Materials Literature
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Two series of heterometallic Fe(III)-Ln(III) compounds, [FeLn(μ3-OH)2(mdea)4(m-NO2C6H4COO)8]·3MeCN where Ln = Y (1) and Dy (2) and [FeLn(μ4-O)3(μ3-O)(mdea)5(m-NO2C6H4COO)9]·3MeCN where Ln = Y (3) and Dy (4), were synthesized. Compounds 1 and 2 were obtained under ambient conditions, whereas 3 and 4 were obtained via a…
Abstract Temporal analysis of products (TAP) was used to study NO reduction to N 2 over H 2 and C 3 H 6 ‐reduced La‐Zr doped ceria at 560 °C. (La‐Zr doped) ceria is found to be capable of fuel oxidation and NO reduction. NO dissociates on oxygen anion defects, thereby refilling these vacancies with oxygen anions and f…
The unique optical properties of semiconductor quantum dots (QDs) are highly advantageous for biological imaging and analysis, particularly when combined with Förster resonance energy transfer (FRET). A recent innovation in this area has been concentric FRET (cFRET), wherein QDs are assembled with multiple copies of t…
We propose that the observed spin relaxation in bilayer graphene is due to resonant scattering by magnetic impurities. We analyze a resonant scattering model due to adatoms on both dimer and nondimer sites, finding that only the former give narrow resonances at the charge neutrality point. Opposite to single-layer gra…
The influence of Sr and Cu variation on the electrochemical performance of cobalt-free cathodes Pr 1- x Sr x Fe 0.8 Cu 0.2 O 3- δ (PSFC x , 0 ≤ x ≤ 0.5) and Pr 0.5 Sr 0.5 Fe 1- y Cu y O 3- δ (PSFC y , 0 ≤ y ≤ 0.3) for intermediate temperature solid oxide fuel cells (IT-SOFCs) was investigated in half cells and full ce…
A single beam laser interferometer based on a modified Mirau detection scheme with a vertical resolution of ∼5 pm was developed for localized d33 measurements on patterned piezoelectric films. The tool provides high spatial resolution (∼2 μm), essential for understanding scaling and processing effects in piezoelectric…
Discoidal high-density lipoproteins generated by the apolipoprotein-mediated solubilization of membrane lipids in vivo can be reconstituted with phospholipids and apolipoproteins in vitro. Recently, it has been reported that such particles can be prepared using the hydrolyzed acid form of styrene-maleic anhydride copo…
Calcium phosphate mineralization was conducted by using polymer composites of liquid-crystalline (ethyl)cellulose (EC) or (hydroxypropyl)cellulose (HPC) with poly(acrylic acid) (PAA) as a scaffolding medium for the inorganic deposition. The EC/PAA and HPC/PAA samples were prepared in colored film form from EC and HPC…
The drug ibuprofen (IBP) appears frequently in the wastewater discharge from pharmaceutical industries. This paper reports studies in degradation of IBP employing hybrid technique of sono-enzymatic treatment. This paper also establishes synergy between individual mechanisms of enzyme and sonolysis for IBP degradation…
The guided mode resonances (GMRs) of diffraction gratings surrounded by low index materials can be designed to produce broadband regions of near perfect reflection and near perfect transmission. These have many applications, including in optical isolators, in hybrid lasers cavities and in photovoltaics. The excitation…
The intrinsic field effect, the change in surface conductance with an applied transverse electric field, of prototypal strongly correlated ${\mathrm{VO}}_{2}$ has remained elusive. Here we report its measurement enabled by epitaxial ${\mathrm{VO}}_{2}$ and atomic layer deposited high-$\ensuremath{\kappa}$ dielectrics.…
In this Letter, I present a versatile strategy to enhance the near-infrared to near-infrared (NIR-to-NIR) upconversion luminescence from sub-10-nm ultra-small LaF(3):Yb(3+)/Tm(3+) colloidal nanoparticles through lanthanide doping under 980 nm laser excitation. It is interesting that the NIR-to-NIR upconversion emissio…
The mechanism of translation symmetry breakdown in newly proposed low-dimensional carbon pentagon-constituted nanostructures (e.g., pentagraphene) with multiple sp(2)/sp(3) sublattices was studied by GGA DFT, DFTB, and model potential approaches. It was found that finite nanoclusters suffer strong uniform unit cell be…
Abstract Cornstalk core, a renewable by‐product of agriculture, has been used as a carbon precursor to prepare high‐performance electrode materials used in electrochemical capacitors (ECs). The influences of temperature and the ratio of activator (KOH) to carbon ( m KOH / m C ) on the structures of porous carbon mater…
The photostabilization of polyvinyl chloride (PVC) films by Schiff bases was investigated. Polyvinyl chloride films containing 0.5 wt % Schiff bases were produced using the same casting method as that used for additive-free PVC films from tetrahydrofuran (THF) solvent. The photostabilization activities of these compou…
The biomedical potential of flavonoids is normally restricted by their low water solubility. However, little has been reported on their encapsulation into polyamidoamine (PAMAM) dendrimers to improve their biomedical applications. Generation four (G4) PAMAM dendrimer containing ethylenediaminetetraacetic acid core wit…
Controlled wrinkling of single-layer graphene (1-LG) at nanometer scale was achieved by introducing monodisperse nanoparticles (NPs), with size comparable to the strain coherence length, underneath the 1-LG. Typical fingerprint of the delaminated fraction is identified as substantial contribution to the principal Rama…
We report the assembly of gold nanoclusters by the nonthiolate ligand diglyme into discrete and dynamic assemblies. To understand this surprising phenomenon, the assembly of Au20(SC2H4Ph)15-diglyme into Au20(SC2H4Ph)15-diglyme-Au20(SC2H4Ph)15 is explored in detail. The assembly is examined by high-angle annular dark f…
New binuclear complexes of La(III), Nd(III), Sm(III), Eu(III), Gd(III) and Tb(III) ions with mefenamic acid were obtained in solid phase. For all compounds considered, complexation occurs at pH 6–6.5. The analyzed complexes were characterized on the basis of chemical and elemental analyses, molar conductance, UV–Vis,…
Thermal properties of organic semiconductors play a significant role in the performance and lifetime of organic electronic devices, especially for scaled-up large area applications. Here we employ silver nanoparticles (Ag NPs) to modify the thermal conductivity of the small molecule organic semiconductor, dinaphtho[2,…