Materials Literature
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The microstructures of the omega phase in Ti-Mo alloy single crystals were investigated using high resolution electron microscopy (HREM), image processing and dark-field methods. By image processing, the assembly of linear defects which had been reported was revealed in the region of the superposition of two kinds of…
Abstract Aromatic poly( o ‐hydroxy amide)s having inherent viscosities of 0.6–2.2 dL/g were readily synthesized by the low‐temperature solution polycondensation of N , N ′, O ‐tris(trimethylsilyl)‐substituted 2,4‐diaminophenol with aromatic dicarboxylic acid chlorides in various organic solvents. The viscosity values…
Poled polymer thin films are studied by SHG, THG, and ATR experiments. The ATR method is used for determining the linear and quadratic electro-optic (chi) (2) (-(omega) ; 0, (omega) ) and (chi) (3) (-(omega) ; 0, 0, (omega) ) coefficients. The part due to the piezoelectricity and electrostriction is characterized and…
Abstract Surface‐enhanced Raman scattering (SERS) from citrate‐coated colloidal particles suspended in organic solvents is used to study surface reactions in an organic phase. Stable colloids which gave good SERS were produced from ethanol and acetonitrile. SERS was easily discriminated from the bulk solvent Raman sca…
The potassium niobyl cyclotetrasilicate K2(NbO)2Si4O12 crystallizes in the non-centrosymmetrical polar space group P4bm with a = 8.7404(8) Å, c = 8.136(1) Å, Z = 2. The acentric character of the structure is mainly due to a sequence of short (niobyl) and long Nb-O bonds along the 4-fold axes. Optical studies on small…
Single crystals of K(Ta1-xNbx)O3 with compositions 0.30<x<1 are grown from solutions with an excess of K2O. In order to minimize striations due to temperature fluctuations a method is applied similar to that known for the crystallization in aqueous solutions. With optimized growth conditions this kind of striations is…
Data The Synthesis, Reactivity, Structure, And Physicochemical Properties Of Vinyl Tellurides, Which Are Potential Monomers, Synthons, And Intermediates, Are Given In The Present Review.
Abstract The influence of deacetylation degree on heterogeneous molecular aggregation has been investigated for chitosan solution in 2 wt % acetic acid aqueous solution using rheological and small‐angle x‐ray scattering (SAXS) methods. Three samples of chitosan, which were designated CS62, CS79, and CS96, were used, a…
Abstract Different grades of PVC resins and a variety of plasticizers are used to adjust processability and properties of plastisol. The plastisol, which is a dispersion of fine particles of PVC in plasticizer, is coated on a substrate and heated in an oven to gel and fuse. In the gelation stage the resin particles be…
We report on a systematic study of the thin-film growth and the electronic structure of the intrinsic molecular semiconductor lutetium–diphthalocyanine (LuPc2). The films were grown in ultrahigh vacuum. Starting from submonolayer coverage, thickness-dependent x-ray and ultraviolet photoemission spectroscopy (UPS) meas…
SUMMARY Potassium release and fixation were studied on Ferralsols (typic Eutrustox) of Southern Togo both by isotopic exchange with 42 K+ ions and by exchange with 1 M ammonium acetate. Experiments were conducted on soil samples taken from surface (0–30 cm) and subsoil (80–100 cm) layers of four plots. These plats, wi…
Abstract The behaviour of adenine and 2′‐deoxyadenosine‐5′‐monophosphate (dAMP) at positive surface potentials of a silver working electrode was investigated using surface‐enhanced Raman scattering (SERS). The use of positive potentials in the presence of adenine or dAMP leads to a rapid accumulation of an intense spe…
Research News: Freely suspended thin film of smectic liquid crystalline materials can be described as two‐dimensinal fluids with a regular layer structure in the third dimention. By reducing the internal pressure in the set up shown in the figure the films can be transferred onto solid supports allowing their study, m…
Abstract X-ray diffraction was used to analyse the distribution of clay minerals in the <2 µ m fraction of the lutitic and marly facies from the centre of the Basque-Cantabrian Basin (Basque Arc), where the sedimentary section is 2000 to 10,000 m thick. Most of the deposits were laid down during the Cretaceous and…
Two non-first-order kinetic peaks at about 350 and 500 K appear in the thermoluminescence (TL) spectra of single-crystal and polycrystalline ${\mathrm{MgAl}}_{2}$${\mathrm{O}}_{4}$ irradiated with ionizing radiation at room temperature. Among others, emission from ${\mathrm{Cr}}^{3+}$ and ${\mathrm{Mn}}^{2+}$ ions are…
Silicon dioxide films deposited from the plasma‐enhanced chemical vapor deposition (PECVD) reaction of silane and nitrous oxide in the presence of helium were studied to determine the effects of temperature and radio frequency (RF) power on the deposition process. Increased RF power density yielded oxides which were s…
We study the interaction of disclinations in the presence of an applied magnetic or extensional flow field, which tends to align the director. Disclinations and inversion walls in the director field of nematic thermotropic liquid-crystal polymers are imaged at high resolution using the lamellar decoration technique of…
Abstract The thermal behaviour of sepiolite and palygorskite treated with pyridine (Py) was investigated by DTA, TG, DTG and EGA (by MS) under a flow of air and inert gases (N 2 or Ar). The thermal analysis showed that the organic base was adsorbed by the clays, penetrating into the clay pores and replacing zeolitic a…
Abstract A new family of addition curing polyimides were prepared that contained 4‐amino [2.2]‐paracyclophane as the endcap. An improved synthesis of the endcap 4‐amino‐[2.2] cyclophane was accomplished increasing the yield to 60% and simplifying the procedure. DSC and rheological analysis of endcapped polyimide oligo…
A new metastable liquid-crystalline phase BPS was observed in pure chiral compounds. The BPS is transformed reversibly from the supercooled BPI and is thermodynamically stable with respect to the BPI and metastable to the cholesteric phase. Rhombic single crystals of the BPS probably indicate a cubic lattice structure…