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CONFORMATION OF CHITIN AND N-ACYL CHITOSANS IN SOLID STATE AS REVEALED BY 13C CROSS POLARIZATION/MAGIC ANGLE SPINNING (CP/MAS) NMR SPECTROSCOPY

Hazime Saitô、Ryoko Tabeta、Shigehiro Hirano1981-10-01Chemistry Letters

Abstract 13C chemical shifts of solid chitin and N-acyl chitosans were measured by cross polarization/magic angle spinning (CP/MAS) NMR spectroscopy. It was found that a regenerated chitin, N-acetyl chitosan, adopts conformation almost identical to that of naturally occurring chitin in solid state. Conformation of N-d…

Nanocomposite Films for Food PackagingCarbohydrate Chemistry and Synthesis

Transition-metal impurities in diluteFe3−xTxSialloys: A spin-echo NMR investigation

T. J. Burch、J. I. Budnick、V. A. Niculescu 等 5 位作者1981-10-01Physical review. B, Condensed matter

A comprehensive collection of spin-echo NMR spectra from nuclei of both host and transition-metal impurities ($T$) in pseudobinary ${\mathrm{Fe}}_{3\ensuremath{-}x}{T}_{x}\mathrm{Si}$ alloys taken at about 1.3 K are presented and analyzed. We summarize some new data on $3d$ elements and also review briefly some result…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Conformational defects and associated molecular motions in crystalline poly(vinylidene fluoride)

Andrew J. Lovinger1981-10-01Journal of Applied Physics

Electron-diffraction investigation of single crystals of γ-poly (vinylidene fluoride) grown from the melt has revealed streaking of 0k0 reflections. The three-dimensional structure of the spikes was studied by specimen tilting during electron diffraction; streaking is maximized in the b*c* view and disappears in the a…

Polymer crystallization and propertiesFiber-reinforced polymer compositesMaterial Properties and Processing

Effect of oxidation states of Mn on the phase stability of Mn-doped BaTiO 3

Seshu B. Desu、E. C. Subbarao1981-10-01Ferroelectrics

The oxidation states of Mn in Mn-doped BaTiO3 were investigated by ESR, supplemented by thermal analysis and electrical conductivity data. Direct evidence for the presence of Mn2+ and Mn4+ and indirect evidence for the presence of Mn3+ is presented. Based on the Jahn-Teller distortion characteristics of the various ox…

Ferroelectric and Piezoelectric MaterialsTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Magnetic field dependence of the nematic-isotropic transition temperature

Charles Rosenblatt1981-10-01Physical Review A

The nematic-isotropic transition temperature was measured by means of an optical technique as a function of applied magnetic field for the material octyl-cyanobiphenyl. The results represent the first unambiguous demonstration of the magnetic field term in the thermodynamic equation for a liquid-crystal phase transiti…

Liquid Crystal Research AdvancementsAdvanced Thermodynamics and Statistical MechanicsMolecular spectroscopy and chirality

A Criterion for the Onset of Instability at a Turning Point

Rafael D. Sorkin1981-10-01The Astrophysical Journal

A very general sufficient condition for the onset of "thermodynamic" instability at a turning point is proved, assuming essentially nothing beyond the smoothness of the equilibrium-sequence in question.

Solidification and crystal growth phenomenaAdhesion, Friction, and Surface InteractionsFluid Dynamics and Thin Films

Thermal Study of Types of Water Associated with Clinoptilolite

Gregory D. Knowlton、T. White、H.L. McKague1981-10-01Clays and Clay Minerals

Abstract The identification and quantification of the water associated with powdered clinoptilolite and clinoptilolite-bearing tuffs were made using thermogravimetric, vacuum gravimetric, and differential scanning calorimetric techniques. Inflection points on thermogravimetric curves at approximately 80° and 170°C cor…

Analytical Chemistry and ChromatographyVarious Chemistry Research TopicsThermal and Kinetic Analysis

Minimum fluidization velocity at high temperatures

Ranga R. Pattipati、C. Y. Wen1981-10-01Industrial & Engineering Chemistry Process Design and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMinimum fluidization velocity at high temperaturesRanga R. Pattipati and C. Y. WenCite this: Ind. Eng. Chem. Process Des. Dev. 1981, 20, 4, 705–707Publication Date (Print):October 1, 1981Publication History Published online1 May 2002Published inissue 1 October 1981https://pu…

Minerals Flotation and Separation TechniquesCrystallization and Solubility StudiesMineral Processing and Grinding

Surface corrosion of nitinol and stainless steel under clinical conditions.

John W. Edie、George F. Andreasen、Mary P. Zaytoun1981-10-01PubMed

Abstract Nitinol has been reported to be more susceptible to electrolytic dissolution than stainless steel. This study compares corrosion of the two metals under clinical conditions and finds no significant difference.

Hydrogen embrittlement and corrosion behaviors in metals

Heat capacity and other thermodynamic properties of linear macromolecules. IV. Polypropylene

Umesh Kumar Gaur、Bernhard Wunderlich1981-10-01Journal of Physical and Chemical Reference Data

The heat capacity of polypropylene from 0 K to 600 K is reviewed on the basis of measurements on 20 samples reported in the literature. The crystallinity dependence is critically evaluated and a set of recommended data for completely crystalline and amorphous polypropylene are derived. The effect of tacticity on the h…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

A Review of Particle-Contaminated Gas Breakdown

J.R. Laghari、A. H. Qureshi1981-10-01IEEE Transactions on Electrical Insulation

The sensitivity of compressed gases to free and fixed conducting and non-conducting particle contaminants is a limiting factor in the design of electrical apparatus. Conducting particles which may result from damage to a gas-filled system constitute a serious threat to its safe and reliable operation. This deteriorati…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

PTC Effect in BaTiO 3 as a Function of Doping with 3d Elements

H. Ihrig1981-10-01Journal of the American Ceramic Society

The electrical resistivities, grain sizes, and charge carrier densities of Sb‐doped PTC‐type BaTiO 3 ceramics were measured as a function of additional doping with 3d ions of varying concentrations. From analysis of the PTC characteristics on the basis of Heywang's model it proved possible to derive grain‐surface acce…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsTransition Metal Oxide Nanomaterials

A Changing Capacitor Technology - Failure Mechanisms and Design Innovations

David G. Shaw、S. W. Cichanowski、A. Yializis1981-10-01IEEE Transactions on Electrical Insulation

During the past few years the ac capacitor industry has seen almost a complete change in dielectrics, electrodes, and impregnants. The dielectric has changed from paper to all poly-propylene film, the electrode from plain foil to either metallized film, metallized paper, or embossed foil, and the fluids have changed f…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Lithium Incorporation by V 6 O 13 and Related Vanadium (+4, +5) Oxide Cathode Materials

D. W. Murphy、P. Christian、F. J. DiSalvo 等 5 位作者1981-10-01Journal of The Electrochemical Society

The known vanadium oxides VO 2 + y ( 0 ≤ y < 0.5 ) have been examined as cathode materials in ambient temperature nonaqueous secondary lithium cells. The discharge products have also been chemically prepared and characterized by x‐ray diffraction, thermal analysis, and magnetic susceptibility. The best cathode materia…

Advancements in Battery MaterialsTransition Metal Oxide NanomaterialsElectron and X-Ray Spectroscopy Techniques

Effect of ionizing radiation on the chemical composition, crystalline content and structure, and flow properties of polytetrafluoroethylene

W. Keith Fisher、J. C. Corelli1981-10-01Journal of Polymer Science Polymer Chemistry Edition

Abstract This article describes a study of ionizing radiation‐induced changes in the chemical composition, crystalline content and structure, and flow properties in polytetrafluoroethylene (PTFE). Irradiatins conducted in the presence of oxygen cause acid fluoride end groups to be formed, which on exposure to water va…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

SETCOL — A Technologically Simple and Reliable Method for Measuring Phytoplankton Sinking Rates

Paul K. Bienfang1981-10-01Canadian Journal of Fisheries and Aquatic Sciences

A simple and reliable method for measuring the sinking rate of phytoplankton is described. This technique is suitable for both heterogeneous field populations and unialgal in vitro cultures. The procedure involves use of settling columns initially containing a uniformly mixed population of cells, and calculates a sink…

Algal biology and biofuel productionDiatoms and Algae Research

The crystal and molecular structure of oxovanadium(V) orthophosphate dihydrate, VOPO4,2H2O

H. Tietze1981-10-01Australian Journal of Chemistry

The structure of a tetragonal crystal of the title compound was determined by X-ray diffraction. The space group was found to be P 4/nmm with a 6.202(2) and c 7.410(1) Å and Z 2. The structure consists of infinite sheets of distorted VO6 octahedra and PO4 tetrahedra linked by shared oxygen atoms. Shared water molecule…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsVanadium and Halogenation Chemistry

Preparation of highly reactive metal powders. New procedure for the preparation of highly reactive zinc and magnesium metal powders

Reuben D. Rieke、Percy Tzu-Jung Li、Timothy P. Burns 等 4 位作者1981-10-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of highly reactive metal powders. New procedure for the preparation of highly reactive zinc and magnesium metal powdersReuben D. Rieke, Percy Tzu-Jung Li, Timothy P. Burns, and Sung T. UhmCite this: J. Org. Chem. 1981, 46, 21, 4323–4324Publication Date (Print):Oc…

Nanomaterials for catalytic reactionsMetallurgical and Alloy Processes

Polymer Collapse

C Williams、F Brochard、H. L. Frisch1981-10-01Annual Review of Physical Chemistry

Machine learning (ML) is transforming all areas of science. The complex and time-consuming calculations in molecular simulations are particularly suitable for an ML revolution and have already been profoundly affected by the application of existing ML ...Read More

Machine Learning in Materials Science

Thin and thick gratings: terminology clarification

Thomas K. Gaylord、M. G. Moharam1981-10-01Applied Optics

Get PDF Email Share Share with Facebook Tweet This Post on reddit Share with LinkedIn Add to CiteULike Add to Mendeley Add to BibSonomy Get Citation Copy Citation Text T. K. Gaylord and M. G. Moharam, "Thin and thick gratings: terminology clarification," Appl. Opt. 20, 3271-3273 (1981) Export Citation BibTex Endnote (…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings