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Lipase-Catalyzed Ring-Opening Polymerizations of 4-Substituted ε-Caprolactones: Mechanistic Considerations

Joris W. Peeters、Oscar Van Leeuwen、Anja R. A. Palmans 等 4 位作者2005-06-01Macromolecules

Lipase-catalyzed ring-opening polymerizations of 4-substituted ε-caprolactones employing Novozym 435 as the biocatalyst demonstrate dramatic differences in polymerization rates and selectivity depending on the size of the substituent. Quantification of the reaction rates shows that the polymerization rate decreases by…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and Bioproduction

A method of determining the effective axial demagnetizing factor of an irregular hexagonal magnetic insulator

J. Helszajn2005-06-01IEEE Microwave and Wireless Components Letters

The shape demagnetizing factors of a planar magnetic insulator are of some interest in the design of a number of microwave ferrite components. One means of experimentally evaluating these quantities, in the case of a disk geometry, is to measure the Kittel line and to make use of a standard identity. Another method, i…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Synthesis of Unsaturated Polyester Resin—Effect of Sequence of Addition of Reactants

Benny Cherian、Eby Thomas Thachil2005-06-01Polymer-Plastics Technology and Engineering

Unsaturated polyesters were synthesized in the laboratory by the condensation of maleic anhydride and phthalic anhydride with propylene glycol. The condensate obtained was mixed with styrene monomer to get an unsaturated polyester resin formulation. The properties of the polyester resin synthesized were found to be af…

Epoxy Resin Curing ProcessesFiber-reinforced polymer compositesSynthesis and properties of polymers

Evaluation of Soil Extractants in Terms of Growth

D. Venkateswara Rao2005-06-01Communications in Soil Science and Plant Analysis

There is a strong criticism against usage of buffered ammonium acetate as an extractant for the determination of exchangeable elements in acid soils dominated by low‐activity clays. There are several reports regarding the use and misuse of diethylene triamine penta acetic acid as a universal extractant for iron, manga…

Plant Micronutrient Interactions and EffectsClay minerals and soil interactionsIron oxide chemistry and applications

Chemical vapour etching of silicon and porous silicon: silicon solar cells and micromachining applications

A. Ben Jaballah、M. Hassen、M. Hajji 等 6 位作者2005-06-01physica status solidi (a)

Abstract In this work, we used HNO 3 /HF Vapour Etching (VE) of silicon (Si) wafers for the formation of different porous structures. Depending on the volume ratio of the HNO 3 /HF acid mixture, we can obtain Porous Silicon (PS) layers or a (NH 4 ) 2 SiF 6 like powder phase. These two kind of porous structures may be…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Polyurethane Foam with a Negative Poisson's Ratio for Diabetic Shoes

K.O. Park、Jong‐Chul Park、Jae Boong Choi 等 6 位作者2005-06-01Key engineering materials

This study fabricated polyurethane foam after transforming the cell structure from a convex polyhedral shape to a concave shape. Polyurethane was synthesized and fabricated after changing the cellular structure of the foam using two methods. Scanning electron microscopy showed that the cellular structure was a more co…

Polymer composites and self-healingAutomotive and Human Injury BiomechanicsPolymer Foaming and Composites

Structure-Property Relationships in Polyoxymethylene/Thermoplastic Polyurethane Elastomer Blends

Krzysztof Pielichowski、Agnieszka Leszczyńska2005-06-01Journal of Polymer Engineering

Article Structure-Property Relationships in Polyoxymethylene/Thermoplastic Polyurethane Elastomer Blends was published on June 1, 2005 in the journal Journal of Polymer Engineering (volume 25, issue 4).

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Electrical Properties of Holmium-Doped BaTiO3

Jaill Jeong、Eun Jung Lee、Young Ho Han2005-06-01Japanese Journal of Applied Physics

The effects of Ho (holmium) doping on the electrical properties and microstructural development of (Ba 1- x Ho x )TiO 3 were investigated by means of defect chemistry on the basis of equilibrium electrical conductivity data measured at 1300°C, as a function of oxygen activity. Ho 2 O 3 additions to BaTiO 3 up to 0.3 m…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

New Approach for Improving UV-Protecting Properties of Woven Cotton Fabrics

Nabil A. Ibrahim、R. Refai、A. F. Ahmed 等 4 位作者2005-06-01Polymer-Plastics Technology and Engineering

This study evaluates the impact of certain finishing formulations, posttreatment with copper acetate as well as type of cotton fabric on the easy-care properties and UV protection of treated fabrics. The results detailed in this article indicate that (1) increasing the finishing agent concentration results in a signif…

Skin Protection and AgingDyeing and Modifying Textile FibersTextile materials and evaluations

Molecular characterization of extracellular medium-chain-length poly(3-hydroxyalkanoate) depolymerase genes from Pseudomonas alcaligenes strains.

Do Young Kim、Hyun Chul Kim、Sun Young Kim 等 4 位作者2005-06-01PubMed

A bacterial strain M4-7 capable of degrading various polyesters, such as poly(epsilon-caprolactone), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), poly(3-hydroxyoctanoate), and poly(3-hydroxy-5-phenylvalerate), was isolated from a marine environment and identified as Pseudomonas alcaligenes. The relative molecular mas…

biodegradable polymer synthesis and propertiesEnzyme Production and CharacterizationCancer-related gene regulation

Qualitative Analysis of Tolerance Factor, Electronegativity and Chemical Bonding of Some Ferroelectric Perovskites Through MOT

K. Singh、Smita Acharya、D. V. Atkare2005-06-01Ferroelectrics

Qualitative analysis of the factors governing variation in T c and P s of PbTiO3, KNbO3 and BaTiO3 members of ABO3 perovskite family considering the parameters like tolerance factor, t, electronic configuration, electronegativity, polarizability and character of bonding using molecular orbital theory (MOT) reveals tha…

Ferroelectric and Piezoelectric MaterialsConducting polymers and applicationsSolid-state spectroscopy and crystallography

Precise Thermal Characterization of Confined Nanocrystalline Silicon by a 3ω Method

Takashi Kihara、T. Harada、Nobuyoshi Koshida2005-06-01Japanese Journal of Applied Physics

Due to a strong quantum confinement effect, the thermal conductivity and heat capacity per unit volume of a nanocrystalline silicon (nc-Si) layer prepared by electrochemical anodization are extremely lowered in comparison to those of single crystal silicon (c-Si). Based on this high contrast between the thermal proper…

Silicon Nanostructures and PhotoluminescenceThermal properties of materialsThermal Radiation and Cooling Technologies

Selecting the optimal neural network architecture for predicting cotton yarn hairiness

Amel Babay、Morched Cheikhrouhou、Brecht Vermeulen 等 5 位作者2005-06-01Journal of the Textile Institute

Models for predicting ring yarn hairiness are built using backpropagation neural network algorithm and linear regression analysis. An original approach dealing with overfitting and allowing the selection of the optimal neural network architecture is used. It is based on the estimation of the leverages, i.e. the influe…

Dyeing and Modifying Textile FibersTextile materials and evaluationsIndustrial Vision Systems and Defect Detection

Three-Dimensional Image Sensing in Air by Thermally Induced Ultrasonic Emitter Based on Nanocrystalline Porous Silicon

Kenji Tsubaki、Hiroshi Yamanaka、Kosaku Kitada 等 5 位作者2005-06-01Japanese Journal of Applied Physics

Ultrasonic three-dimensional (3-D) image sensing in air is successfully demonstrated by combining a novel thermally induced ultrasonic emission from nanocrystalline porous silicon (nc-PS) device with a condenser microphone array. The nc-PS ultrasonic emitter is composed of a patterned heater electrode, an nc-PS layer,…

Gas Sensing Nanomaterials and SensorsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Effect of Microstructure on Dielectric Properties of Si<sub>3</sub>N<sub>4</sub> at Microwave Frequency

Min Kyu Park、Ha‐Neul Kim、Kee Sung Lee 等 7 位作者2005-06-01Key engineering materials

Silicon nitride (Si3N4) has been researched intensively because of superior mechanical properties up to high temperature. The mechanical properties of Si3N4 are strongly related to microstructure. The microstructure control of silicon nitride is well known to be a key issue for tailoring the mechanical properties of s…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsMicrowave Dielectric Ceramics Synthesis

High‐aspect‐ratio silicon dioxide pillars

T. Trifonov、A. Rodrı́guez、F. Servera 等 6 位作者2005-06-01physica status solidi (a)

Abstract This paper presents a technique for fabricating high‐aspect‐ratio silicon dioxide pillars by electrochemical etching of n‐type silicon in hydrofluoric acid (HF) solutions. Basic process flow and etching conditions are described, which make it possible to obtain high‐aspect‐ratio pillar arrays with good unifor…

Advanced MEMS and NEMS TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Effect of the hydrocarbon molecular structure in diesel fuel on the in-cylinder soot formation and exhaust emissions

Kiyomi Nakakita、Kazuhiro Akihama、W. Weissman 等 4 位作者2005-06-01International Journal of Engine Research

Evaluations of diesel fuel effects on combustion and exhaust emissions in single-cylinder direct-injection diesel engines led to the unexpected result that a Swedish ‘class 1’ fuel generated more particulate matter (PM) than a fuel denoted ‘improved’, even though ‘class 1’ fuel had much lower distillation temperatures…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Determination of Moisture Diffusivity by Thermo-Gravimetric Analysis under Non-Isothermal Condition

Zhanyong Li、Noriyuki Kobayashi2005-06-01Drying Technology

: In drying of solids, the diffusion model based on Fick's second law is usually applied to interpret the moisture migration within the solid. Then the temperature dependence of the moisture diffusivity, generally described by an Arrhenius-type equation, is obtained through the drying kinetics. In this article, a noni…

Food Drying and ModelingEpoxy Resin Curing ProcessesThermal and Kinetic Analysis

Surface engineering for thermal control of spacecraft

Anand Sharma2005-06-01Surface Engineering

Surface engineering plays an important role in aerospace and allied applications. Finishing for space applications, however, requires higher standards and better control than those used for ground applications, because an on-orbit spacecraft is not approachable for repair and space conditions are severe. Mass reductio…

Solidification and crystal growth phenomenaMetallurgical Processes and ThermodynamicsSpacecraft Design and Technology

Corrosion behaviour of aluminium in rain water containing garlic extract

S. Lakshmi Priya、A. Chitra、S. Rajendran 等 4 位作者2005-06-01Surface Engineering

The inhibition efficiency of an aqueous extract of garlic in controlling corrosion of aluminium immersed in sodium hydroxide solution at pH 11 and 12, in the absence and presence of Zn 2+ , was evaluated by the weight loss method. At pH 11, the extract accelerated corrosion of aluminium in the absence and presence of…

Concrete and Cement Materials ResearchCorrosion Behavior and InhibitionConcrete Corrosion and Durability