Materials Literature
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The water content of electrochemically deposited polyvinylferrocene films was studied using the electrochemical quartz crystal microbalance. Unhydrated films were introduced into aqueous sodium perchlorate solution. Using cyclic voltammetry, the mass and charge change accompanying electrochemical cycling between oxidi…
The adsorption isotherm and the enthalpy of adsorption of CO2 on oxides of oxygen-deficient magnetite have been studied by adsorption techniques. Oxygen-deficient magnetite was prepared by flowing H2 gas through magnetite powder at 300 °C. Adsorption of CO2 onto oxygen-deficient magnetite was studied in the temperatur…
The effects of phospholipid adsorption onto the polymer surface during adsorption of plasma proteins were investigated. When a polymer with the phosphorylcholine moiety, 2-methacryloyloxyethyl phosphorylcholine (MPC) co-polymer, was treated with dipalmitoylphosphatidylcholine (DPPC) liposome solution, an organized ads…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermotropic properties and conformational studies on poly(triethylene glycol p,p'-bibenzoate) and poly(octamethylene p,p'-bibenzoate)Ernesto Perez, Evaristo Riande, Antonio Bello, Rosario Benavente, and Jose M. PerenaCite this: Macromolecules 1992, 25, 2, 605–610Publication…
The thermally-stable coloured form 5a, obtained by irradiation (λ= 366 nm) of the title compound 4a, contains a rigid inflexible spiroadamantylidene group which results in a five- to nine-fold increase in the quantum efficiency for bleaching compared to the analogous compound 2 having methyl groups in the 7-position.…
All articles of this category The design and synthesis of a molecular shuttle, in which the two components are a cyclobis(paraquat- p -phenylene) tetracationic macrocycle and a linear polyether chain intercepted by a 2,3,5-trisubstituted indole unit and a hydroquinol residue, and terminated by two 4-tritylphenyl ether…
Using self-assembly strategies, catenanes consisting of zinc and free base porphyrins with hydroquinol-containing polyether straps of different lengths interlinked with a tetracationic bipyridinium cyclophane have been synthesised.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of phosphine ligands in gold cluster chemistry. Relativistic SCF calculations on Au2 and Au2(PH3)2Peter Schwerdtfeger and Peter D. W. BoydCite this: Inorg. Chem. 1992, 31, 2, 327–329Publication Date (Print):January 1, 1992Publication History Published online1 May 2002Pu…
Optimal conditions of electroblotting that led to high protein recovery on polyvinylidene difluoride (PVDF) membranes were determined for sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). SDS concentrations in the gel and transfer buffer were found to be the most important factors affecting the amo…
The effects of nitrogen dioxide and ammonia on the semiconductivity properties of solution-deposited thin films of the tetra-substituted 15-crown-5, 18-crown-6 and 21-crown-7 metal-free and copper phthalocyamnes are reported. The 15-crown-5 films showed good reversible conductivity changes at room temperature in NO2 c…
Direct and quantitative probing of space charge was carried out to study effects of space charge on dielectric breakdown of polymeric insulating materials. In poly-p-phenylene sulfide, in which dielectric-breakdown characteristics were explained in terms of space-charge formation, positive homo space charge was observ…
A crystalline orientated interatomic-potential model, including the directionality of Si—O bonds, has been applied in molecular-dynamics simulations of the atomic-scale structures of x[yNa2O·(1 –y)K2O].(1 –x)SiO2 glasses. The structures of the mixed-alkali-metal silicate glasses were investigated both as a function of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-pressure functionalization of diaza-crown ethers: new synthesis of silver(1+) ion-specific bindersHiroshi Tsukube, Hiroyuki Minatogawa, Megumi Munakata, Mitsuo Toda, and Kiyoshi MatsumotoCite this: J. Org. Chem. 1992, 57, 2, 542–547Publication Date (Print):January 1, 19…
Als Ausschnitte aus der V 2 O 5 ‐Schichstruktur (Bild rechts; verbrückende O‐Atome große schattierte, terminale O‐Atome große weiße und V‐Atome kleine weiße Kugeln) lassen sich die im Titel erwähnten, in jüngster Zeit hergestellten, neuartigen Polyvanadat‐Strukturen beschreiben und systematisieren. Diese im Gegensatz…
New phthalocyanines (M = Cu, Zn, Ni, Co or 2H) substituted with four 17-membered trioxadiaza macrocycles have been prepared. Detosylation of aza groups with concentrated sulfuric acid simultaneously leads to sulfonated groups on the aromatic rings of the macrocyclic substituents. While the N-tosylated derivatives are…
The optical properties of doped columnar phases formed either by a 1 : 1 mixture of an electron donor [2,3,6,7,10,11-hexa-(n-pentyloxy)triphenylene] and an electron acceptor (2,4,7-trinitrofluoren-9-one) or by a dimer in which the donor (triphenylene moiety) and the acceptor (trifluorenone moiety) are covalently linke…
Fourier-transform infrared (FTIR) spectra are reported of formic acid and formaldehyde on ZnO/SiO2, reduced Cu/ZnO/SiO2 and reoxidised Cu/ZnO/SiO2 catalyst. Formic acid adsorption on ZnO/SiO2 produced mainly bidentate zinc formate species with a lesser quantity of unidentate zinc formate. Formic acid on reduced Cu/ZnO…
Long-circulating liposomes can be prepared by coating liposome surface with a hydrophilic layer of oligosaccharides, glycoproteins, polysaccharides and synthetic polymers in order to make liposomes “invisible” for scavenger cells of the mononuclear phagocyte system. Incorporation of lipid-anchored poly(ethylene glycol…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, characterization, and dynamics of a rod/sphere composite liquidMark A. Tracy and R. PecoraCite this: Macromolecules 1992, 25, 1, 337–349Publication Date (Print):January 1, 1992Publication History Published online1 May 2002Published inissue 1 January 1992https://pu…
The structure of the solvated lithium cation in acetone solutions has been investigated using Raman spectroscopy. Two bands at 1220 and 1238 cm–1 have been assigned to two types of asymmetric carbon–carbon stretching vibration of acetone: the former is from the bulk solvent and the latter arises from acetone molecules…