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Preparation and properties of heat curable blended methylfluorosilicone rubber

Yuetao Liu、Hongzhi Liu、Rong Zhang 等 5 位作者2012-07-06Polymer Engineering and Science

Abstract Heat curable blended methylfluorosilicone rubber (MFSR) was prepared by combination of methylsilicone rubber (MSR) and fluorosilicone rubber (FSR). 2,5‐Bis(tert‐butylperoxy)‐2,5‐dimethylhexane (DBPMH) was chosen as a curing agent. Poly(methylsiloxane‐ co ‐fluorosiloxane) with low molecular weight was used as…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Simultaneous measurement of X-ray diffraction and ferroelectric polarization data as a function of applied electric field and frequency

Jenny Wooldridge、Steph Ryding、S. D. Brown 等 9 位作者2012-07-06Journal of Synchrotron Radiation

The characteristics of a new ferroelectric measurement system at the European Synchrotron Radiation Facility are presented. The electric-field-induced phase transitions of Pb(Mg(1/3)Nb(2/3))O(3)-xPbTiO(3) are determined via in situ measurements of electric polarization within the synchrotron diffraction beamline. Real…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Wettability of dragonfly wings: the structure detection and theoretical modeling

Chunying Gao、Guixian Meng、Xin Li 等 9 位作者2012-07-06Surface and Interface Analysis

Hydrophobic surfaces have gained extensive attention in recent decades for their potential applications. The hydrophobic properties of dragonfly's ( Pantala flavescens ) wings were measured, and the water contact angles (WCAs) of the distal and basal part of a dragonfly's wing were 134.9° and 125.8°, respectively. Ima…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsIcing and De-icing Technologies

Graphene Sheet Orientation of Parent Material Exhibits Dramatic Influence on Graphene Properties

Chun Kiang Chua、Zdeněk Sofer、Martin Pumera2012-07-06Chemistry - An Asian Journal

The production of graphene from various sources has garnered much attention in recent years with the development of methods that range from "bottom-up" to "top-down" approaches. The top-down approach often requires thermal treatment to obtain a few-layered and lowly oxygenated graphene sheets. Herein, we demonstrate t…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

19F MRI Monitoring of Gene Expression in Living Cells through Cell‐Surface β‐Lactamase Activity

Hisashi Matsushita、Shin Mizukami、Yuki Mori 等 7 位作者2012-07-06ChemBioChem

Magnetic resonance imaging provides important intravital information on deep tissues that cannot be visualized by other methods. Although we had previously developed an off/on switching (19)F MRI probe to monitor reporter enzyme activity on the basis of the paramagnetic relaxation enhancement effect, it was difficult…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Growth Mechanism of Microporous Zincophosphate Sodalite Revealed by In Situ Atomic Force Microscopy

Mark A. Holden、Pablo Cubillas、Martin P. Attfield 等 5 位作者2012-07-06Journal of the American Chemical Society

Microporous zincophosphate sodalite crystal growth has been studied in situ by atomic force microscopy. This simple model system permits an in depth investigation of some of the axioms governing crystal growth of nanoporous framework solids in general. In particular, this work reveals the importance of considering the…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesChemical Synthesis and Characterization

Magnetic excitations in underdoped Ba(Fe1−xCox)2As2withx=0.047

G. S. Tucker、Rafael M. Fernandes、Haifeng Li 等 11 位作者2012-07-06Physical Review B

The magnetic excitations in the paramagnetic-tetragonal phase of underdoped Ba(Fe${}_{0.953}$Co${}_{0.047}$)${}_{2}$As${}_{2}$, as measured by inelastic neutron scattering, can be well described by a phenomenological model with purely diffusive spin dynamics. At low energies, the spectrum around the magnetic ordering…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Power-Law Kinetics in the Photoluminescence of Dye-Sensitized Nanoparticle Films: Implications for Electron Injection and Charge Transport

Ian J. McNeil、Dennis L. Ashford、Hanlin Luo 等 4 位作者2012-07-06The Journal of Physical Chemistry C

Dye-sensitized solar cells have provided a model to inexpensively harness solar energy, but the underlying physics that limit their efficiency are still not well understood. We probe electron injection in sensitized nanocrystalline TiO 2 films using time-correlated single photon counting (TCSPC) to measure time-depend…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesElectrochemical Analysis and Applications

Valley polarized electronic transmission through a line defect superlattice of graphene

Xiaoling Lü、Zhe Liu、Haibo Yao 等 6 位作者2012-07-06Physical Review B

The band structure of a one-dimensional superlattice formed by patterning graphene lattice with a periodic line defect array is calculated. The lowest conduction subband of such a superlattice connects two inequivalent Dirac points with flat dispersion, which is reminiscent of the flat-bottomed subband of a zigzag-edg…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Real time in situ spectroscopic ellipsometry of the growth and plasmonic properties of au nanoparticles on SiO2

H. T. Beyene、J. W. Weber、Marcel A. Verheijen 等 5 位作者2012-07-06Nano Research

The evolution of the film thickness and plasmonic properties for sputtered deposited Au nanoparticles on SiO2 layers have been monitored in real time using in situ spectroscopic ellipsometry in the photon energy range 0.75–4.1 eV. The spectroscopic ellipsometry data were analyzed with an optical model in which the opt…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials Studiesnanoparticles nucleation surface interactions

Bimetallic Multifunctional Core@Shell Plasmonic Nanoparticles for Localized Surface Plasmon Resonance Based Sensing and Electrocatalysis

Ji‐Eun Lee、Kyungwha Chung、Yoon Hee Jang 等 7 位作者2012-07-06Analytical Chemistry

Smart bimetallic core@shell nanoparticles were fabricated based on gold nanoparticles (AuNPs) decorated with pH-sensitive polymer shell. Concretely, AuNPs having poly(4-vinylpyridine) (P4VP) on the surface were first fabricated through surface-initiated atom transfer radical polymerization (SI-ATRP). Then, they were m…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

Partial discharge recognition based on SF 6 decomposition products and support vector machine

Jiren Tang、F. Liu、Xiaoxing Zhang 等 5 位作者2012-07-06IET Science Measurement & Technology

Partial discharge (PD) is usually aroused before the failure of gas-insulated switchgear (GIS) caused by insulation defects, which results in the decomposition of SF6 used as insulation gas. Concentrations of decomposition products of SF6 under different kinds of PDs are disparate. Thus, SF6 decomposition products can…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElevator Systems and Control

Morphological and Rheological Insights on Polyimide Chain Entanglements for Electrospinning Produced Fibers

Ştefan Chişcă、Andreea Irina Barzic、Ion Sava 等 5 位作者2012-07-06The Journal of Physical Chemistry B

Solution rheology and electrospinning performance of an aromatic polyimide based on 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) and 3,3'-dimethyl-4,4'-diaminodiphenylmethane (MMDA) was studied. Analyzing the dependence of specific viscosity on polymer concentration enabled the evaluation of the transition…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Single-Molecule Tracking Studies of Millimeter-Scale Cylindrical Domain Alignment in Polystyrene–Poly(ethylene oxide) Diblock Copolymer Films Induced by Solvent Vapor Penetration

Khanh‐Hoa Tran‐Ba、Jason J. Finley、Daniel A. Higgins 等 4 位作者2012-07-06The Journal of Physical Chemistry Letters

Single-molecule tracking (SMT) was used to probe the alignment of cylindrical microdomains in polystyrene–poly(ethylene oxide) diblock copolymer (PS- b -PEO) films induced by directional solvent penetration. PS- b -PEO films were supported between two glass plates. Aligned PEO domains were obtained upon horizontal pen…

Force Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesBlock Copolymer Self-Assembly

Nanocomposites of Ni(OH)2/Reduced Graphene Oxides with Controllable Composition, Size, and Morphology: Performance Variations as Pseudocapacitor Electrodes

Junwu Xiao、Shihe Yang2012-07-06ChemPlusChem

Abstract Although Ni(OH) 2 is a promising electrode material for electrochemical capacitors on account of its high theoretical specific capacitance and low cost, its application has been hindered by the low measured specific capacitance and poor cycle stability often associated with low specific surface area and poor…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Scanning Probe Manipulation of Magnetism at the LaAlO3/SrTiO3 Heterointerface

Beena Kalisky、Julie A. Bert、Christopher Bell 等 9 位作者2012-07-06Nano Letters

Manipulation of magnetism is a longstanding goal of research in exotic materials. In this work, we demonstrate that the small ferromagnetic patches in LaAlO(3)/SrTiO(3) heterostructures can be dramatically changed by in situ contact of a scanning probe. Our results provide a platform for manipulation of small magnets…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Experimental Confirmation of Local Field Enhancement Determining Far‐Field Measurements with Shell‐Isolated Silver Nanoparticles

Ariel R. Guerrero、Yun Zhang、Ricardo F. Aroca2012-07-06Small

The first direct experimental evidence for the dependence on the local field enhancement with Raman/fluorescence measurements in the far field is provided. This is achieved using shell-isolated silver nanoparticles permitting recording both the surface-enhanced Raman scattering (SHINERS) and surface-enhanced fluoresce…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

Biocompatibility of fluoride‐coated magnesium‐calcium alloys with optimized degradation kinetics in a subcutaneous mouse model

Andreas Drynda、Juliane Seibt、Thomas Hassel 等 5 位作者2012-07-06Journal of Biomedical Materials Research Part A

The principle of biodegradation has been considered for many years in the development of cardiovascular stents, especially for patients with congenital heart defects. A variety of materials have been examined with regard to their suitability for cardiovascular devices. Iron- and magnesium-based stents were investigate…

Magnesium Alloys: Properties and ApplicationsHydrogen Storage and MaterialsCardiac Structural Anomalies and Repair

Benthic diatoms (Bacillariophyta) from seepages and streams on James Ross Island (NW Weddell Sea, Antarctica)

Kateřina Kopalová、Jana Veselá、Josef Elster 等 6 位作者2012-07-06Plant Ecology and Evolution

Background and aim – The non-marine diatom communities in the Antarctic Region are characterized by a typical species composition, in close relationship with their environment. Despite the growing interest, the diatom flora of James Ross Island is only poorly known. The present paper discusses the diversity of limnote…

Microbial Community Ecology and PhysiologyDiatoms and Algae ResearchPolar Research and Ecology

Synthesis of Porous Carbon Balls from Spherical Colloidal Crystal Templates

Youngchan Kim、Chang‐Yeol Cho、Ji‐Hwan Kang 等 5 位作者2012-07-06Langmuir

Spherical inverse opal (IO) porous carbon was produced utilizing silica colloidal crystal spheres as templates. The spherical colloidal crystals were obtained through the self-assembly of monodisperse particles inside an emulsion droplet with confined geometry. The templates were inverted using a carbon precursor, phe…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisPorphyrin and Phthalocyanine Chemistry