Materials Literature
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The single crystal X-ray analysis of [Au9{P(p-C6H4OMe)3}8]-(BF4)3; has provided the first example of a cluster compound with a metal atom incorporated into the centre of a puckered ring of like metal atoms.
The corrosion resistance of commercial austenitic alloys in the Fe-Cr-Ni-Mo system in marine environments has been reviewed. The types of corrosion examined include intergranular corrosion, stress-corrosion cracking, corrosion fatigue, pitting, crevice corrosion, galvanic corrosion, cavitation damage, and erosion-corr…
The composite structural material comprising paper and wood is analysed in terms of thermal softening and hygroplasticization with regard to its constituent polymers. In particular, an attempt is made to relate the softening occurring under dry conditions to that occurring under moist conditions. It is proposed that t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSteric effects in metal cluster compoundsD. M. P. MingosCite this: Inorg. Chem. 1982, 21, 1, 464–466Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1 January 1982https://pubs.acs.org/doi/10.1021/ic00131a094https://doi.o…
The thermotropic liquid crystal mesophase formed by di-isobutylsilanediol has been known for over twenty-five years, but its nature and structure have remained uncertain and the physical characteristics of the phase appeared unique and quite different from those of any other recognised type of liquid crystal. In a pre…
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Research Article| July 01, 1982 Clay mineralogy of weathering rinds and possible implications concerning the sources of clay minerals in soils Steven M. Colman Steven M. Colman 1U.S. Geological Survey, Denver Federal Center, Denver, Colorado 80225 Search for other works by this author on: GSW Google Scholar Geology (1…
Published Online: 2009-01-01 Published in Print: 1982-01-01 © 2013 Walter de Gruyter GmbH, Berlin/Boston
The acidity developed by elemental sulphur when mixed with neutral water has been studied by measurements of the variaiion of pH with changes in the ratio of the solid sulphur to water and the effect of the presenece of metallic iron. The results obtained have been shown to extend the data reported at high temperature…
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Parallel screw dislocations performing cyclic slip are considered. Plastic resolved-shear-strain amplitudes γpl below a certain limit γpl,s can be accomplished by a static dislocation density, i.e. by the reversible to-and-fro motion of the screw dislocations. If γpl ≥ γpl,s, steady-state cyclic deformation requires t…
Combination rules for intermolecular potential parameters based on different approximations for the long-range dispersion energy are derived and applied to the Lennard-Jones (12–6) and Kihara potential functions. The resulting group of rules is given by the expressions σ12 = <σ≳j, and ε12 = <εσ6γ≳i/‖&…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRaman spectroscopic identification of the S4N- and S3- ions in blue solutions of sulfur in liquid ammoniaT. Chivers and C. LauCite this: Inorg. Chem. 1982, 21, 1, 453–455Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1…
Poly-beta-hydroxybutyrate has been identified in the cyanobacterium Spirulina platensis. The addition of reduced carbon compounds to the growth medium was not required for poly-beta-hydroxybutyrate accumulation. Poly-beta-hydroxybutyrate accumulated during exponential growth to 6% of the total dry weight and then decr…
Abstract The extent of phase separation in Nafion® perfluorosulfonate ionomer membranes has been studied by small‐angle neutron scattering (SANS). These polymers, which consist of a perfluorocarbon main chain and a sulfonate‐containing side group, can absorb up to 30% by weight of water. Previous studies have shown th…
Abstract A practical scheme for the calculation of excited states of the same symmetry as a given reference state is outlined in the context of the Hartree‐Fock method. In order to prevent the excited state from “collapsing” into a lower‐lying state, the prediagonalized Fock matrix is diagonalized in a restricted subs…
We describe a new flexoelectric volume effect in homogeneous electric field, in the nematic phase of MBBA. An initial splay-bend texture is created by strong antagonistic planar and homeotropic anchoring on two glass plates. This results in a volume flexoelectric polarization. A transverse DC electric field creates a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMixed-ligand complexes of trivalent lanthanide ions with .beta.-diketones and heterocyclic aminesK. Iftikhar, M. Sayeed, and N. AhmadCite this: Inorg. Chem. 1982, 21, 1, 80–84Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inis…
Basic principles of polymer science. Thermoplastics materials. Additives, blends and composites. Deformation behaviour of thermoplastics in relation to product design. Engineering interpretations of mechanical failures. Complementary engineering properties. Rheological behaviour of thermoplastics in relation to proces…
Hydrogen peroxide decomposition in 1–5 mol dm–3 KOH and 1–2 mol dm–3 NaOH solutions is a first-order reaction with respect to undissociated hydrogen peroxide. The decomposition is catalysed by compounds of heavy metals (Fe, Cu) present as trace impurities in these solutions and is first order with respect to them. The…