse、Sara Nardis、Manuela Stefanelli 等 5 位作者2005-04-12Angewandte Chemie

Die Bildung einer vinylogen Brücke zwischen benachbarten Pyrrolringen (A und B) bei der Reaktion von 5,10,15-Triphenylcorrol mit CI4 führt zum entsprechenden Hemiporphycen (siehe Struktur; N blau, I rosa, C weiß, H grün). Dieser Ansatz eröffnet einen einfachen Zugang zu funktionalisierten Hemiporphycenen.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Dendritic Structures Based on Bis(hydroxymethyl)propionic Acid as Platforms for Surface Reactions

Emma Östmark、Lubica Macáková、Tommaso Auletta 等 6 位作者2005-04-12Langmuir

In this paper we present results related to the self-assembly of different generations of disulfide-cored 2,2-bis(hydroxymethyl)propionic acid-based dendritic structures onto gold surfaces. These molecular architectures, ranging from generation 1 to generation 3, contain removable acetonide protecting groups at their…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

CuO Supported on Al2O3-Coated Cordierite-Honeycomb for SO2 and NO Removal from Flue Gas: Effect of Acid Treatment of the Cordierite

Qingya Liu、Zhenyu Liu、Zhanggen Huang2005-04-12Industrial & Engineering Chemistry Research

CuO supported on Al 2 O 3 -coated cordierite-honeycomb CuO catalysts exhibit high activities for SO 2 and NO removal from flue gas at 400 °C. In a catalyst preparation process, it was found that acid treatment of the cordierite was crucial. This work presents a detailed study on the promoting effect of acid treatment…

ZnO doping and propertiesCatalytic Processes in Materials ScienceIndustrial Gas Emission Control

A metabolically active dermal replacement (Dermagraft) for vestibuloplasty

Jan-Dirk Raguse、Hans Joachim Gath2005-04-12Journal of Oral Rehabilitation

This article describes the use of tissue-engineered dermal replacement in the vestibular extension instead of palatal donor tissue or (split-thickness) skin graft. In three patients the living human-derived fibroblast skin substitute (Dermagraft) was implanted on the wound surface after mucogingival junction and supra…

Reconstructive Surgery and Microvascular TechniquesElectrospun Nanofibers in Biomedical ApplicationsReconstructive Facial Surgery Techniques

Localized and conducting states in carbon nanotube superlattices

W. Jaskólski、Leonor Chico2005-04-12Physical Review B

The electronic structure and quantum conductance of superlattices made of metallic carbon nanotubes are investigated. It is shown that minibands with the same origin as nonconductive states in metallic quantum dots [L. Chico and W. Jask\'olski, Phys. Rev. B 69, 085406 (2004)] can have a nonzero conductance in superlat…

Carbon Nanotubes in CompositesGraphene research and applicationsSemiconductor materials and interfaces

Fast grain boundary diffusion and rate-limiting surface exchange reactions in polycrystalline materials

Wolfgang Preis、Werner Sitte2005-04-12Journal of Applied Physics

Analytical solutions to the diffusion equations for fast grain boundary diffusion in polycrystalline solids of finite thickness bounded by two parallel surface planes are presented. The grain boundary diffusion coefficient may be higher by several orders of magnitude than the bulk (volume) diffusion coefficient. The m…

Microstructure and mechanical propertiesNumerical methods in engineeringComposite Material Mechanics

Semiconductor Nanocrystal Quantum Dots on Single Crystal Semiconductor Substrates: High Resolution Transmission Electron Microscopy

A. Konkar、Siyuan Lu、A. Madhukar 等 5 位作者2005-04-12Nano Letters

We report on high-resolution transmission electron microscope structural studies of InAs colloidal semiconductor nanocrystal quantum dots (NCQDs) on ultrathin GaAs (001) semiconductor single-crystal substrates. We employ a benign method for preparing electron transparent specimens that is suitable for the study of suc…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNear-Field Optical Microscopy

High performance, high temperature perovskite piezoelectrics

Thomas R. Shrout、Shujun Zhang、Richard E. Eitel 等 5 位作者2005-04-12OpenAlex

The industrial and scientific communities have expressed the need for sensing and actuation over a broad temperature range. This review presents high temperature piezoelectric materials that are commercially available and those that are under development. Key materials, in order of increasing Curie temperature (T/sub…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Visualizing profile-profile alignment: pairwise HMM logos

Benjamin Schuster‐Böckler、Alex Bateman2005-04-12Computer applications in the biosciences

UNLABELLED: The availability of advanced profile-profile comparison tools, such as PRC or HHsearch demands sophisticated visualization tools not presently available. We introduce an approach built upon the concept of HMM logos. The method illustrates the similarities of pairs of protein family profiles in an intuitive…

Protein Structure and DynamicsAdvanced Proteomics Techniques and ApplicationsEnzyme Structure and Function

Excitation Energy Migration in A Dodecameric Porphyrin Wheel

In‐Wook Hwang、Dah Mee Ko、Tae Kyu Ahn 等 8 位作者2005-04-12The Journal of Physical Chemistry B

Intramolecular excitation energy hopping (EEH) time within a dodecameric porphyrin wheel C6ZA, in which six meso-meso linked zinc(II) diporphyrin (Z2) subunits are bridged by 1,3-phenylene spacers, is deduced by a Förster energy hopping model based on S(1)-S(1) exciton-exciton annihilation and anisotropy depolarizatio…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

The Reaction between ZnO and Molten Na2S2O7 or K2S2O7 Forming Na2Zn(SO4)2 or K2Zn(SO4)2, Studied by Raman Spectroscopy and X-ray Diffraction

Rolf W. Berg、N. Thorup2005-04-12Inorganic Chemistry

Reactions between solid zinc oxide and molten sodium or potassium pyrosulfates at 500 degrees C are shown by Raman spectroscopy to be 1:1 reactions leading to solutions. By lowering the temperature of the solution melts, colorless crystals form. Raman spectra of the crystals are given and tentatively assigned. Crystal…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

N-(2-Hydroxypropyl)methacrylamide Copolymer Conjugates

Ruth Duncan2005-04-12OpenAlex

Improved therapies for the treatment of life-threatening and chronic debilitating disease are urgently needed. Many seek to achieve more effective chemotherapy through the use of nanosized drug carriers-now being called ‘‘nanomedicines.’’ The technologies being explored include nanoparticles (1), polymer-coated liposo…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationLanthanide and Transition Metal Complexes