Materials Literature
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We present the synthesis and switching studies of systems with two photochromic dihydroazulene (DHA) units connected by a phenylene bridge at either para or meta positions, which correspond to a linear or cross-conjugated pathway between the photochromes. According to UV/Vis absorption and NMR spectroscopic measuremen…
Recent interest in the use of nanoparticles in emulsion stabilization has driven increased efforts to understand how the characteristics of the particles influence the emulsion properties. While it is clear that the contact angle and wettability must play significant roles in determining the type of emulsion formed, i…
Abstract A novel aromatic diamine monomer bearing tertbutyl and 4‐tertbutylphenyl groups, 3,3′‐ditertbutyl‐4,4′‐diaminodiphenyl‐4′′‐tertbutylphenylmethane (TADBP), was prepared and characterized. A series of non‐coplanar polyimides (PIs) were synthesized via a conventional one‐step polycondensation from TADBP and vari…
Research on development of efficient passivation materials for high performance and stable quantum dot sensitized solar cells (QDSCs) is highly important. While ZnS is one of the most widely used passivation material in QDSCs, an alternative material based on ZnSe which was deposited on CdS/CdSe/TiO 2 photoanode to fo…
Ultrasound has emerged as a promising means to effect controlled delivery of therapeutic agents through cell membranes. One possible mechanism that explains the enhanced permeability of lipid bilayers is the fast contraction of cavitation bubbles produced on the membrane surface, thereby generating large impulses, whi…
Titanium dioxide nanoparticles are photoactive and produce reactive oxygen species under natural sunlight. Reactive oxygen species can be detrimental to many organisms, causing oxidative damage, cell injury, and death. Most studies investigating TiO2 nanoparticle toxicity did not consider photoactivation and performed…
Abstract Silicon oxynitride coatings on glass and polyethylene terephthalate ( PET ) film have been fabricated by thermal annealing of inorganic polymer perhydropolysilazane ( PHPS ) between 60 °C and 200 °C. The chemical structure, thermal behavior and structural evolution of PHPS were investigated. The coatings obta…
Polyampholyte-coated (poly(acrylic acid) (PAA)-co-3-(diethylamino)-propylamine (DEAPA)) magnetite nanoparticles (PAMNPs) have been prepared as contrasting agent used in magnetic resonance imaging (MRI). Excellent biocompatibility is required for contrasting agents used in high-resolution magnetic resonance angiography…
A series of large-sized (maximum 16 × 16 × 20 mm 3 ), high-quality K 1– x Na x NbO 3 ( x = 0.118, 0.378, 0.462, 0.545, and 0.666) single crystals were successfully cultivated using the top-seeded solution growth method. The crystallization and structures of the K 1– x Na x NbO 3 single crystals were studied using firs…
The issue of how to improve the thermoelectric figure of merit (ZT) in oxide semiconductors has been challenging for more than 20 years. In this work, we report an effective path to substantial reduction in thermal conductivity and increment in carrier concentration, and thus a remarkable enhancement in the ZT value i…
Besides its interesting physical properties, graphene as a two-dimensional lattice of carbon atoms promises to realize devices with exceptional electronic properties, where freely suspended graphene without contact to any substrate is the ultimate, truly two-dimensional system. The practical realization of nano-device…
The development of non-volatile logic through direct coupling of spontaneous ferroelectric polarization with semiconductor charge carriers is nontrivial, with many issues, including epitaxial ferroelectric growth, demonstration of ferroelectric switching and measurable semiconductor modulation. Here we report a true f…
We have recently succeeded in loading extremely small monodisperse gold clusters (1.2 ± 0.3 nm) as cocatalysts on a water-splitting BaLa 4 Ti 4 O 15 photocatalyst using a glutathione-protected Au 25 cluster (Au 25 (SG) 18 ) as a precursor; an improved photocatalytic activity of 2.6-fold was obtained when compared with…
We show, by molecular simulation, that for a range of standard, coarse-grained, nematic liquid crystal models, the director bend fluctuation is a propagating mode. This is in contrast to the generally accepted picture of nematic hydrodynamics, in which all the director modes (splay, twist, bend, and combinations there…
Almost all proteins fold via a number of partially structured intermediates such as molten globule (MG) and pre-molten globule states. Understanding the structure of these intermediates at atomic level is often a challenge, as these states are observed under extreme conditions of pH, temperature, and chemical denatura…
We employ the tight-binding propagation method to study Klein tunneling and quantum interference in large graphene systems. With this efficient numerical scheme, we model the propagation of a wave packet through a potential barrier and determine the tunneling probability for different incidence angles. We consider bot…
The ecotoxicity of nanoparticles (NPs) is a growing area of research with many challenges ahead. To be relevant, laboratory experiments must be performed with well-controlled and environmentally realistic (i.e., low) exposure doses. Moreover, when focusing on the intensively manufactured titanium dioxide (TiO2) NPs, s…
In this work, it is shown that the hydrophilic functionalized multiwall carbon nanotubes (MWCNs) can stabilize a large amount of pristine graphene nanosheets in pure water without the assistance of surfactants, ionic liquids, or hydrophilic polymers. Role of stabilizer is conveyed by highly hydrophilic carbon nanotube…
Bioadhesive microporous architectures that mimic the functions of a natural extracellular matrix (ECM) were prepared by self-assembling polydopamine (PDA) microcapsules, which not only favor cell adhesion and growth, but also facilitate growth factor immobilization and release. PDA-coated polystyrene (PS) microspheres…
This article describes the formation of dopamine-melanin thin films (50-200 nm thick) at an air/dopamine solution interface under static conditions. Beneath these films, spherical melanin granules formed in bulk liquid phase. The thickness of dopamine-melanin films at the interface relied mainly on the concentration o…