Materials Literature
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In this paper, we study the electronic structure of monolayer materials based on a double hexagonal geometry with (1×1) and [Formula: see text] superstructures. Inspired from the two-dimensional root system of an exceptional Lie algebra called G 2 , this hexagonal atomic configuration involves two hexagons of unequal…
Polyaniline film as primer coating was deposited on stainless steel (SS) in aniline containing aqueous oxalic acid solution, and subsequent synthesis of top PPy film with 2-((5-ethylthiophen-2-yl) methylamino)-1-phenylpropan-1-ol (AAN) compound of different concentrations was achieved in acetonitrile-LiClO4 successful…
Atomic force microscopy (AFM) of microfibres fabricated from the self-assembly and fracturing of silica nanoparticles reveals mesoporous structure with hcp packing. Pore size distribution for (20 - 30) nm sized particles are calculated to lie within rtet ~(2.2 - 3.3) nm and roct ~(4.2 - 6.2) nm for the octahedral and…
Adsorption of O, O 2 , and OH on Pt(111), Pt(100), and Pt(110) surfaces was studied using periodic DFT calculations. It was found that generally adsorbate-surface interaction strengths increase with the decrease in surface packing density. On the Pt(111) surface the dissociation of O 2 molecule was not predicted, but…
In this study, effects of solidification rate and 0·2, 0·5 and 1·0 wt-% Sb additions on the microstructure and mechanical properties of AM60 magnesium alloy were investigated. AM60 and AM60+xSb magnesium alloys were cast in a step-like mould with three different cooling rates. As cast microstructures of the different…
A core–shell cobalt ferrite/silicon dioxide/europium ion-doped Y 2 O 3 (CoFe 2 O 4 /SiO 2 /Y 2 O 3 :Eu 3+ ) composite was synthesized by a facile layer-by-layer method. Magnetization of the composite under an external magnetic field of approximately 0.25 T enhanced the photoluminescence (PL) intensity by 56%. The rema…
In this paper, we present an innovative method for the synthesis of CdTe/CdSe type-II core/shell structure quantum dots (QDs) using 'greener' chemicals. The PL of CdTe/CdSe type-II core/shell structure QDs ranges from 600 to 820 nm, and the as-synthesized core/shell structures show narrow size distributions and stable…
Species of Haliotis (abalone) show high variety in structure and mineralogy of the shell. One of the European species (Haliotis tuberculata) in particular has an unusual shell structure in which calcite and aragonite coexist at a microscale with small patches of aragonite embedded in larger calcitic zones. A detailed…
The advancement of supercapacitor electrodes is predicated using simple and efficient synthesis methods. In this study a simple electrochemical precipitation method is presented for the synthesis of an α-nickel hydroxide (α-Ni(OH)2) electrode directly on a Ti substrate without any templates or surfactants. The α-Ni(OH…
Abstract A highly active Cu‐based Deacon catalyst with an enhanced lifetime was developed by combining two corrosion‐resistant high‐throughput reactor setups in this combinatorial study. Catalyst activities were studied in a sequential 10‐fold reactor equipped with online MS. For accelerated catalyst ageing studies, a…
In this paper, a new NOx removal control technique coupled with energy recovery in a sintering plant is proposed. On the basis of energy calculation, it was found that the energy of sintered ore was large enough to supply the energy necessary to heat effluent flue gas to the catalytic temperature window. Moreover, the…
The performance of a polymer-stabilized blue phase system based on a nematic host with large dielectric anisotropy and a chiral dopant with high helical twisting power is investigated and the influence of the reactive monomer composition on the electro-optic characteristics is studied. Field-induced birefringence with…
Abstract Distances between amine groups were varied through three different approaches, which were found to play a crucial role in influencing the intrinsic fluorescence properties. Experimental data confirmed that the short distance between amine groups favored the intense emission and red shift of the maximum wavele…
Monoclinic Yb-sensitized (Tm, Ho)-doped KLu(WO4)2 nanocrystals of ~100 nm size have been synthesized by the modified Pechini sol-gel method. Their diode laser near-infrared (~980 nm) excited upconversion emission properties have been characterized at power densities in the range 30-355 W cm(-2). Bright white light com…
A class of binary mixtures of Janus fluids formed by colloidal spheres with the hydrophobic hemispheres constrained to point either up or down are studied by means of Gibbs ensemble Monte Carlo simulations and simple analytical approximations. These fluids can be experimentally realized by the application of an extern…
Three kinds of para-phenylenediamine (PDA) derivatives bearing nitronyl nitroxide (NN) groups were prepared and characterized on the basis of the electrochemical, electron spin resonance (ESR) spectroscopic, absorption spectroscopic, and magnetic susceptibility measurements. It was clarified that the oxidation potenti…
Carbonaceous nanodots (CDs) have drawn increasing attention owing to their inspiring properties. CDs based composites have been attracting extensive research interest because of the properties improvement of materials and introduction of new physical or chemical properties. In this work, we designed a quick, handy and…
Dendritic julolidine-based nonlinear optical (NLO) chromophore (JTCFC) possessing isolation group was designed and synthesized to realize effective isolation of NLO chromophores in the polymer backbone. Electro-optic (EO) polycarbonates (PC-JTCFCs) consisting of the dendritic JTCFC and comonomers were prepared through…
Contact thermocouples often are used to measure surface body temperature changes of insects during cold exposure. However, small temperature changes of minute insects can be difficult to detect, particularly during the measurement of supercooling points. We developed two thermocouple designs, which use 0.51 mm diamete…
Si heterojunction solar cells were fabricated on p-type single-crystal Si (sc-Si) substrates using phosphorus-doped Si nanocrystals (Si-NCs) embedded in SiNx (Si-NCs/SiNx) films as emitters. The Si-NCs were formed by post-annealing of silicon-rich silicon nitride films deposited by electron cyclotron resonance chemica…