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Solubility of Xylose, Mannose, Maltose Monohydrate, and Trehalose Dihydrate in Ethanol–Water Solutions

Xingchu Gong、Chuan Wang、Lei Zhang 等 4 位作者2012-10-24Journal of Chemical & Engineering Data

The solubilities of (2 R,3 S,4 R )-2,3,4,5-tetrahydroxypentanal (xylose), (2 R,3 R,4 R,5 R )-2,3,5,6-tetrahydroxy-4-[(2 R,3 R,4 S,5 S,6 R )-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexanal hydrate (maltose monohydrate), (2 R,3 S,4 S,5 R,6 R )-2-(hydroxymethyl)-6-[(2 R,3 R,4 S,5 S,6 R )-3,4,5-trihydroxy-6-(hydrox…

Phase Equilibria and ThermodynamicsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Interaction Between Polymer Brush-Coated Spherical Nanoparticles: Effect of Solvent Quality

Federica Lo Verso、S. A. Egorov、Kurt Binder2012-10-24Macromolecules

The interaction between two spherical polymer brushes in solvents of variable quality is studied by molecular dynamics simulation and by self-consistent field theory, varying both the radius of the spherical particles and their distance, as well as the grafting density and the chain length of the end-grafted flexible…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

A Self‐Contained Regeneration Scheme for Spent Ammonia Borane Based on the Catalytic Hydrodechlorination of BCl3

Christian Reller、Florian Mertens2012-10-24Angewandte Chemie International Edition

Recycling: A self-contained procedure for the recycling of BNH-waste, based on the three major steps: polymer break-up, amine supported catalytic hydrodehalogenation of boron halogens, and the base exchange in borane amine adducts, is developed (see picture). Beyond the original task of recycling spent ammonia borane,…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionChemical Synthesis and Characterization

Enhanced Ultraviolet Emission from Poly(vinyl alcohol) ZnO Nanoparticles Using a SiO2–Au Core/Shell Structure

Dali Shao、Hongtao Sun、Mingpeng Yu 等 5 位作者2012-10-24Nano Letters

Enhanced near band gap edge (NBE) emissions of PVA-ZnO nanoparticles were achieved by employing SiO(2)-Au core/shell nanostructures whereas the defect-level emission (DLE) is greatly suppressed. A maximum enhancement of nearly 400% was observed using SiO(2)-Au for the emission with optical resonance at 554 nm. SiO(2)-…

ZnO doping and propertiesGold and Silver Nanoparticles Synthesis and ApplicationsGa2O3 and related materials

Fluorescence Correlation Spectroscopy Directly Monitors Coalescence During Nanoparticle Preparation

David Schaeffel、Roland H. Staff、Hans‐Jürgen Butt 等 6 位作者2012-10-24Nano Letters

Dual color fluorescence cross-correlation spectroscopy (DC FCCS) experiments were conducted to study the coalescence and aggregation during the formation of nanoparticles. To assess the generality of the method, three completely different processes were selected to prepare the nanoparticles. Polymeric nanoparticles we…

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsPhotochemistry and Electron Transfer Studies

Solution Crystallization of Vanillin in the Presence of a Liquid–Liquid Phase Separation

Haiping Zhao、Chuang Xie、Xu Zhao 等 7 位作者2012-10-24Industrial & Engineering Chemistry Research

The crystallization process of vanillin in a 1-propanol/water system was investigated. It was found that liquid–liquid phase separation, also termed oiling out, will happen under some conditions. To fully understand this process, the oiling out as well as the following nucleation and crystal growth of this compound we…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesBiochemical and biochemical processes

Exotic Cubic Carbon Allotropes

Meng Hu、Fei Tian、Zhisheng Zhao 等 9 位作者2012-10-24The Journal of Physical Chemistry C

Elemental carbon exists in various aesthetically pleasing architectures. These forms include a group of synthesized allotropes with cubic modifications that have taken controversial or even unidentified crystal structures, which makes determining their physical properties difficult. In this study, four novel cubic car…

Graphene research and applicationsFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

Shape memory characteristics of woven glass fibre fabric reinforced epoxy composite in flexure

Márta Fejős、Gábor Romhány、J. Karger‐Kocsis2012-10-24Journal of Reinforced Plastics and Composites

Shape memory characteristics of a woven glass fibre fabric reinforced epoxy composite (reinforcement content: 38 vol.%) were assessed in three-point bending mode in a dynamic mechanical analysis device and compared to those of the parent epoxy resin. From unconstrained tests, the shape fixity and recovery ratios and t…

Mechanical Behavior of CompositesPolymer composites and self-healingSilk-based biomaterials and applications

Synthesis of PEGylated gold nanostars and bipyramids for intracellular uptake

Julien R. G. Navarro、Delphine Manchon、Frédéric Lerouge 等 15 位作者2012-10-24Nanotechnology

A great number of works have focused their research on the synthesis, design and optical properties of gold nanoparticles for potential biological applications (bioimaging, biosensing). For this kind of application, sharp gold nanostructures appear to exhibit the more interesting features since their surface plasmon b…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

The Structure of MLn(hfbc)4 and a Key to High Circularly Polarized Luminescence

Sebastiano Di Pietro、Lorenzo Di Bari2012-10-24Inorganic Chemistry

The heterobimetallic complex CsEu[(+)-hfbc](4) (hfbc = 3-heptafluorobutyryl camphorate), prepared by Kaizaki and co-workers, displays the highest ratio of polarization versus total luminescence (measured by the g(lum) factor), i.e., ~85% of the emitted photons at 595 nm are left-circularly polarized. We present a deta…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

A review of multiscale composite manufacturing and challenges

Micah CL McCrary-Dennis、Okenwa I. Okoli2012-10-24Journal of Reinforced Plastics and Composites

As the utilization of advanced composites in structural applications grows, the need for improving their through-thickness properties becomes imperative. Although the behavior of composite laminates under structural and thermal loads has received much attention with their growth in safety critical structures, more eff…

Carbon Nanotubes in CompositesDielectric materials and actuatorsSmart Materials for Construction

On the use of modification functions when Fourier transforming total scattering data

Alan K. Soper、Emma R. Barney2012-10-24Journal of Applied Crystallography

When Fourier transforming radiation total scattering data to the pair distribution function it is common to use a `modification' function to help reduce the termination ripples that would otherwise occur as a result of the finite range and counting statistics of the scattering data. One of the most common functions em…

High-pressure geophysics and materialsGlass properties and applicationsX-ray Diffraction in Crystallography

Ising Universality Class for the Liquid-Liquid Critical Point of a One Component Fluid: A Finite-Size Scaling Test

Paola Gallo、Francesco Sciortino2012-10-24Physical Review Letters

We present a finite-size scaling study of the liquid-liquid critical point in the Jagla model, a prototype model for liquids that present the same thermodynamic anomalies which characterize liquid water. Performing successive umbrella sampling grand canonical Monte Carlo simulations, we evaluate an accurate density of…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

A Critical Review of Basic Crystallography to Salt Crystallization Fouling in Heat Exchangers

Xu Zhao、Xiao Dong Chen2012-10-24Heat Transfer Engineering

Fouling formation on heat exchanger surfaces due to crystallization of inverse solubility salts is one of the fundamental problems in process industries. Despite numerous studies carried out in recent years, comprehensive understanding of crystallization fouling mechanism remains a challenge to chemical engineers. In…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Novel drug carriers: from grafted polymers to cross-linked vesicles

Jiangtao Xu、Qiang Fu、Jing Ren 等 5 位作者2012-10-24Chemical Communications

A simple and straightforward method of self-assembling grafted copolymers was developed to fabricate cross-linked polymer vesicles, which could conjugate anticancer drug cis-platinum and possess the capability of a high drug loading content, and a steady release rate.

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Fano-Like Resonances Arising from Long-Lived Molecule-Plasmon Interactions in Colloidal Nanoantennas

Renee R. Frontiera、Natalie L. Gruenke、Richard P. Van Duyne2012-10-24Nano Letters

We examine ultrafast dynamics in a coupled molecule-plasmon system. Using a new ultrafast Raman technique called surface enhanced-femtosecond stimulated Raman spectroscopy (SE-FSRS), we prove that plasmonic nanoparticles and adsorbed molecules are coupled by the appearance of Fano-like lineshapes, which arise from the…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchSpectroscopy and Quantum Chemical Studies

Experimental Realization of a Metamaterial Detector Focal Plane Array

David Shrekenhamer、Wangren Xu、Suresh Venkatesh 等 6 位作者2012-10-24Physical Review Letters

We present a metamaterial absorber detector array that enables room-temperature, narrow-band detection of gigahertz (GHz) radiation in the S band (2-4 GHz). The system is implemented in a commercial printed circuit board process and we characterize the detector sensitivity and angular dependence. A modified metamateri…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Three-dimensional plastic response in polycrystalline coppervianear-field high-energy X-ray diffraction microscopy

Shiu Fai Li、Jonathan Lind、Christopher M. Hefferan 等 7 位作者2012-10-24Journal of Applied Crystallography

The evolution of the crystallographic orientation field in a polycrystalline sample of copper is mapped in three dimensions as tensile strain is applied. Using forward-modeling analysis of high-energy X-ray diffraction microscopy data collected at the Advanced Photon Source, the ability to track intragranular orientat…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsComposite Material Mechanics

A new strategy for the surface-free-energy-distribution induced selective growth and controlled formation of Cu 2 O–Au hierarchical heterostructures with a series of morphological evolutions

Han Zhu、Mingliang Du、Dongliang Yu 等 8 位作者2012-10-24Journal of Materials Chemistry A

A strategy of surface-free-energy-distribution induced selective growth of Au nanograins (AuNGs) on specific positions of Cu2O octahedron surfaces with a series of morphological evolutions has been demonstrated. The surface energy distribution of Cu2O octahedra generally follows the order of {111} facets < crystal edg…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications