Materials Literature
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cis-Biphenyl-2,3-dihydrodiol-2,3-dehydrogenase (BphB) is involved in the aerobic biodegradation of polychlorinated biphenyls (PCBs). The crystal structure of the NAD+-enzyme complex was determined by molecular replacement and refined to an R-value of 17.9% at 2.0 A. As a member of the short-chain alcohol dehydrogenase…
A model of strength degradation for ceramics subject to damage from contact with hard spheres is developed. Primary attention is focused on tough ceramics with heterogeneous microstructures which deform in a quasi‐plastic mode. Brief consideration is also given to ideally brittle ceramics which form classical ring cra…
Several photosensitive polyimide (PSPI) precursors were synthesised by the acid/base complexations of conventional poly(amic acid) precursors with photochemically cross-linkable 2-(dimethylamino)ethyl methacrylate. PSPIs in films were prepared from the photosensitive precursors by thermal imidisation, whereas the corr…
The new compounds N -phenyl-4,4‘-bipyridinium (PhQ + ), N -(4-acetylphenyl)-4,4‘-bipyridinium (4-AcPhQ + ), and N -(2,4-dinitrophenyl)-4,4‘-bipyridinium (2,4-DNPhQ + ), together with the known ligand N -methyl-4,4‘-bipyridinium (MeQ + ), have been used to prepare a series of Ru(II) complex salts trans -[Ru(NH 3 ) 4 (L…
Single-crystal Ni2MnGa shows a nearly 0.2% strain under a magnetic field of 8 kOe at −8 °C. Polycrystalline samples have been prepared near stoichiometry to study the composition dependence of the magnetic and elastic properties. A narrow band of compositions has been found having a range of Curie and martensitic tran…
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Highly smooth and particulate free relatively thick polycrystalline La0.7Sr0.3MnO3 films out to 6 μm thick have been grown by shadowed pulse laser deposition at 30 Hz (248 nm, 500 mJ). Such films exhibited a low field and high field magnetoresistance as previously reported by a number of groups. Multilayer films made…
Hexagonal (Na 3/4 K 1/4 )AlGeO 4 crystallizes in the space group P 6 3 with unit-cell parameters a = 10.164 (2), c = 8.540 (2) Å and Z = 8 [ wR ( F 2 ) = 0.066 for all 3060 independent reflections]. Monoclinic (Na 3/4 K 1/4 )AlGeO 4 crystallizes in the space group P 2 1 with unit-cell parameters a = 10.0477 (4), b = 8…
We present a combined experimental and theoretical study of the formation of silicon hydride surface species during the F2 laser (157 nm) chemical vapor deposition of amorphous hydrogenated silicon (a-Si:H). A one-dimensional stochastic model has been applied to simulate the growing surface. The predictions of the mod…
The fabrication process of color filters produced with a series of new pigmented photoresists (CX513RGB) and their performance are described. The novel resist materials offer excellent contrast, good film uniformity and a stable shelf life exceeding 6 months, which was achieved by optimization of the amount and the mo…
We present a model for the propagation of optical beams in a nematic droplet. For a low intensity electromagnetic field, we first derive an analytical asymptotic expression for the configuration of a nematic droplet that satisfies hard-anchoring, bipolar boundary conditions. Then, from Maxwell's equation, we find the…
This paper discusses how the luminescence-excitation method affects the spectral content of the emission in ZnS: Mn single crystals. It shows that the nearest neighborhood of the Mn 2+ ions is associated with the elementary emission bands having maxima at the wavelengths λ m =557, 578, 600, 616, and 638±2 nm in zinc s…
Grain‐boundary sliding and grain interlocking of two‐phase ceramics during creep are examined on the basis of the Dryden–Kucerovsky–Wilkinson–Watt theory. That theory is extended to the plane–strain creep deformation of model arrays of square and hexagonal grains embedded in a continuous grain‐boundary melt phase to d…
The Mössbauer spectra of a series of rhombohedral Tb2Fe17−xSix solid solutions, with x equal to 0, 1, 2, and 3, have been measured as a function of temperature. Although the spectra of Tb2Fe17 change substantially upon cooling from 295 to 85 K, it has been possible to fit them with a consistent seven sextet model corr…
Abstract This report re-examines the technical basis for the AET as presented inPCA Research Department Bulletin RX45 as well as more recent research. Thefocus is on the potential for disruptive expansions caused by crystallineMgO in portland cements hydrated under various conditions, including the AET.Much of the dat…
Using an oriented single crystal, Raman and infrared vibrational spectra have been measured for phenakite, Be 2 SiO 4 . The results have been interpreted on the grounds of Born−von Karman rigid-ion lattice-dynamical calculations, using empirical potentials derived from fitting the vibrational frequencies of a group of…
Magnetostriction λ∥(H) and field-induced phase transitions were studied in the single crystal of La1−xSrxMnO3 (x=0, 0.05, 0.1, and 0.175) in the pulsed magnetic fields up to 230 kOe. Anomalies in the λ∥(H) curves were revealed at 200 kOe in the LaMnO3, which were identified with the spin-reorientation AyFz→AzFy in the…
Electrical properties of defect structure in Ni-doped (Ba 1- x Sr x )TiO 3 ceramics were studied by means of electron spin resonance (ESR), thermally stimulated current (TSC), dielectric and conduction measurements. A set of experimental results revealed that the nickel cations were located on the B-site of the perovs…
Abstract The crystal structure of the ternary Co 2 NiAl 9 (Y 2 phase in the Co–Ni–Al system) has been solved by single crystal methods. Despite the expectation, the Y 2 structure cannot be considered as a possible approximative structure for decagonal/icosahedral phases because of the small size of the structural segm…
Thermoelectric power measurements have been made on macroporous (pore width >500 Å°) porous silicon samples prepared by an anodic dissolution technique. The sign of thermopower is found to be negative indicating that conduction takes place due to electrons in the conduction band. The conduction mechanism is fou…