Materials Literature
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Different reaction temperatures have allowed the isolation of 1 : 1 and 1 : 2 adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine. Thermal, vibrational, and magnetic-susceptibility analyses have provided useful information about the structural properties of these complexes; e.s.r. and electronic s…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelenium dioxide oxidation of d-limonene. ReinvestigationHarbo P. Jensen and K. Barry SharplessCite this: J. Org. Chem. 1975, 40, 2, 264–265Publication Date (Print):January 1, 1975Publication History Published online1 May 2002Published inissue 1 January 1975https://doi.org/1…
Abstract The shape of the continuous spectrum between 0.5 and 10 keV generated by 10 to 25 keV electrons has been calculated. It is shown that Kramers' law underestimates the intensity generated at low X‐ray energies. However, this is partially compensated by the greater absorption suffered by continuum X‐rays compare…
The skin interfacing potential of various velours, felts, foams and rough cast surfaces of some polymers was investigated by bonding these substances to solid core silastic rods using Dow-Corning Medical Adhesive Type A. These dummy cannulae were implanted as skin penetrating rods onto the dorsum of canines, goats, an…
A new effective pair potential is proposed. This potential is based on the thermodynamic properties of alkali metal halides in the crystal phase and takes into account the pressure dependence of the compressibility. The form of the new potential is; ϕ(rij)=+ [graphic omitted] + [graphic omitted] exp[–k(rmij–rm0ij)]– […
Tests of 0–90° ply fiberglass roving-epoxy plates, impacted by hard steel cylindrical penetrators, have revealed a sequential delamination mechanism, especially well developed in plates having more than one layer of fibers in each unidirectionally reinforced lamina. In these plates the sequential delamination mechanis…
In order to clarify the effect of heat treatment on the martensitic transformation in the TiNi compound, the electrical resistivity vs temperature curves of TiNi containing hyper-stoichiometric concentration of nickel which were heat-treated under various conditions were obtained. TiNi containing more than 51 at%Ni sh…
Dislocation density, ρ, during steady-state creep of A1–5.54 at.-%Mg alloy was measured as a function of applied stress (oc= 14.7–68.6N/mm2) and of test temperature (T=573–673 K). Effect of the concentration of magnesium (C=0.52–5.54 at.-%) on ρ, was also studied at 573 K. From the present results together with the da…
The T'' phase in the system AI-Cu-Zn has been investigated using electron diffraction, X-ray diffraction, and electronprobe microanalysis. It is established that T'' has a rhombohedral structurewith a==8''676 ÅA and α==27.41∘°. This structure is a superlattice based on an assembly of five small CsCI-type cells, joined…
Spin susceptibility measurements in crystalline alkali+ TCNQ− salts reveal the occurrence of continuous changes and first-order phase transitions in these salts, except Li+TCNQ−. A consideration of the total free energy of these distorted linear systems, in which the electronic energy results from an elementary one-di…
The zero field splitting (zfs) for porphyrin is calculated for possible transitions b2u(π), a1u(π), a2u(π) → eg(π*). Calculations are done with pi−electron orbital coefficients determined from extended Hückel calculations on the deprotonated dianion, the free base, and the acid dication. The spin dipole−dipole couplin…
The fracture modes, metallurgical and environmental influences, and suggested mechanisms of aqueous stress corrosion cracking in titanium alloys are reviewed. Many observations can be rationalised, but the task of assembling a complete quantitative model is formidable.
Molecular dynamics calculations are reported for liquid sodium chloride simulated by Born–Huggins–Mayer type pair potentials. Thermodynamic properties and self diffusion constants have been obtained for 22 VT points ranging between 1000 and 2000 K and between –1 and 14 kbars. The agreement with experimental data is, o…
Optical techniques for data storage have advanced rapidly during the last decade. Optical data storage presents many unique advantages, notably the high storage density and low access time, not attainable by conventional recording techniques. The special features of optical recording, the proposed materials and techni…
Abstract Several novel polyamides containing the N , N ′‐dialkyl‐4,4′‐dipyridinium (“viologen”) system were made by interfacial condensation of N , N ′‐bis(aminoalkyl)‐4,4,‐dipyridinium salts with di‐, tri‐, or tetrafunctional acid chlorides. These materials are useful redox polymers which turn deeply colored when red…
Pressure against composition isotherms, and changes in the relative electrical resistance with hydrogen content, have been determined over the temperature range 303–373 K, for the absorption of hydrogen by palladium alloys containing 5, 10, 15 and 20 atom % copper. For each alloy, the relative resistance increases con…
Published treatments of peel mechanics are shown to yield inconsistent relations for the dependence of peel force upon the angle of peel. The paradox is resolved by limiting the stress analyses to small bending deformations of the detaching strip in the still-attached region. This condition holds when the moment arm o…
Pd–SnO2 catalysts are more active for CO oxidation than either Pd–SiO2 or SnO2, but are relatively inactive for C2H4 hydrogenation; grinding of Pd–SiO2 and SnO2 mixtures enhances CO oxidation activity, indicating that Pd induces activity on the SnO2 surface.
On analyse les déclins de luminescence, à toutes températures comprises entre 4 et 500 K, des centres Bi3+ incorporés dans les oxydes de terres rares La2O3 et Y2O3, les métaantimoniates CaSb 2O6 et SrSb2O6 avec et sans compensation de charge, et dans l'antimoniate de terre rare Y2LuSbO7. En utilisant de plus les résul…
A matrix variational calculation has been done for electron scattering by atomic O, which includes $2{s}^{2}2{p}^{4}$, $2s2{p}^{5}$, and $2{p}^{6}$ target configurations and all possible single excitations of the $2p$ orbital. Integral and differential cross sections are reported for elastic and inelastic scattering f…