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Properties and morphologies of UV‐cured epoxy acrylate blend films containing hyperbranched polyurethane acrylate/hyperbranched polyester

Gang Xu、Yongbin Zhao、Wenfang Shi2005-09-26Journal of Polymer Science Part B Polymer Physics

Abstract The properties and morphologies of UV‐cured epoxy acrylate (EB600) blend films containing hyperbranched polyurethane acrylate (HUA)/hyperbranched polyester (HPE) were investigated. A small amount of HUA added to EB600 improved both the tensile strength and elongation at break without damaging its storage modu…

Epoxy Resin Curing ProcessesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Atomistic dynamics of deformation, fracture, and joining of individual single-walled carbon nanotubes

Koji Asaka、Tokushi Kizuka2005-09-26Physical Review B

The tensile deformation process of individual single-walled carbon nanotubes (SWCNTs) was in situ observed with measurements of the mechanical properties by transmission electron microscopy combined with the functions of scanning probe microscopy. The values of Young's modulus, tensile stress and strain at the fractur…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsNanotechnology research and applications

Rf‐sputtering growth of stoichiometric amorphous TeO2 thin films

Massimo Di Giulio、Andrea Zappettini、L. Nasi 等 4 位作者2005-09-26Crystal Research and Technology

Abstract Amorphous stoichiometric thin films of TeO 2 have been successfully grown by reactive rf‐sputtering deposition. The proper choice of deposition parameters such as the rf power, the Ar/O 2 composition and pressure of the sputtering gas, the substrate temperature, enabled us to obtain TeO x films of different t…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

Formation of II‐VI nanocrystals in polymeric matrix: Thermolytic synthesis and structural characterization

F. Antolini、T. Di Luccio、M. Re 等 4 位作者2005-09-26Crystal Research and Technology

Abstract In this work we report on the growth of CdS and ZnS semiconductor nanocrystals embedded in a polymeric matrix (polystyrene) by synthesizing a metal thiolate precursor and its subsequent thermolysis at about 300 °C after dispersion in the polymer. The crystallinity, shape and size of the metal sulfide nanocrys…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Cracks and Topological Defects in Lyotropic Nematic Gels

Mohammad F. Islam、Maurizio Nobili、Fangfu Ye 等 5 位作者2005-09-26Physical Review Letters

We report on the effects of the coupling of nematic order and elasticity in anisotropic lyotropic gels consisting of large nematic domains of surfactant coated single wall carbon nanotubes embedded in a cross-linked N-isopropyl acrylamide polymer matrix. We observe the following striking features: (i) undulations and…

Liquid Crystal Research AdvancementsMicro and Nano RoboticsAdvanced Materials and Mechanics

A dependency of quantum efficiency of silicon CMOS n/sup +/pp/sup +/ LEDs on current density

Lukas W. Snyman、H. Aharoni、Monuko du Plessis2005-09-26IEEE Photonics Technology Letters

A dependency of quantum efficiency of nn/sup +/pp/sup +/ silicon complementary metal-oxide-semiconductor integrated light-emitting devices on the current density through the active device areas is demonstrated. It was observed that an increase in current density from 1.6/spl times/10/sup +2/ to 2.2/spl times/10/sup +4…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Optical detection of deoxyribonucleic acid hybridization using an anchoring transition of liquid crystal alignment

Hak‐Rin Kim、Jae‐Hoon Kim、Tae‐Sun Kim 等 5 位作者2005-09-26Applied Physics Letters

We demonstrate an optical method for detecting specific binding events in an oligo deoxyribonucleic acid (DNA) chip using an anchoring transition of a nematic liquid crystal (NLC) as a result of DNA hybridization. A homeotropic orientation of the NLC supported by oligoDNA changes to a random planar orientation after h…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsMolecular spectroscopy and chirality

Ferromagnetism of MnO and Mn3O4 nanowires

Chan Woong Na、Doo Suk Han、Dae Sung Kim 等 7 位作者2005-09-26Applied Physics Letters

Mixture of single-crystalline MnO and Mn3O4 nanowires was synthesized by thermal evaporation of MnCl2 powders. The diameter is 50–100nm, the length is about 20μm, and the growth direction is uniformly [100] for both cubic MnO and tetragonal Mn3O4 nanowires. The temperature-dependent magnetization and magnetic hysteres…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Extracting subnanometer single shells from ultralong multiwalled carbon nanotubes

Byung Hee Hong、Joshua P. Small、Meninder Purewal 等 11 位作者2005-09-26Proceedings of the National Academy of Sciences

We report a simple but powerful method for engineering multi-walled carbon nanotubes (MWNTs) by using manipulation by an atomic-force microscope. The successive shell-by-shell extraction process of ultralong MWNTs allows the exposure of the innermost single-walled carbon nanotubes (SWNTs), which have diameters as smal…

Carbon Nanotubes in CompositesGraphene research and applicationsForce Microscopy Techniques and Applications

Wet etching of Ge2Sb2Te5films and switching properties of resultant phase change memory cells

Huai‐Yu Cheng、Chao An Jong、Ren‐Jei Chung 等 5 位作者2005-09-26Semiconductor Science and Technology

Wet-etching of amorphous Ge2Sb2Te5 films was studied by ICP and XPS spectrometries. It is thought that wet-etching arises from chemical etching that starts with bond breakages, oxidation of each element and subsequent dissolution of the resultant oxides. The Ge element debonds more easily from the Ge–Sb–Te matrix than…

Chalcogenide Semiconductor Thin FilmsTransition Metal Oxide NanomaterialsPhase-change materials and chalcogenides

Activated events in glasses: The structure of entropic droplets

Maxim Dzero、Jörg Schmalian、Peter G. Wolynes2005-09-26Physical Review B

Using an effective potential approach, we present a replica instanton theory for the dynamics of entropic droplets in glassy systems. Replica symmetry breaking in the droplet interface leads to a length scale dependent reduction of the droplet surface tension and changes the character of the dynamical heterogeneity an…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Morphological, structural and optical study of quasi‐1D SnO2 nanowires and nanobelts

Davide Calestani、L. Lazzarini、G. Salviati 等 4 位作者2005-09-26Crystal Research and Technology

Abstract 0.1–0.3 mm thick entanglements of quasi‐one‐dimensional semiconducting Tin dioxide nanocrystals, in form of nanowires and nanobelts, are successfully grown by low cost Chemical Vapour Deposition directly on large area (100 mm 2 ) Al 2 O 3 , SiO 2 and Si substrates. Their lateral size ranges from 50 to 700 nm…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Development of a novel serum‐free freezing medium for mammalian cells using the silk protein sericin

Masahiro Sasaki、Yoichi Kato、Hideyuki Yamada 等 4 位作者2005-09-26Biotechnology and Applied Biochemistry

Cryopreservation is a pivotal process in cellular engineering for creating a continuous source of generated functional cell lines and for the convenience of various medical treatments that involve cell culture. FBS (fetal bovine serum) supplemented with 10% (v/v) DMSO is extensively used as a freezing medium for mamma…

Protein Hydrolysis and Bioactive PeptidesViral Infectious Diseases and Gene Expression in InsectsSilk-based biomaterials and applications

Road Map for the Controlled Synthesis of CdSe Nanowires, Nanobelts, and Nanosaws—A Step Towards Nanomanufacturing

Chengwei Ma、Zhong Lin Wang2005-09-26Advanced Materials

Abstract One‐dimensional (1D) nanostructures of CdSe have been found to exhibit morphologies of nanowires, nanobelts, and nanosaws, but their synthesis is by trial and error. To meet the needs of large‐scale, controlled, and designed synthesis of nanostructures, it is imperative to systematically find experimental con…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Magnetic-field-induced transition in the lattice modulation of colossal magnetoelectricGdMnO3andTbMnO3compounds

T. Arima、T. Goto、Yuichi Yamasaki 等 9 位作者2005-09-26Physical Review B

Single-crystal synchrotron x-ray diffraction measurements in strong magnetic fields have been performed for magnetoelectric compounds $\mathrm{Gd}\mathrm{Mn}{\mathrm{O}}_{3}$ and $\mathrm{Tb}\mathrm{Mn}{\mathrm{O}}_{3}$. It has been found that the $\mathbit{P}\ensuremath{\Vert}a$ ferroelectric phase induced by the app…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

How do electronic carriers cross Si-bound alkyl monolayers?

Adi Salomon、Olga Girshevitz、David Cahen 等 7 位作者2005-09-26arXiv

Electron transport through Si-C bound alkyl chains, sandwiched between n-Si and Hg, is characterized by two distinct types of barriers, each dominating in a different voltage range. At low voltage, current depends strongly on temperature but not on molecular length, suggesting transport by thermionic emission over a b…

Mesoscale and Nanoscale PhysicsMaterials Science

Sub-wavelength imaging: Resolution enhancement using metal wire gratings

G. Fedorov、S. I. Maslovski、A. V. Dorofeenko 等 6 位作者2005-09-26arXiv

An experimental evidence of subwavelength imaging with a "lens", which is a uniaxial negative permittivity wire medium slab, is reported. The slab is formed by gratings of long thin parallel conducting cylinders. Taking into account the anisotropy and spatial dispersion in the wire medium we theoretically show that th…

Materials Science

Dielectric dispersion of CaCu3Ti4O12 ceramics at high temperatures

J. L. Zhang、Peng Zheng、C. L. Wang 等 6 位作者2005-09-26Applied Physics Letters

Ca Cu 3 Ti 4 O 12 ceramics has been prepared by the conventional solid-state reaction method under different sintering conditions. Dielectric properties have been investigated in the temperature range of 25–350°C within the frequency range of 40Hz–10MHz. It has been found that both the dielectric constants and the gra…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Evidence of an enhanced interband absorption in Au nanoparticles: Size-dependent electronic structure and optical properties

B. Balamurugan、Toshiro Maruyama2005-09-26Applied Physics Letters

The present study reports clear evidence and physical significance of an interband transition due to the transition from the d band to an empty state in the conduction band in the optical absorption spectra of Au nanoparticles. The optical absorption due to interband transitions has been observed to dominate the plasm…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesLaser-Ablation Synthesis of Nanoparticles

Platinum Chromophore-Based Systems for Photoinduced Charge Separation: A Molecular Design Approach for Artificial Photosynthesis

Soma Chakraborty、Thaddeus J. Wadas、Heidi Hester 等 5 位作者2005-09-26Inorganic Chemistry

Photoinduced charge separation is a fundamental step in photochemical energy conversion. In the design of molecularly based systems for light-to-chemical energy conversion, this step is studied through the construction of two- and three-component systems (dyads and triads) having suitable electron donor and acceptor m…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies