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High-performance metasurface polarizers with extinction ratios exceeding 12000

Hiroyuki Kurosawa、Bong-Seok Choi、Yoshimasa Sugimoto 等 4 位作者2017-02-16Optics Express

High-performance ultrathin polarizers have been experimentally demonstrated employing stacked complementary (SC) metasurfaces, which were produced using nanoimprint lithography. It is experimentally determined that the metasurface polarizers composed of Ag and Au have large extinction ratios exceeding 17000 and 12000,…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Homometallic DyIII Complexes of Varying Nuclearity from 2 to 21: Synthesis, Structure, and Magnetism

Sourav Biswas、Sourav Das、Joydev Acharya 等 9 位作者2017-02-16Chemistry - A European Journal

Abstract The synthesis, structure, and magnetic properties of four Dy III coordination compounds isolated as [Dy 2 (LH 2 ) 2 (μ 2 ‐η 1 :η 1 ‐Piv)]Cl ⋅ 2 MeOH ⋅ H 2 O ( 1 ), [Dy 4 (LH) 2 (μ 3 ‐OH) 2 (Piv) 4 (MeOH) 2 ] ⋅ 4 MeOH ⋅ 2 H 2 O ( 2 ), [Dy 6 (LH 2 ) 3 (tfa) 3 (O 3 P t Bu)(Cl) 3 ]Cl 4 ⋅ 15.5 H 2 O ⋅ 4 MeOH ⋅ 5 C…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Iron‐Containing SSZ‐39 (AEI) Zeolite: An Active and Stable High‐Temperature NH3‐SCR Catalyst

Nuria Martín、Peter N. R. Vennestrøm、Joakim R. Thøgersen 等 5 位作者2017-02-16ChemCatChem

Abstract The preparation of the iron‐containing SSZ‐39 zeolite is described for the first time through two different synthesis methods: post‐synthetic cation exchange and one‐pot synthesis. The nature and stability of the iron species within the different Fe‐SSZ‐39 materials have been studied through different charact…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Bioinspired Ultrastable Lignin Cathode via Graphene Reconfiguration for Energy Storage

Xiumei Geng、Yelong Zhang、Li Jiao 等 9 位作者2017-02-16ACS Sustainable Chemistry & Engineering

Lignin extracted from trees is one of the most abundant biopolymers on Earth. Quinone, a substructure in lignin, can be used for energy storage via reversible redox reactions through absorbing and releasing electrons and protons. However, these efforts have encountered hindrances, such as short life cycle, low cycling…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationLignin and Wood Chemistry

Influence of LaFeO3 Surface Termination on Water Reactivity

Kelsey A. Stoerzinger、R. Comès、Steven R. Spurgeon 等 7 位作者2017-02-16The Journal of Physical Chemistry Letters

The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular, with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry but are challenging to pr…

Advanced Photocatalysis TechniquesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Aluminum Alkyl Complexes Bearing Salicylaldiminato Ligands: Versatile Initiators in the Ring-Opening Polymerization of Cyclic Esters

Tiziana Fuoco、Daniela Pappalardo2017-02-16Catalysts

Linear aliphatic polyesters are degradable thermoplastic polymers, which can be obtained by ring-opening polymerization (ROP) of cyclic esters through a coordination-insertion mechanism. Aluminum based organometallic complexes have a leading position as efficient catalysts for this polymerization process. Aluminumalky…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Biological Activity and Bio-Sorption Properties of the Ti2C Studied by Means of Zeta Potential and SEM

Agnieszka Jastrzębska、Ewa Karwowska、Dariusz Basiak 等 8 位作者2017-02-16International Journal of Electrochemical Science

The expanded Ti 2 C MXene phase was synthesized from the commercial Ti 2 AlC MAX phase using classical acidic aluminium extraction method. The individual expanded Ti 2 C sheets were characterized by the diameters of between 26 and 61 nm and formed the specific network of slit-shaped pores in the size range of 3–5 nm.…

2D Materials and ApplicationsMetal and Thin Film MechanicsMXene and MAX Phase Materials

Crystallization of Anatase TiO2 in Niobium Potassium Phosphate Glasses

Carolina D. Freschi、José Tadeu Gouveia、Lia Mara Marcondes 等 6 位作者2017-02-16Materials Research

In this work, the glass forming ability was studied in potassium phosphate glasses with increasing amounts of TiO2 in order to obtain a glass-ceramic with photocatalytic properties. The first studied series has been the binary system (100-x) KPO3-xTiO2. Homogeneous and transparent glasses could be obtained with x vary…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesLuminescence Properties of Advanced Materials

Distribution map of gadolinium deposition within the cerebellum following GBCA administration

Donna R. Roberts、Cynthia A. Welsh、David P. LeBel 等 4 位作者2017-02-16Neurology

Gadolinium-based contrast agents (GBCAs) are an essential tool in clinical MRI. Millions of doses are administered annually to patients worldwide.1 However, free gadolinium, the basis of GBCAs, is extremely toxic in only small amounts. Gadolinium has an atomic radius similar to that of calcium and can interfere with c…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Hydrostatic pressure effect on magnetic phase transition and magnetocaloric effect of metamagnetic TmZn compound

Lingwei Li、Guanghui Hu、Yang Qi 等 4 位作者2017-02-16Scientific Reports

Abstract The magnetocaloric effect (MCE) is an intrinsic thermal response of all magnetic solids which has a direct and strong correlation with the corresponding magnetic phase transition. It has been well recognized that the magnetic phase transition can be tuned by adjusting applied pressure. Therefore, we perform t…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsAdvanced Condensed Matter Physics

Overview of the JET ITER-like wall divertor

A. Widdowson、E. Alves、A. Baron-Wiecheć 等 17 位作者2017-02-16Nuclear Materials and Energy

The work presented draws on new analysis of components removed following the second JET ITER-like wall campaign 2013–14 concentrating on the upper inner divertor, inner and outer divertor corners, lifetime issues relating to tungsten coatings on JET carbon fibre composite divertor tiles and dust/particulate generation…

Fusion materials and technologiesMetallurgical Processes and ThermodynamicsNuclear Materials and Properties

Nanoengineered Eggshell–Silver Tailored Copolyester Polymer Blend Film with Antimicrobial Properties

Boniface J. Tiimob、Gregory Mwinyelle、Woubit Abdela 等 6 位作者2017-02-16Journal of Agricultural and Food Chemistry

In this study, the reinforcement effect of different proportions of eggshell/silver (ES-Ag) nanomaterial on the structural and antimicrobial properties of 70/30 poly(butylene-co-adipate terephthalate)/polylactic acid (PBAT/PLA) immiscible blends was investigated. The ES-Ag was synthesized using a single step ball mill…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

The Effect of Concentration of Lawsonia inermis as a Corrosion Inhibitor for Aluminum Alloy in Seawater

Mohammad Fakhratul Ridwan Zulkifli、Nora’aini Ali、M. Sukeri M. Yusof 等 7 位作者2017-02-16Advances in Physical Chemistry

Lawsonia inermis also known as henna was studied as a corrosion inhibitor for aluminum alloy in seawater. The inhibitor has been characterized by optical study via Fourier transform infrared spectroscopy (FTIR). The FTIR proves the existence of hydroxyl and carbonyl functional groups in Lawsonia inermis . Aluminum all…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityMaterial Selection and Properties

Performance Analysis of Hybrid Metal–Graphene Frequency Reconfigurable Antennas in the Microwave Regime

Christian Núñez Álvarez、Rebecca Cheung、John Thompson2017-02-16IEEE Transactions on Antennas and Propagation

This paper analyzes the potential application of graphene in microwave frequency reconfigurable antennas. Two multiband designs, one for wireless fidelity (WIFI), covering the frequency bands of 2.4, 3.6, and 5 GHz, and another for the cellular long-term evolution system, operating the frequency bands of 1.8, 2.5, 2.6…

Graphene research and applicationsMetamaterials and Metasurfaces ApplicationsEnergy Harvesting in Wireless Networks

Optical Switching Using Transition from Dipolar to Charge Transfer Plasmon Modes in Ge2Sb2Te5 Bridged Metallodielectric Dimers

Arash Ahmadivand、Burak Gerislioglu、Raju Sinha 等 5 位作者2017-02-16Scientific Reports

Abstract Capacitive coupling and direct shuttling of charges in nanoscale plasmonic components across a dielectric spacer and through a conductive junction lead to excitation of significantly different dipolar and charge transfer plasmon (CTP) resonances, respectively. Here, we demonstrate the excitation of dipolar an…

Phase-change materials and chalcogenidesNonlinear Optical Materials StudiesThermal Radiation and Cooling Technologies

Direct Formation of Large-Area 2D Nanosheets from Fluorescent Semiconducting Homopolymer with Orthorhombic Crystalline Orientation

Sanghee Yang、Suyong Shin、In-Ho Choi 等 5 位作者2017-02-16Journal of the American Chemical Society

Semiconducting polymers have been widely investigated due to their intriguing optoelectronic properties and their high crystallinity that provides a strong driving force for self-assembly. Although there are various reports of successful self-assembly of nanostructures using semiconducting polymers, direct in situ sel…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Dynamic control of asymmetric electromagnetic wave transmission by active chiral metamaterial

Ke Chen、Yijun Feng、Li Cui 等 6 位作者2017-02-16Scientific Reports

The asymmetric transmission of electromagnetic (EM) wave can be fully manipulated by chiral metamaterials, but little can achieve real-time and high efficient tunability due to challenges in practically deployable solutions. Here, we proposed a new scheme for flexibly and dynamically controlling the asymmetric EM wave…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Properties of cementitious mortars reinforced with natural fibers

Abderraouf Achour、Fouad Ghomari、Naïma Belayachi2017-02-16Journal of Adhesion Science and Technology

The purpose of this study is firstly to investigate the effect of various treatments on the chemical and morphological properties of the fibers of two xerophyte plants (Doum ‘Chamaerops humilis’ and Diss ‘Ampelodesmos mauritanicus’), in order to improve the adhesion between fibers and cement matrix, secondly the effec…

Natural Fiber Reinforced CompositesInnovative concrete reinforcement materialsInnovations in Concrete and Construction Materials

Pressure-Induced Densification of Oxide Glasses at the Glass Transition

Saurabh Kapoor、Lothar Wondraczek、Morten M. Smedskjær2017-02-16Frontiers in Materials

Densification of oxide glasses at the glass transition offers a novel route to develop bulk glasses with tailored properties for emerging applications. Such densification can be achieved in the technologically relevant pressure regime of up to ~ 1GPa. However, the present understanding of the composition–structure–pro…

High-pressure geophysics and materialsGlass properties and applicationsMetallic Glasses and Amorphous Alloys

Green Microwave-Assisted Combustion Synthesis of Zinc Oxide Nanoparticles with Citrullus colocynthis (L.) Schrad: Characterization and Biomedical Applications

Susan Azizi、Rosfarizan Mohamad、Mahnaz Mahdavi Shahri2017-02-16Molecules

In this paper, a green microwave-assisted combustion approach to synthesize ZnO-NPs using zinc nitrate and Citrullus colocynthis (L.) Schrad (fruit, seed and pulp) extracts as bio-fuels is reported. The structure, optical, and colloidal properties of the synthesized ZnO-NP samples were studied. Results illustrate that…

ZnO doping and propertiesCopper-based nanomaterials and applicationsMagnesium Oxide Properties and Applications