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High-temperature processable carbon–silicate nanocomposite cold electron cathodes for miniature X-ray sources

Rémi Longtin、Hans‐Rudolf Elsener、Juan R. Sánchez‐Valencia 等 8 位作者2012-12-13Journal of Materials Chemistry C

We report on the fabrication, Raman characterization and electron emission behavior of cold electron cathodes that are specifically designed to be used in miniature X-ray sources. The cathodes are fabricated by screen-printing a nanocomposite paste comprising multiwall carbon nanotubes as fillers in a matrix of graphi…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchAdvanced Electron Microscopy Techniques and Applications

Ultraviolet Radiation from Combustion of a Dense Magnesium Powder Flow in Air

Teri M. Baker、Timothy F. Miller2012-12-13Journal of Thermophysics and Heat Transfer

Combustion of magnesium produces copious ultraviolet and visible light emissions. The ultraviolet emission can be employed potentially in an antibacterial capacity. Ultraviolet radiation from the combustion of a heavily laden flow of magnesium powder with air was measured in a linear test combustor fitted with optical…

Luminescence Properties of Advanced Materials

Neutral Dimethylzirconocene Complexes as Initiators for the Ring‐Opening Polymerization of ϵ‐Caprolactone

Elena Villaseñor、Rubén Gutiérrez‐González、Fernando Carrillo‐Hermosilla 等 7 位作者2012-12-13European Journal of Inorganic Chemistry

Abstract The synthesis, structures, and ring‐opening polymerization (ROP) activity of new dimethyl‐ ansa ‐ and ‐non‐ ansa ‐zirconocene complexes are reported. The substituted indene precursors 1‐C 9 H 7 R [R = CH 3 ( 1 ), CH 2 Ph ( 2 ) and C 2 H 4 (C 4 H 7 O 2 ) ( 3 )] were synthesised by treating RBr [R = CH 2 Ph and…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Precise Control of the Number of Walls of Carbon Nanotubes of a Uniform Internal Diameter

Ankur Baliyan、Yasuhiro Hayasaki、Takahiro Fukuda 等 7 位作者2012-12-13The Journal of Physical Chemistry C

It still remains a crucial challenge to control actively the structures of carbon nanotubes (CNTs) such as the alignment, length, diameter, chirality, and the number of walls. The properties of CNTs are highly dependent on the structures. There is a strong demand for invention of some innovative methodology to precise…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Rejuvenation, Aging, and Confinement Effects in Atactic‐Polystyrene Films Subjected to Oscillatory Shear

Dmytro Hudzinskyy、M. A. J. Michels、Alexey V. Lyulin2012-12-13Macromolecular Theory and Simulations

Abstract Molecular‐dynamics simulations of 5 nm‐thick atactic‐polystyrene films have been used to study the influence of cyclic‐shear deformation on the stress–strain behavior and local segmental mobility. Upon cyclic yield the stress–strain behavior of the films slowly evolves towards a steady state which is characte…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Tough thermoplastic starch modified with polyurethane microparticles by reactive extrusion

Yu Zhang、Lei Huang、Hongbin Zhou 等 7 位作者2012-12-13Starch - Stärke

Abstract In this work, a starch–water mixture was blended with polyurethane prepolymer (PUP) at 0, 5, 10, 15, and 20 wt% and extruded in a twin screw extruder. The ensuing results showed that the reaction ratio of PUP used for modified starch was 98.6 ± 0.3%. This was attributed to the polyurethane particles being for…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Protective Properties of SF<sub>6</sub> under Various Carrier Gases for the Protection of Molten Mg

Byeong Deok Lee、Ui Hyeon Beak、Ki Woo Lee 等 5 位作者2012-12-13MATERIALS TRANSACTIONS

Molten magnesium can oxidize rapidly in atmospheres containing oxygen. During the casting and handling of molten magnesium, it is essential to protect the melt from ignition. The protective gas normally contains air and/or CO2, and with a small amount of an inhibiting agent. This study examined the minimum amount of S…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesMolten salt chemistry and electrochemical processes

Growth of Nanocrystalline PbS Thin Films by Solid-Vapor Deposition

A.S. Obaid、M.A. Mahdi、Hassan Zainuriah2012-12-13Advanced materials research

Solidvapor deposition was used to synthesize nanocrystalline PbS thin films on a Si (100) substrate. Lead sulfide (PbS) powder was first prepared and then heated to 1050 °C in a tube furnace. The resulting vapor was carried to the substrate zone by an argon flow. The structure of the nanocrystalline PbS thin films was…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Textural Characteristics of Coconut Shell-Based Activated Carbons with Steam Activation

Xin Ying Wang、Dan Xi Li、Bao Yang 等 4 位作者2012-12-13Advanced materials research

Activated carbons were prepared from coconut shells by using carbonization at 600 °C for 2 h followed by water steam activation. Effects of activation temperature, hold time and water steam amount on the yield, BET surface area and micropore volume of activated carbons were evaluated. The pore structure of the activat…

Adsorption and biosorption for pollutant removalSupercapacitor Materials and FabricationAerogels and thermal insulation

Directed self-assembly of PS-b-PMMA block copolymer using HSQ lines for translational alignment

Dipu Borah、Sozaraj Rassapa、Matthew T. Shaw 等 8 位作者2012-12-13Journal of Materials Chemistry C

We report here the graphoepitaxial alignment of a lamellar forming PS-b-PMMA block copolymer (BCP) for directed self-assembly using topographical patterns (simple line structures) of hydrogen silsesquioxane (HSQ). The system demonstrates the importance of the sidewall chemistry on translational alignment of BCP domain…

Semiconductor materials and devicesPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Antifouling Surfaces for Proteins Labeled with Dye-Doped Silica Nanoparticles

Hui Wang、Qi Tong、Mingdi Yan2012-12-13Analytical Chemistry

We report that proteins labeled with fluorescein-doped silica nanoparticles (FSNPs) showed drastically different fouling behavior than those labeled with the fluorescein dye. Arrays of polymer films were covalently immobilized on silicon wafers and were treated with protein conjugated on FSNPs. Fluorescence imaging sh…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Ab initio study of collective excitations in a disparate mass molten salt

Taras Bryk、Ivan Klevets2012-12-13The Journal of Chemical Physics

Ab initio molecular dynamics simulations and the approach of generalized collective modes are applied for calculations of spectra of longitudinal and transverse collective excitations in molten LiBr. Dispersion and damping of low- and high-frequency branches of collective excitations as well as wave-number dependent r…

Material Dynamics and PropertiesSolid-state spectroscopy and crystallographyMolten salt chemistry and electrochemical processes

Preparation, dielectric and a.c. conductivity studies on chemically treated sisal powder filled polyvinyl alcohol biocomposites

Archana Nigrawal、Navin Chand2012-12-13International Journal of Engineering Science and Technology

In this paper, development and electrical characterization of sisal powder filled polyvinyl alcohol (PVA) composites is reported. Dielectric measurements were conducted on these composites on a LCR meter in the temperature range from 30 to 150°C and in the frequency range 1 kHz - 10 kHz. The effects of temperature and…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesDielectric materials and actuators

Effect of molding condition and pellets material on the weld property of injection molded jute/polylactic acid

Cuntao Wang、Putinun Uawongsuwan、Yuqiu Yang 等 4 位作者2012-12-13Polymer Engineering and Science

Abstract Natural fibers such as jute fiber and biodegradable poly(lactic acid) (PLA) polymer are very good choices for environmental friendly material. Multi‐gate injection is often used to meet the demand of mass production of injection moldings, therefore weld line is inevitable. The presence of weld lines not only…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Mechanical characterizations of high-quality quantum dot arrays via transfer printing

Sangmin Lee、Daesung Yoon、Dukhyun Choi 等 4 位作者2012-12-13Nanotechnology

In this study, we investigate the mechanical characteristics of transfer-printed quantum dot (QD) arrays. Transfer printing of a spin-coated QD array by elastomers results in changes of the mechanical properties of the QD films since QDs encapsulated by organic aliphatic ligands can be deformed by physical forces such…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresNanowire Synthesis and Applications

X-Ray and Morphological Characterization of Al-O Thin Films Used for Vertically Aligned Single-Walled Carbon Nanotube Growth

Mohd Asyadi Azam、Mohd Warikh Abd Rashid、Kazuki Isomura 等 5 位作者2012-12-13Advanced materials research

Al oxide (Al-O) films used as catalyst-support layer for vertical growth of carbon nanotubes (CNTs) were characterized by means of X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission, and scanning electron microscopies (TEM and SEM). EB-deposited Al films (20 nm) were thermally-oxidized at 40…

Carbon Nanotubes in CompositesGraphene research and applicationsElectrophoretic Deposition in Materials Science

Heteroepitaxial Growth of Single-Walled Carbon Nanotubes from Boron Nitride

Dai‐Ming Tang、Lili Zhang、Chang Liu 等 11 位作者2012-12-13Scientific Reports

The growth of single-walled carbon nanotubes (SWCNTs) with predefined structure is of great importance for both fundamental research and their practical applications. Traditionally, SWCNTs are grown from a metal catalyst with a vapor-liquid-solid mechanism, where the catalyst is in liquid state with fluctuating struct…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

An interplay between electrostatic and polar interactions in peptide hydrogels

Katherine Joyner、Marc B. Taraban、Yue Feng 等 4 位作者2012-12-13Biopolymers

Inherent chemical programmability available in peptide-based hydrogels has allowed diversity in the development of these materials for use in biomedical applications. Within the 20 natural amino acids, a range of chemical moieties are present. Here we used a mixing-induced self-assembly of two oppositely charged pepti…

Protein Structure and DynamicsHydrogels: synthesis, properties, applicationsSupramolecular Self-Assembly in Materials

Luminescent properties of passivated europium(iii)-doped rare earth oxide sub-10 nm nanoparticles

Rafael D.L. Gaspar、Emille M. Rodrigues、Ítalo Odone Mazali 等 4 位作者2012-12-13RSC Advances

Passivated nanoparticles of europium(III)-doped yttrium, lanthanum and gadolinium oxides were synthesized by a modified sol–gel method and their luminescent properties were studied. The passivation of the nanoparticles surface is confirmed by infrared spectroscopy. Gadolinium and yttrium oxides crystalize as cubic pha…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceLanthanide and Transition Metal Complexes

The influence of linking group in exterior point on mesogenic properties of the basket moulded molecules: calix[4]arene

Pinkesh G. Sutariya、Alok Pandya、V. A. Rana 等 4 位作者2012-12-13Liquid Crystals

Novel basket-shaped molecules having calix[4]arene as central rigid core possessing azomaterial in outer space unit in the lengthening arm were synthesised and characterised by elemental analysis and different spectroscopic methods such as Fourier Transform Infrared (FT-IR), electron spin ionization (ESI)-MASS, 1H nuc…

Liquid Crystal Research AdvancementsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials