Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
We etched thermally poled fused-silica coverslips in 49% HF for 30 s transverse to the poling direction to reveal structural details of the nonlinear region. A peaked ridge below the anode surface, corresponding to a slower etch rate than that of the bulk SiO(2) , was located approximately 5 microm below the anode sur…
Activated carbon fibers (ACF) are microporous carbon consisting of a three-dimensional network of micrographites having the size of ∼3 nm. We investigate structural and electronic properties of ACFs in relation to the adsorption of helium, nitrogen, and oxygen gases, by means of adsorption isotherm, ESR (electron spin…
The reaction of [Cu(CH(3)CN)(4)](BF(4)) with 3,5-dimethyl-4-nitropyrazole (Hdmnpz) in the presence of triethylamine yields the new copper(I) complexes [Cu(dmnpz)](3) (1) and (Et(3)NH)(2)[Cu(4)(dmnpz)(6)] (2), depending on the experimental conditions. The reactivity of 1 and 2 toward neutral ligands such as triphenylph…
An extended-core liquid crystal (LC) based on the 3,3′-di(acylamino)-2,2′-bipyridine unit is investigated with respect to its behavior in alkane solvents. It is demonstrated that the lyotropic mesomorphism observed in dodecane can be tuned by varying the concentration of the sample, and the columns can be switched in…
Vapour–liquid coexistence densities near the critical point are reported for polarizable water models, determined by a series of grand canonical Monte Carlo simulations with the histogram reweighting method. Previously proposed point charge models rescaled to match the experimental permanent dipole moment in the gas p…
Al 2 O 3 -, TiO 2 -, SiO 2 -, and ZrO 2 -based mixed-oxide supports were synthesized by sol−gel techniques using 2,4-pentanedione as the complexing/templating agent. These materials have been investigated by employing nitrogen adsorption, 27 Al, 29 Si, and 1 H solid-state magic-angle spinning nuclear magnetic resonanc…
Inhibition of copper corrosion in aerated 0.5 M sulfuric acid (H2SO4) solutions containing various concentrations of indole was studied in the temperature range from 25°C to 55°C using potentiodynamic curve, weight-loss, and analytical methods. Indole shifted corrosion potentials toward more noble values (i.e., it had…
Super-tough nylon 6 was prepared by using maleic anhydride grafted polyethylene-octene rubber/semicrystalline polyolefin blend (TPEg) as an impact modifier. The morphology, dynamic mechanical behavior, mechanical properties, and toughening mechanism were studied. Results indicate that TPEg with a semicrystalline polyo…
Broad-band UV absorption spectroscopy was used to determine radical densities in reactive gas plasmas generated in a 13.56 MHz capacitively coupled parallel plate reactor. Five radical species were detected: , CF, AlF, and . Absolute (line-integrated) densities were determined in and plasmas, as were the vibrational a…
The addition of tetraalkylammonium cations to aqueous silicate solutions enhances the abundance of symmetric, cagelike, polysilicate anions including the cubic octamer, Si(8)O(20)(8)(-). The equilibrium ratio of tetramethylammonium (TMA) cations to the octameric silicate anion is 8:1 for solutions with a concentration…
Earlier studies involving water-mediated transformations in lysozyme and ribonuclease A have shown that the overall movements in the protein molecule consequent to the reduction in the amount of surrounding water are similar to those that occur during enzyme action, thus highlighting the relationship among hydration,…
Enzymatic ring-opening polymerization and copolymerization of a nine-membered lactone, 8-octanolide (8-OL), was performed in isooctane by using various lipases of different origin as catalyst. The polymerization behavior greatly depended on the lipase origin. Candida antarctica and Pseudomonas cepacia lipases (lipases…
We have used photon correlation spectroscopy and quartz crystal microbalance techniques to examine the relaxation dynamics of ultrathin $(h<400\AA{})$ polystyrene films in both supported and freely standing geometries. These studies probe relaxation dynamics of polymer films in which the glass transition temperatur…
A subdivision of the stability region of decagonal Al-Co-Ni quasicrystals into eight different structural modifications is presented for the temperature against composition section along the maximum extension of the decagonal phase. The only methods identifying this subdivision are transmission electron microscopy tec…
Direct mapping of the interface between parathyroid hormone (PTH) and its receptor (hPTH1-Rc) was carried out by photoaffinity scanning studies. Photoreactive analogs of PTH singularly substituted with a p-benzoylphenylalanine (Bpa) at each of the first six N-terminal positions have been prepared. Among these, the ana…
The inhibition of carbon steel in solutions of mixtures of calcium- and zinc-gluconate with sodium benzoate was investigated in the temperature range from 25° to 60°C, under atmospheric conditions in stagnant solutions prepared with the tap water. The efficiency and the mechanism of inhibition were estimated by potent…
Pergularia daemia (Forsk.) Chiov. (Asclepiadaceae), a wild plant of the arid zone of Rajasthan, hasdemonstrated significant antiinflammatory, antipyretic and analgesic activities including the release of prostaglandin. © 1998 John Wiley & Sons, Ltd.
Direct reactions of nickelocene and manganocene with molten pyrazoles in an inert atmosphere or under vacuum have led to the isolation of the following metal pyrazolate compounds: [Ni(4-Xpz) 2 ] x (where X = H, Cl and pz = pyrazolate); [M(4-Xdmpz) 2 ] x (where X = H, CH 3 , Cl, Br and M = Ni, Mn anddmpz = 3,5-dimethyl…
Surface-enhanced Raman imaging (SERI) has recently been developed as a surface imaging technique that is chemically selective, has monolayer sensitivity and can be used under ambient pressure conditions. At present, the resolution is 1–2 μm. A particularly interesting application is to image patterned self-assembled m…
Abstract Whereas pultrusion with thermoset resins has been widely analyzed, there is a scarcity of knowledge about pultrusion with thermoplastic resins. The aims of this work were to strive towards deeper knowledge of temperature distribution and degree of crystallinity in the composite during processing, to develop a…