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Some Considerations About Bond Indices in Non-orthogonal Bases and the MO Calculation of Valence and Oxidation Number

Myriam Segre de Giambiagi、Mario Giambiagi、F.E. Jorge1984-12-01Zeitschrift für Naturforschung A

In order to guarantee the desired invariance properties of bond indices, we show the importance of expliciting the tensor character of the matrices concerned, so as to deal with a contraction in the tensor sense between a covariant index and a contravariant one. A straightforward definition of oxidation numbers is pro…

Inorganic and Organometallic ChemistryThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Alloy cluster beams: nickel/chromium and nickel/aluminum

Eric A. Rohlfing、D. M. Cox、R. Petkovic‐Luton 等 4 位作者1984-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlloy cluster beams: nickel/chromium and nickel/aluminumE. A. Rohlfing, D. M. Cox, R. Petkovic-Luton, and A. KaldorCite this: J. Phys. Chem. 1984, 88, 25, 6227–6231Publication Date (Print):December 1, 1984Publication History Published online1 May 2002Published inissue 1 Dece…

Aluminum Alloy Microstructure PropertiesQuasicrystal Structures and PropertiesNanoporous metals and alloys

Effects of Exchangeable Cation Composition on the Thermal Expansion/Contraction of Clinoptilolite

D. L. Bish1984-12-01Clays and Clay Minerals

Abstract To understand and predict the effects of a thermal pulse induced by a radioactive waste repository on clinoptilolite-bearing rocks, the lattice parameters of 6 natural and 3 cation-exchanged (Ca, K, Na) clinoptilolites were studied as a function of temperature. The samples were examined at room temperature, u…

Inorganic and Organometallic ChemistryCrystallization and Solubility StudiesThermal and Kinetic Analysis

Effect of Thiosulfate on Crevice Corrosion of Stainless Steels

Desmond Tromans、Laurel A Frederick1984-12-01CORROSION

Crevice corrosion studies were conducted on AISI 304, AISI 316L, and UHB 904L stainless steels using Teflon/metal crevices exposed to aqueous solutions of 1M NaCl and 1M NaCl + 0.01 M Na2S2O3. Tests were conducted at 22 C, except for some additional tests at 55 C on the more crevice resistant 904L. Crevice potentials…

Hydrogen embrittlement and corrosion behaviors in metals

Screening of hydrodynamic interactions in dense polymer solutions: a phenomenological theory and neutron-scattering investigations

Dieter Richter、Kurt Binder、B. Ewen 等 4 位作者1984-12-01The Journal of Physical Chemistry

We present a study on single-chain relaxation of linear polymers covering the full concentration range from dilute solution to the melt. Assuming incomplete screening of the hydrodynamic interaction between different segments of a chain, we introduce a phenomenological theory of chain dynamics in semidilute and concen…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

Proton NMR study of diffusion in continuous, nonstoichiometric metal-hydrogen systems:HfV2HxandZrV2Hx

J. Shinar、D. Davidov、D. Shaltiel1984-12-01Physical review. B, Condensed matter

The proton spin-relaxation times ${T}_{1}$ and ${T}_{2}$ in the continuous, nonstoichiometric, single-phase hydrides $\mathrm{Zr}{\mathrm{V}}_{2}{\mathrm{H}}_{x}$ and $\mathrm{Hf}{\mathrm{V}}_{2}{\mathrm{H}}_{x}$ ($0.25\ensuremath{\le}x\ensuremath{\le}4.2$) were measured in the temperature range $100 \mathrm{K}\ensure…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsNuclear Materials and Properties

Iron(III)-catalyzed oxygenation of catechols. Structure of (nitrilotriacetato)(3,5-di-tert-butylcatecholato)ferrate(III) dianion

Laura White、P. V. NILSSON、L. H. Pignolet 等 4 位作者1984-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIron(III)-catalyzed oxygenation of catechols. Structure of (nitrilotriacetato)(3,5-di-tert-butylcatecholato)ferrate(III) dianionL. S. White, P. V. Nilsson, L. H. Pignolet, and L. Que Jr.Cite this: J. Am. Chem. Soc. 1984, 106, 26, 8312–8313Publication Date (Print):December 1,…

Advanced oxidation water treatmentPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

The inelastic mean free path of electrons in some semiconductor compounds and metals

A. Jabłoński、P. Mrozek、György Gergely 等 5 位作者1984-12-01Surface and Interface Analysis

Abstract The elastic backscattering probability P e of electrons is proportional to the product of the inelastic mean free path (IMFP), effective backscattering cross section (σ eff ), and atomic density ( N ). Thus, experimental evaluation of P e , e.g. from the elastic peak intensity measurements, enables the determ…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Productive Lifespan of Bull Progeny Groups: Failure Time Analysis

Stephen Smith、R.L. Quaas1984-12-01Journal of Dairy Science

For genetic parameters herd lives of 587,013 Holstein cows recorded in Dairy Herd Improvement were analyzed by paternal half-sister analysis and Cox regression models. Length of life was duration in days between birth and failure or censoring. Failure was defined in two ways; first was death or sale for beef as determ…

Metallurgy and Material Science

A XANES investigation of the bonding of divalent lead in solids

K. J. Rao、Joe Wong1984-12-01The Journal of Chemical Physics

XANES (X-ray absorption near-edge structure) spectra of divalent lead compounds have been studied at both the Pb LIII and LI edges using synchrotron x rays from CHESS (Cornell High Energy Synchrotron Source). The combined LIII and LI near-edge spectral features strongly support a sp3d2 hybridization scheme in covalent…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsX-ray Spectroscopy and Fluorescence Analysis

An experimental study of hypervalent molecular clusters by neutralized ion beam spectroscopy: ammonium-ammonia (NH4(NH3)n) and deuterated ammonium-ammonia (ND4(ND3)n)

Gregory I. Gellene、Richard F. Porter1984-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn experimental study of hypervalent molecular clusters by neutralized ion beam spectroscopy: ammonium-ammonia (NH4(NH3)n) and deuterated ammonium-ammonia (ND4(ND3)n)Gregory I. Gellene and Richard F. PorterCite this: J. Phys. Chem. 1984, 88, 26, 6680–6684Publication Date (Pr…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceInorganic Fluorides and Related Compounds

Time-resolved light scattering studies on the kinetics of phase separation and phase dissolution of polymer blends. 2. Phase separation of ternary mixtures of polymer A, polymer B, and solvent

Takeji Hashimoto、Kouji Sasaki、Hiromichi Kawai1984-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTime-resolved light scattering studies on the kinetics of phase separation and phase dissolution of polymer blends. 2. Phase separation of ternary mixtures of polymer A, polymer B, and solventTakeji Hashimoto, Kouji Sasaki, and Hiromichi KawaiCite this: Macromolecules 1984,…

Polymer crystallization and propertiesPolymer Nanocomposites and Properties

Temperature dependence of neutron scattering behavior and resultant thermodynamics of mixing of poly(2,6-dimethyl-1,4-phenylene oxide) in polystyrene

Ann Maconnachie、R. P. Kambour、Dwain M. White 等 5 位作者1984-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemperature dependence of neutron scattering behavior and resultant thermodynamics of mixing of poly(2,6-dimethyl-1,4-phenylene oxide) in polystyreneAnn Maconnachie, Roger P. Kambour, Dwain M. White, Shamsedin Rostami, and David J. WalshCite this: Macromolecules 1984, 17, 12…

Polymer crystallization and propertiesConducting polymers and applicationsElectrochemical Analysis and Applications

Cenozoic Diatom Biostratigraphy and Paleoceanography of the Rockall Plateau Region, North Atlantic, Deep Sea Drilling Project Leg 81

Jack G. Baldauf1984-12-01U.S. Government Printing Office eBooks

Diatoms are present within the Eocene to Holocene sediments recovered during Deep Sea Drilling Project (DSDP) Leg 81. A late Cenozoic, North Atlantic diatom zonation is developed as a result of the occurrence of common wellpreserved diatoms within middle Miocene to Holocene sediments. This high-latitude diatom zonatio…

Geology and Paleoclimatology ResearchPaleontology and Stratigraphy of FossilsDiatoms and Algae Research

Nickel phthalocyanine iodide: A highly-one-dimensional low-temperature molecular metal

Jens Martinsen、Sharon M. Palmer、Jirō Tanaka 等 5 位作者1984-12-01Physical review. B, Condensed matter

The conductivity of the linear-chain molecular-metal phthalocyanatonickel(II)iodide [Ni(pc)I] remains metallic down to \ensuremath{\sim}30 K, goes through a weak maximum, and then levels off to a high asymptotic ($T\ensuremath{\rightarrow}0$) value that varies from \textonehalf{} to 2 times the value at room temperatu…

Magnetism in coordination complexesAdvanced Condensed Matter PhysicsOrganic and Molecular Conductors Research

DEVELOPMENTALLY REGULATED GENES IN SILKMOTHS

Marian R. Goldsmith、Fotis C. Kafatos1984-12-01Annual Review of Genetics

We have made rapid progress in recent years in identifying the genetic causes of many human diseases. However, despite this recent progress, our mechanistic understanding of these diseases is often incomplete. This is a problem because it limits our ...Read More

Silk-based biomaterials and applicationsStudies on Chitinases and ChitosanasesSilkworms and Sericulture Research

Geometrical models of interface evolution. II. Numerical simulation

David A. Kessler、Joel Koplik、Herbert Levine1984-12-01Physical Review A

We continue our study of local interface models for dendritic growth by presenting detailed numerical simulations of the evolution of snowflake patterns. The local model we employ is quantitatively valid for early stages of the dendritic growth process and is qualitatively similar to the true diffusion-controlled dyna…

Solidification and crystal growth phenomenaNonlinear Dynamics and Pattern FormationFluid Dynamics and Thin Films

The Role of Surface Dislocations in the Continuum Theory of Lattice Defects

M. J. Marcinkowski1984-12-01physica status solidi (b)

Abstract The close relationship between the concept of surface dislocations and the continuum theory of lattice defects is clearly demonstrated. In fact, it is shown that without the incorporation of surface dislocations into the classical continuum theories, it is not possible to obtain a complete and self‐consistent…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesHigh-Velocity Impact and Material Behavior

The Thermoelectric Power of p‐Ge at Low Temperatures

E. Kaden、H.‐L. Günter1984-12-01physica status solidi (b)

Abstract The thermoelectric power of lightly doped p‐Ge is measured in the temperature range of 5 to 300 K for the investigation of phonon scattering. The application of a simple theoretical model requires some knowledge of the dominant carrier scattering processes obtained by measurements of electrical conductivity a…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaThermal properties of materials

OBSERVATIONS ON THE MICROSTRUCTURE AND MAGNETIZATION OF ALNICO PERMANENT MAGNETS

M.G. Hetherington、A. Cerezo、J. P. Jakubovics 等 4 位作者1984-12-01Le Journal de Physique Colloques

Alnico5 and 7 specimens have been studied by field ion microscopy, atom probe microanalysis and high voltage electron microscopy. The composition and morphology of the phases was accurately determined. From the results, it was shown that magnetization changes occurred by Bloch wall motion.

Metallurgical and Alloy Processes