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Some Observations on Times to Equilibrium for Semivolatile Polycyclic Aromatic Hydrocarbons

Richard M. Kamens、Jay R. Odum、Zhi Hua Fan1995-01-01Environmental Science & Technology

The relative time scales at which semivolatile gas and particle PAH approach equilibrium under both moderate and cool temperatures were investigated. Combustion particles were added directly from a diesel car and a wood stove to a 190 m^3 outdoor Teflon film chamber. The rate of migration of a gas-phase semivolatile P…

Carbon Nanotubes in CompositesPhase Equilibria and ThermodynamicsAdvanced Physical and Chemical Molecular Interactions

Immobilization of small proteins in carbon nanotubes: high-resolution transmission electron microscopy study and catalytic activity

Shik Chi Edman Tsang、Jason J. Davis、Malcolm L. H. Green 等 6 位作者1995-01-01Journal of the Chemical Society Chemical Communications

The morphologies of the small proteins Zn2Cd5-metallothionein, cytochrome c3 and β-lactamase I immobilized inside carbon nanotubes have been studied by high-resolution transmission electron microscopy (HRTEM); single protein molecules and their associated forms were clearly observed inside the central cavity and a sig…

Carbon Nanotubes in CompositesAdvanced Electron Microscopy Techniques and ApplicationsEnzyme Structure and Function

A general formula for prediction of iron losses under nonsinusoidal voltage waveform

M. Amar、Robert Kaczmarek1995-01-01IEEE Transactions on Magnetics

A simple and efficient method for the estimation of iron loss under any nonsinusoidal voltage without multiple zero crossings (i.e. without minor hysteresis loops) is proposed. This method is based on the loss separation model, where iron loss is decomposed into hysteresis, classical and excess loss components. The vo…

Power Quality and HarmonicsMagnetic Properties and ApplicationsPower Transformer Diagnostics and Insulation

Preparation and characterisation of mesoporous, high surface area zirconium(IV) oxides

James A. Knowles、Michael J. Hudson1995-01-01Journal of the Chemical Society Chemical Communications

High surface area, mesoporous zirconium(IV) oxides may be prepared by controlled heating of a surfactant–zirconium(IV) oxide composite in which the surfactant acts as a combined drying-control and scaffolding agent.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Destruction of Formaldehyde with Dielectric Barrier Discharge Plasmas

Moo Been Chang、Chin Ching. Lee1995-01-01Environmental Science & Technology

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDestruction of Formaldehyde with Dielectric Barrier Discharge PlasmasMoo Been. Chang and Chin Ching. LeeCite this: Environ. Sci. Technol. 1995, 29, 1, 181–186Publication Date (Print):January 1, 1995Publication History Published online1 May 2002Published inissue 1 January 199…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Energy Transfer in Mechanical Alloying (<I>Overview</I>)

M. Magini、A. Iasonna1995-01-01Materials Transactions JIM

It is essential to understand in which way and how much energy is transferred from the milling tools to the powder in the milling process. We have attempted to quantify the energy transferred per impact and per unit of mass in a planetary mill assuming that collision is the dominant energy transfer event. Further, att…

High-Velocity Impact and Material BehaviorMineral Processing and GrindingMetallurgy and Cultural Artifacts

Phase diagrams and crystal chemistry in the Li + ion conducting perovskites, Li 0.5 – 3x RE 0.5 +x TiO 3 : ReLa, Nd

A. Robertson、Susana García Martín、Alison M. Coats 等 4 位作者1995-01-01Journal of Materials Chemistry

The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5 – 3xRE0.5 +xTiO3: RELa, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in t…

Ferroelectric and Piezoelectric MaterialsAdvanced Battery Materials and TechnologiesMicrowave Dielectric Ceramics Synthesis

Adsorption of Branched and Cyclic Paraffins in Silicalite. 1. Equilibrium

Célio L. Cavalcante、Douglas M. Ruthven1995-01-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of Branched and Cyclic Paraffins in Silicalite. 1. EquilibriumCelio L. Jr. Cavalcante and Douglas M. RuthvenCite this: Ind. Eng. Chem. Res. 1995, 34, 1, 177–184Publication Date (Print):January 1, 1995Publication History Published online1 May 2002Published inissue…

Zeolite Catalysis and SynthesisClay minerals and soil interactionsSurface Chemistry and Catalysis

Triphenylene-Based Discotic-Liquid-Crystalline Polymers: A Universal, Rational Synthesis

N. Boden、Richard J. Bushby、Andrew N. Cammidge1995-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTriphenylene-Based Discotic-Liquid-Crystalline Polymers: A Universal, Rational SynthesisNeville Boden, Richard J. Bushby, and Andrew N. CammidgeCite this: J. Am. Chem. Soc. 1995, 117, 3, 924–927Publication Date (Print):January 1, 1995Publication History Published online1 May…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPhase-change materials and chalcogenides

Flashover mechanism of silicone rubber insulators used for outdoor insulation-I

G.G. Karady、M. Shah、Richard L. Brown1995-01-01IEEE Transactions on Power Delivery

Experimental results show that the contamination performance of silicone rubber composite insulators is better than porcelain insulators. This is attributed to the hydrophobicity of the silicone rubber. This suggests that the flashover mechanism of these insulators is different. This paper experimentally investigates…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationThermal Analysis in Power Transmission

Design of luminescent building blocks for supramolecular triple-helical lanthanide complexes

Claude Piguet、Jean‐Claude G. Bünzli、Gérald Bernardinelli 等 5 位作者1995-01-01Journal of the Chemical Society Dalton Transactions

The ligand 2,6-bis(1′-ethyl-5′-methylbenzimidazol-2′-yl)pyridine (L5) reacts with lanthanide perchlorate in acetonitrile to give the mononuclear triple-helical complexes [Ln(L5)3]3+(Ln = Eu, Gd or Tb). The crystal structure of [Eu(L5)3][ClO4]3·4MeCN has been determined, which shows three unco-ordinated perchlorate ani…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The First Bis(.mu.-oxo)diiron(III) Complex. Structure and Magnetic Properties of [Fe2(.mu.-O)2(6TLA)2](ClO4)2

Yan Zang、Yanhong Dong、Lawrence Que 等 5 位作者1995-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe First Bis(.mu.-oxo)diiron(III) Complex. Structure and Magnetic Properties of [Fe2(.mu.-O)2(6TLA)2](ClO4)2Yan Zang, Yanhong Dong, Lawrence Que Jr., Karl Kauffmann, and Eckard MuenckCite this: J. Am. Chem. Soc. 1995, 117, 3, 1169–1170Publication Date (Print):January 1, 199…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

NO Reduction by Activated Carbons. 2. Catalytic Effect of Potassium

María José Illán Gómez、Á. Linares-Solano、Ljubis̆a R. Radović 等 4 位作者1995-01-01Energy & Fuels

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNO Reduction by Activated Carbons. 2. Catalytic Effect of PotassiumM. Jose Illan-Gomez, Angel Linares-Solano, Ljubisa R. Radovic, and Concepcion Salinas-Martinez de LeceaCite this: Energy Fuels 1995, 9, 1, 97–103Publication Date (Print):January 1, 1995Publication History Pub…

Catalytic Processes in Materials Science

Thin films for optical systems

F. Flory1995-01-01M. Dekker eBooks

Part 1 Coating design: thin-film optical coating design. Part 2 Deposition techniques and related topics: starting materials optical monitoring reactive physical vapor deposition processes ion assisted deposition ion beam sputtering plasma impulse chemical vapor deposition molecular beam deposition uniformity. Part 3…

Optical Coatings and GratingsSurface Roughness and Optical Measurements

Effect of SiC Submicrometer Particle Size and Content on Fracture Toughness of Alumina–SiC “Nanocomposites”

Igor Levin、Wayne D. Kaplan、David Brandon 等 4 位作者1995-01-01Journal of the American Ceramic Society

A simple model was developed which describes the effect of SiC submicrometer particles on the fracture toughness of alumina–SiC “nanocomposites.” This effect was attributed to the change in the fracture mode observed in alumina on adding SiC submicrometer particles, which was suggested to be a result of both matrix we…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisAluminum Alloys Composites Properties

Strength and Young's Modulus Behavior of a Partially Sintered Porous Alumina

Savitha C. Nanjangud、Rasto Brezny、David J. Green1995-01-01Journal of the American Ceramic Society

The strength of alumina materials that had been subjected to varying degrees of densification was determined. Significant increases in strength were obtained for these materials even when there was minimal densification. For the most porous materials, the Weibull modulus values were similar but showed a significant in…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesComposite Material Mechanics

Characterisation of moderately acid-treated, size-fractionated montmorillonites using IR and MAS NMR spectroscopy and thermal analysis

C. Breen、Jana Madejová、Peter Komadel1995-01-01Journal of Materials Chemistry

The < 2 µm fractions of Cheto (Arizona, USA) and Jelšový Potok (Slovakia) montmorillonites have been treated with 1 mol dm–3 H2SO4 for periods up to 6 h at 95 °C. The materials obtained were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), infrared (IR) spectroscopy, and 29Si and 27Al magic-angle spi…

Polymer Nanocomposites and PropertiesClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

N-methyltetraphenylporphyrin with an inverted N-methylpyrrole ring: the first isomer of N-methyltetraphenylporphyrin

Piotr J. Chmielewski、Lechosław Latos‐Grażyński1995-01-01Journal of the Chemical Society Perkin Transactions 2

In the course of the mild methylation of 5,10,15,20-tetraphenyl-21-carbaporphyrin (CTPPH2) a novel isomer of N-methyl-5,10,15,20-tetraphenylporphyrin with an inverted N-methylated pyrrole ring, i.e. 2-N-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrin (2-NCH3TPPH) has been synthesised. The protonation of 2-NCH3CTPPH pr…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Thread biomechanics in the two orb‐weaving spiders Araneus diadematus (Araneae, Araneidae) and Uloborus walckenaerius (Araneae, Uloboridae)

Tamara Köhler、Fritz Vollrath1995-01-01Journal of Experimental Zoology

Abstract The absorption of high kinetic energy by a small amount of material depends not only on the quality of the material but also on the structural design of the elements involved. Using a rapid response microbalance, we measured the tensions of radial threads in webs of the garden cross spider, Araneus diadematus…

Insect and Arachnid Ecology and BehaviorSilk-based biomaterials and applicationsSpider Taxonomy and Behavior Studies