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Excitation and emission spectra of polyethylene terephthalate and polyethylene 2,6-naphthalate films

Isuke Ouchi、Ryo Miyamura、Makoto Sakaguchi 等 5 位作者1999-03-01Polymers for Advanced Technologies

With excitation by the light of the wavelengths longer than 320 nm, fluorescence spectra of polyethylene terephthalate (PET) films had somewhat different shapes from those excited below 300 nm through the intrinsic absorption of PET molecules. Also, in the measurements taken with a polarizer in front of the receiving…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Topological Studies of Bimodal Networks

Paris R. von Lockette、Ellen M. Arruda1999-03-01Macromolecules

A new cross-linking algorithm, NETSIM, is described which enables the study of continuously spatially distributed (off-lattice) polymer networks and reveals some topological features possibly associated with the enhanced mechanical properties seen in certain bimodal elastomer networks. These features are identified ba…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Electro-op tic properties of Sn2P2S6

J. Kroupa、Yuri I. Tyagur、A. A. Grabar 等 4 位作者1999-03-01Ferroelectrics

We report new data on the electrooptic behaviour of the semiconductor ferroelectric crystal Sn2P2S6 in the temparature region 295-390 K. At the room temperature the magnitude of the effective longitudinal electro-optic coefficient is about 50 pm/V, much larger than the value reported previously. Corresponding half-wav…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

On the Use of Darcy Permeability in Sheared Fabrics

F. D. Dungan、M. T. Senoguz、A. M. Sastry 等 4 位作者1999-03-01Journal of Reinforced Plastics and Composites

Determination of a set of processing parameters for a given material type is a complex process, and much work has been done using the framework developed in the last century by Darcy. While this model, assuming Newtonian flow through a granular (essentially a smoothed, porous) medium, has produced useful flow front pr…

Computer Graphics and Visualization TechniquesEpoxy Resin Curing ProcessesTextile materials and evaluations

Liquid crystal bridges

Milind P. Mahajan1999-03-01Liquid Crystals

The liquid crystalline material octylcyanobiphenyl was studied in the form of bridges spanning the space between two solid supports in an immiscible water bath. In the nematic phase the bridge collapses above a certain length-to-diameter ratio, consistent with the behaviour of ordinary Newtonian liquid bridges. The sm…

Liquid Crystal Research AdvancementsSurface Modification and SuperhydrophobicityElectrohydrodynamics and Fluid Dynamics

Antiferromagnetic resonance in the cubic perovskiteKNiF3

Hideki Yamaguchi、K. Katsumata、Masayuki Hagiwara 等 8 位作者1999-03-01Physical review. B, Condensed matter

Low-temperature high-magnetic-field far-infrared spectroscopy and electron-spin-resonance measurements have been performed on single crystals of the cubic perovskite ${\mathrm{KNiF}}_{3}.$ We found the absorption at $48.7\ifmmode\pm\else\textpm\fi{}0.3 {\mathrm{cm}}^{\ensuremath{-}1}$ observed by Richards [P. L. Richa…

Magnetism in coordination complexesMultiferroics and related materialsAdvanced Condensed Matter Physics

Influence of interfacial adhesion on stress-strain properties of highly filled polyethylene

Zhengping Fang、Qiaoling Hu1999-03-01Die Angewandte Makromolekulare Chemie

This paper studied the structure and properties of highly filled polyethylene/magnesium hydroxide composite. A third additive component was introduced to alter interfacial adhesion. Scanning electronic microscopy proved that the filler particles were totally surrounded by additive material. Interfacial adhesion played…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Texture and orientation of kaolin in coatings

N. J. Elton、L. F. Gate、J. J. Hooper1999-03-01Clay Minerals

Abstract X-ray diffraction (XRD), infra red (IR) spectroscopy, gloss goniophotometry and stylus profilometry were used to investigate the alignment of kaolinite applied as a thin coating on a polyester film substrate. The principles and applicability of the analytical methods are reviewed and discussed in the context…

Cultural Heritage Materials AnalysisBuilding materials and conservationClay minerals and soil interactions

1H NMR Relaxation Studies of Cured Natural Rubbers with Different Carbon Black Fillers

Johannes Leisen、J. Breidt、J. Kelm1999-03-01Rubber Chemistry and Technology

Abstract 1 H NMR relaxation data provide insight into the effects of carbon black fillers on the structure of polymer networks in products based on natural rubber so that accepted ideas concerning the interaction between elastomeric networks and active filling materials are confirmed. A new 1 H NMR relaxation experime…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingLubricants and Their Additives

Thermal Properties and Crystallization Behavior of Highly Deproteinized Natural Rubber

Seiichi Kawahara、Takashi Kakubo、Michio Suzuki 等 4 位作者1999-03-01Rubber Chemistry and Technology

Abstract Natural rubber was deproteinized with a proteolytic enzyme and surfactant to reduce nitrogen content less than 0.02%. The deproteinized rubber was further purified by acetone-extraction followed by transesterification with sodium methoxide. The density of rubber decreased and the thermal expansion coefficient…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Grain-size limit of polycrystalline materials

Nian X. Sun、K. Lu1999-03-01Physical review. B, Condensed matter

Through combining an experimental investigation on the isothermal nanocrystallization thermodynamics of bulk amorphous selenium and a theoretical analysis, an easy and reliable way to derive the lower grain-size limit of polycrystalline materials was proposed. The grain-size limit for the polycrystalline selenium was…

Material Dynamics and PropertiesMetallic Glasses and Amorphous Alloysnanoparticles nucleation surface interactions

Adsorption Behavior of Poly(ethylene glycol) at the Solid/Liquid Interface

William J. Walker、James S. Reed、Surendra Kumar Verma 等 4 位作者1999-03-01Journal of the American Ceramic Society

Adsorption behavior of two grades of poly(ethylene glycol) (PEG) was measured on silica and alumina in the presence of other organic and inorganic additives commonly used in ceramic processing. A fractional factorial designed experiment showed that the level of adsorption was significantly influenced by the powder or…

Microfluidic and Capillary Electrophoresis ApplicationsPolymer Surface Interaction StudiesElectrophoretic Deposition in Materials Science

Cast Iron Brake Discs - Current Position, Performance and Future Trends in Europe

Trish Chatterley、M. P. Macnaughtan1999-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">The paper represents a brief summary of a survey of the chemical and metallurgical composition of cast iron brake discs, as used in automotive applications by a wide range of different manufacturers across Europe. From the findings, sample discs were produced, to a standard design…

Aluminum Alloys Composites PropertiesMetal Alloys Wear and PropertiesMetallurgy and Material Science

Engineering Thermoplastic Energy Absorbers for Bumpers

Darin Evans、Terry Morgan1999-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="section abstract"><div class="htmlview paragraph">Automotive styling trends point to reduced bumper overhang, greater sweeps, and reduced overall package space for the bumper system. At the same time engineers are charged with improving bumper performance to reduce collision repair costs and en…

Natural Fiber Reinforced CompositesCellular and Composite StructuresMechanical Engineering and Vibrations Research

The Reduction of Diesel Engine Emissions by Using the Oxidation Catalysts of Japan Diesel 13 Mode Cycle

Hironobu Mogi、Kazunao Tajima、Mitsuru Hosoya 等 4 位作者1999-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">To reduce emissions from diesel engines, the effects of oxidation catalysts on the emissions reductions were studied. The effectiveness of several oxidation catalysts on both the regulated and unregulated emissions was evaluated. The oxidation activity of the catalysts was varied…

Catalytic Processes in Materials Science

Silica and Silane Coupling Agent for in Situ Reinforcement of Acrylonitrile-Butadiene Rubber

Kenichi Murakami、Shodai Osanai、M. Shigekuni 等 7 位作者1999-03-01Rubber Chemistry and Technology

Abstract In situ silica reinforcement for the acrylonitrile-butadiene rubber (NBR) vulcanizates, which were premixed with a conventional silica (VN-3) and γ-mercaptopropyltrimethoxysilane (γ-MPS), was achieved by the sol-gel reaction of tetraethoxysilane (TEOS) using ethylenediamine. It was observed that the reinforce…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Facile Preparation of Robust Organic Gels by Cross-link of a Sugar-integrated Gelator by Toluene-2,4-diisocyanate

Kazuhiko Inoue、Yoshiyuki Ono、Yasumasa Kanekiyo 等 6 位作者1999-03-01Chemistry Letters

Abstract Gelator 1 which has two aliphatic chains, three amide groups, and one glucosamine unit showed an excellent gelation ability for many organic solvents. The in situ cross-link of these organic gels by toluene-2,4-diisocyanate resulted in new robust gels with high Tgel values, retaining their gel fiber super-str…

Polymer composites and self-healingSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Kinetic Crystallization Behavior of Phase-Change Medium

Donyau Chiang、Tzuan-Reng Jeng、Der-Ray Huang 等 5 位作者1999-03-01Japanese Journal of Applied Physics

The crystallization behavior of nominal-composition GeSb 2 Te 4 films prepared by rf-magnetron sputtering are examined. The crystal structures of the as-sputtered and the annealed films at different annealing temperatures are identified by the X-ray diffraction (XRD) method. Two phase transformations occur in the conv…

Liquid Crystal Research AdvancementsGlass properties and applicationsPhase-change materials and chalcogenides

Computer Simulation Studies of Molecular Orientation and the Stress−Optical Properties of Polyethylene Networks

D. J. R. Taylor、R. F. T. Stepto、Richard A. Jones 等 4 位作者1999-03-01Macromolecules

A new Monte Carlo (MC) method is used to interpret experimental stress−optical coefficients ( C ) of polyethylene (PE) networks in uniaxial deformation. The method considers the deformation of individual PE-network chains, whose conformational properties and −CH 2 − segment orientations are calculated using a rotation…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesElasticity and Material Modeling

Age‐hardening associated with grain boundary precipitation in a commercial dental gold alloy

H. I. Kim、Myoung-Ik Jang、Min‐Soo Kim1999-03-01Journal of Oral Rehabilitation

The aim of this study was to make clear the age-hardening mechanism in a dental high carat gold alloy. For this purpose, age-hardening behaviour of a commercial dental high carat gold alloy, 65.5 wt% Au-14.0 wt% Ag-10.0 wt% Cu-8.9 wt% Pt, was investigated by means of hardness testing, X-ray diffraction study and scann…

Microstructure and mechanical propertiesMetallurgy and Material FormingMetallurgy and Cultural Artifacts