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Inorganic photophysics in solution. Part 3.—Temperature activation of decay processes in the luminescence of tris(2,2′-bipyridine)osmium(II) and tris(1,10-phenanthroline)osmium(II) ions

Stephen R. Allsopp、Alan L. Cox、Terence J. Kemp 等 6 位作者1979-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The behaviour of (i) the luminescence spectrum, (ii) the (relative) luminescence quantum yield and (iii) the luminescence lifetime of [Os(phen)3]2+(phen = 1,10-phenanthroline) and [with respect to (ii) and (iii)] of [Os(bipy)3]2+(bipy = 2,2′-bipyridine), has been examined in the temperature range 77–300 K, principally…

Organic Light-Emitting Diodes ResearchPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes

The crystal structure of γ Ag8GeTe6, a potential mixed electronic-ionic conductor*

作者信息未提供1979-01-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract γ Ag 8 GeTe 6 belongs to space group F [unk]3 m with Z = 4 and a = 11.58 ± 0.02Å. The arrangement of the tellurium atoms is almost precisely that of both the magnesium and copper atoms in the Friauf-Laves cubic phase of MgCu 2 . This arrangement produces 136 tetrahedra per unit cell, of which four are occupie…

Crystal Structures and PropertiesPhase-change materials and chalcogenidesOrganic and Molecular Conductors Research

Penetration behaviour of a high-strength aluminium alloy

R. L. Woodward1979-01-01Metals Technology

The ballistic penetration behaviour of a high-strength aluminium alloy, 7001 T6, was investigated and targets of the alloy were found to fail in two modes, discing or plugging, depending on the orientation of the target in relation to the extrusion direction of the round bar from which it was cut. The dependence of fa…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsElectromagnetic Launch and Propulsion Technology

The crystal structure of hexabromobenzene: constrained refinement of neutron powder diffraction data

E. Baharie、G. S. Pawley1979-01-01Acta Crystallographica Section A

The structure of hexabromobenzene, C6Br6, has been determined at 300 K by neutron powder diffraction. The crystal is monoclinic, a = 15.357 (4), b = 4.007 (1), c = 8.364 (2) Å, β = 92.65 (2)°, space group P21/n, Z = 2. The problem is well suited for a constrained refinement with the program EDINP. Within the accuracy…

Crystallography and molecular interactionsX-ray Diffraction in CrystallographyChemical Thermodynamics and Molecular Structure

Hot Corrosion of Gas Turbine Components

V.M. Patarini、N. S. Bornstein、M. A. DeCrescente1979-01-01Journal of Engineering for Power

Hot corrosion is the accelerated rate of oxidation of coatings and substrates, which occurs when a condensed phase is present on the surface. The major constituent of the corrosive deposit is sodium sulfate, although when fuels other than light distillates are employed, the deposit can contain various amounts of vanad…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceHigh-Temperature Coating Behaviors

Evaluation of acetylene as a spark ignition engine fuel

David L. Hilden、Russell F. Stebar1979-01-01International Journal of Energy Research

In spite of its known shortcomings as a fuel for spark ignition engines, acetylene has been suggested as a possible alternative to petroleum-based fuels since it can be produced from non-petroleum resources (coal, limestone and water). Therefore, acetylene was evaluated in a single-cylinder engine to investigate perfo…

Catalytic Processes in Materials ScienceSynthesis and Biological Evaluation

Effect of Thiourea and Some of its Derivatives on the Corrosion Behaviour of Nickel in 50% v/v (5·6M) Hydrochloric Acid

Phillip Clark、E. Jackson、Michael J. Robinson1979-01-01British Corrosion Journal

The corrosion rate of commercial grade, coid-rolled nickel in 50%v/v (5·6 M) hydrochloric acid, with and without the presence of thiourea or one of several of its derivatives, has been studied by gravimetric and electrochemical methods over the temperature range, 23–79°c. All the compounds exhibited some ability to in…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

High‐Temperature Crystallization, Composition, Structure, and Certain Properties of Rare‐Earth Gallium Borates

L. I. Al'Shinskaya、Ν. I. Leonyuk、T. I. Timchenko1979-01-01Kristall und Technik

Abstract Solution‐melts based on PbF 2 —B 2 O 3 and Bi 2 O 3 —B 2 O 3 were used in studying the stability regions and for growth, by way of spontaneous crystallization, of crystals up to 3 mm in size of twelve compounds having the general formula RGa 3 (BO 3 ) 4 . All of these compounds are isostructural with carbonat…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Temperature Dependence of Refractive Indices and Order Parameter of p-n-Butoxy- and p-n-Amyloxy Benzoic Acids

J. V. Yakhml、V. K. Kelkar、R. P. Shukla 等 4 位作者1979-01-01Molecular crystals and liquid crystals

The refractive indices in the nematic and isotropic phases have been determined for the pnbutoxy-and p-n-amyloxybenzoic acids. The orientational order parameter in the nematic phase has been calculated for both the compounds using Vuks formula. The variation of order parameter with respect to reduced temperature for b…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Tensile Properties of Neutron-Irradiated 6061 Aluminum Alloy in Annealed and Precipitation-Hardened Conditions

K. Farrell、RT King1979-01-01OpenAlex

Tension specimens of 6061 aluminum alloy (nominally 1Mg-0.6Si) were heat-treated to give fully annealed (“0” temper) and precipitation-hardened (“T6” temper) conditions, and were irradiated in water at 328 K (0.35 Tm) to fast (>0.1 MeV) fluences up to 1.8 × 1027 neutrons/m2 and thermal (<0.025 eV) fluenc…

Microstructure and mechanical propertiesFusion materials and technologiesAluminum Alloy Microstructure Properties

Raman Spectrum of the Split ν4Mode of CO[dbnd]3Ions in Aragonite

V. Rives、G. Munuera、J. M. Criado1979-01-01Spectroscopy Letters

Infrared and Raman spectra of CO[dbnd] 3 ions are different in the two crystallographic forms of CaCO3 Calcite and Aragonite owing to their different site symmetries. Due to this fact, i.r. has been used to assess the reversible Calcite ← → Aragonite transformation which occurs upon grinding of CaCO3, and much work ha…

Methane Hydrates and Related PhenomenaCalcium Carbonate Crystallization and InhibitionCO2 Sequestration and Geologic Interactions

Acoustical Techniques for Detecting and Locating Electrical Discharges

RT Harrold1979-01-01OpenAlex

Acoustical detection of electrical discharges was perhaps the earliest technology used by man as he became aware of lightning flashes and the associated sound of thunder during rainstorms. Presumably, for millions of years man knew that the sound of thunder gave an early warning of an approaching storm (Lucretius (95-…

High voltage insulation and dielectric phenomena

Chain Scission and Cross-Linking in the Radiation Degradation of Polymers: Limitations on the Utilization of Theoretical Expressions and Experimental Results in the Pregel Region

J. H. O'Donnell、Nazia Rahman、Craig A. Smith 等 4 位作者1979-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChain Scission and Cross-Linking in the Radiation Degradation of Polymers: Limitations on the Utilization of Theoretical Expressions and Experimental Results in the Pregel RegionJ. H. O'Donnell, N. P. Rahman, C. A. Smith, and D. J. WinzorCite this: Macromolecules 1979, 12, 1…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Beiträge zum thermischen Verhalten von Sulfaten. II. Zur thermischen Dehydratisierung des ZnSO4 · 7 H2O und zum Hochtemperaturverhalten von wasserfreiem ZnSO4

M. Spiess、R. Gruehn1979-01-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Mit kontinuierlichen Heizguinieraufnahmen wurde die Dehydratisierung von ZnSO 4 · 7 H 2 O und das Hochtemperaturverhalten von wasserfreiem ZnSO 4 untersucht. Der Abbau von ZnSO 4 · 7 H 2 O verläuft an der Luft über das 6‐Hydrat, eine unbekannte Hydratphase und das 1‐Hydrat zum N‐ZnSO 4 , der Normaltemperaturf…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsThermal and Kinetic Analysis

Effects of boron, titanium, and nitrogen on the hardenability of boron-treated steels for heavy machinery

F. Nakasato、Masatoshi Takahashi1979-01-01Metals Technology

The effects of boron, titanium, and nitrogen contents on the hardenability of boron-bearing steels have been studied. The boron hardenability factor was found to be a rapidly decreasing function of (total N – N as TiN). Thus, it was confirmed that titanium plays a very important role in retaining the excellent hardena…

Metal and Thin Film MechanicsAdvanced materials and compositesMetal Alloys Wear and Properties

Electron-microscope observation of structure domains in the ferroelastic phase of lead phosphate, Pb3(PO4)2

R. Ayroles、J. Torrès、J. Aubrée 等 5 位作者1979-01-01Applied Physics Letters

We have used for the first time the electron-microscopy technique to reveal the pure ferroelastic phase domain structure of lead phosphate, Pb3(PO4)2. The domain configuration confirms previous identifications of the symmetry elements lost at the transition. The domains are found separated by thin walls whose thicknes…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallography

Biphasic photochemistry: micellar regioselectivity in enone dimerisation

Kong-Hung Lee、P. de Mayo1979-01-01Journal of the Chemical Society Chemical Communications

Irradiation of 3-alkylcylcopentenones in potassium dodecanoate micelles leads to greatly increased efficiency of dimerisation over that in homogeneous solution and regiospecific head-to-head control far beyond that possible by solvent variation.

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Synthesis of 1 - (4-Alkoxy or Alkyl- Benzoyloxy-Phenyl) - 2- (4′- Pentylphenyl) - Ethanes. Influence of the Central Group on the Mesomorphic Properties

Nguyễn Hữu Tình、A. Zann、Jean Dubois1979-01-01Molecular crystals and liquid crystals

An homologous series of mesomorphic compounds, the I-(4-alkoxy or alkyl-benzoyloxyphényl)-2-(4′-pentylphenyl)-ethanes, has been synthesized. The compounds with R = alkyl have low-melting points and wide mesomorphic ranges, for example from 33.5°C to 106.5C. The compounds with R = alkoxy exhibit a smectic polymorphism;…

Liquid Crystal Research AdvancementsSynthesis of Organic CompoundsAxial and Atropisomeric Chirality Synthesis