Semiconducting Properties of Cubic Boron Phosphide
Received 15 February 1960DOI:https://doi.org/10.1103/PhysRevLett.4.282©1960 American Physical Society
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Mechanism for the Sidewise Motion of 180° Domain Walls in Barium Titanate
An important unanswered question concerning the sidewise motion of 180\ifmmode^\circ\else\textdegree\fi{} domain walls in single crystal BaTi${\mathrm{O}}_{3}$ is the mechanism by which the boundaries move. This paper considers two possible models. One model assumes that the wall motion results from the repeated nucle…
Corrosion and Weldability Studies On Chromium-Manganese Austenitic Stainless Steels
Corrosion and weldability studies have been made on Cr-Mn-Ni and Cr-Mn-N grades of austenitic stainless steel to determine their usefulness for chemical plant applications. These studies show that the corrosion resistance of Type 202 (18% Cr-5% Ni-8% Mn-0.10% max. C) stainless steel is comparable to that of Type 304 s…
9—THE TEARING STRENGTH OF FABRICS: I. A REVIEW OF THE LITERATURE
A comprehensive survey of the literature on the tearing strength of fabrics is presented. The various test methods employed for determining tearing strength, the machines and instruments used in making these tests, and the different expressions for tearing strength are discussed. The elfccts of the type of fibre, clot…
Direct electron microscopy of thin foils of internally oxidized dilute copper alloys
(1960). Direct electron microscopy of thin foils of internally oxidized dilute copper alloys. The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics: Vol. 5, No. 51, pp. 298-301.
Infrared spectra of crystalline polysaccharides. IV. The use of inclined incidence in the study of oriented films
Abstract The infrared spectra (tilting spectra) obtained with the incident beam inclined to oriented films are discussed. Various experimental settings for obtaining the tilting spectra are studied. It is pointed out that quantitative interpretations (to determine the direction of the transition moment of a normal mod…
Studies on Lead Titanate Ceramics Containing Niobium or Tantalum
Dielectric, lattice constant, and thermal‐expansion measurements have been made on solid solution ceramics in the systems PbTiO 3 Pb 0.5 NbO 3 and PbTiO 3 ‐Pb o.5 TaO 3 . The ferro‐electric Curie temperature is lowered to 465OC. at the solubility limit (2 to 5% Nb or Ta). Replacement of Ti 4+ by Nb 5+ or Ta 5+ in thes…
Polymerization of α‐piperidone by alkali metal and certain acyl compounds
Abstract It has been shown that the resonance‐stabilized, six‐membered lactam, α‐piperidone, is polymerized by alkali metal and acyl compounds to form poly‐5‐valeramide, melting point 259°C., [ r ] = 0.25, d = 1.243. A mechanism is proposed for the polymerization of α‐piperidone with alkali metal and acyl compound whi…
Infrared Properties of Gold in Germanium
The fundamental parameters of gold in germanium have been investigated between 60-300\ifmmode^\circ\else\textdegree\fi{}K by absorption, photoconductivity, and lifetime studies.Photoconductivity measurements reveal the following capture cross sections for electrons and holes at 80\ifmmode^\circ\else\textdegree\fi{}K (…
Stability of Dicalcium Phosphate Dihydrate in Aqueous Solutions and Solubility of Octocalcium Phosphate
Abstract The hydrolysis of dicalcium phosphate dihydrate, CaHPO 4 ·2H 2 O, in dilute phosphoric acid solutions and in water was investigated at 25° C. in the absence of CO 2 . Octocalcium phosphate, Ca 4 H(PO 4 ) 3 ·3H 2 O, was found to precipitate when the pH of the solution was higher than 6.38. The extent of the hy…
Dimorphecolic Acid—A Unique Hydroxydienoid Fatty Acid2
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDimorphecolic Acid—A Unique Hydroxydienoid Fatty Acid2C. R. Smith Jr., T. L. Wilson, E. H. Melvin, and I. A. WolffCite this: J. Am. Chem. Soc. 1960, 82, 6, 1417–1421Publication Date (Print):March 1, 1960Publication History Published online1 May 2002Published inissue 1 March…
The interaction between styrene-butadiene rubber and carbon black on heating
The interaction between a carbon black filler and styrene-butadiene rubber is increased if the material is heated after milling. This effect has been attributed to the polymeric free radicals which are presented after milling but which require a high temperature to increase their mobility to the point where they can r…
The Melting Temperature of Natural Rubber Networks
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Melting Temperature of Natural Rubber NetworksD. E. Roberts and L. MandelkernCite this: J. Am. Chem. Soc. 1960, 82, 5, 1091–1095Publication Date (Print):March 1, 1960Publication History Published online1 May 2002Published inissue 1 March 1960https://pubs.acs.org/doi/10.1…
The Solubilities and Heats of Solution of Disperse Dyes in Water
The aqueous solubilities of 16 carefully purified disperse dyes have been measured over the temperature range 60–90°C. From these results, the heats of solution in water have been found to lie mainly in the range 10–20 kcal./mole. It is suggested that the higher heats of solution are associated with the presence of hy…
The electrical resistivity of stacking faults
The scattering of electrons and x-rays by stacking faults is due to a phase change in the diffraction by crystal planes which do not lie parallel to the fault. A simple model of the process in copper estimates a resistivity p≃1 × 10−12 β ohm-cm for a total stacking fault density of β cm−1 on all planes. A wave matchin…
The crystal structures of BaZnO2, BaCoO2and BaMnO2
Earth-alkali oxides and bivalent transition-metal oxides will form compounds ABO 2 when the earth-alkali ion is large and the transition-metal ion is small.
Phenylene sulfide polymers. II. Structure of polymers obtained by the Macallum polymerization
Abstract Polymers prepared by the Macallum homopolymerization and copolymerization were compared to a linear phenylene sulfide polymer prepared by the self‐condensation of sodium p ‐chlorothiophenoxide. The properties compared included solubility, softening point, melting point, x‐ray diffraction pattern, infrared spe…
The crystallography of deformation twinning
The crystallography of deformation twinning is formulated on a fresh mathematical basis. This leads to a simplified technique for calculating the reciprocal elements corresponding to a given pair of rational twinning elements. It is shown how the scale of homogeneity of the deformation may be deduced from macroscopica…
High-Energy Sputtering
Sputtering ratios for copper have been determined in the energy ranges 5–40 kev for bombardment by Ar+, He+, and D+. Argon values range from 6.48 at 5 kev to 9.25 at 27.5 kev, deuterium from 0.048 at 10 kev to 0.023 at 44 kev, and helium from 0.23 at 15 kev to 0.75 at 40 kev. Preliminary data are included for 30-kev s…
The Movement of Thallium Ions in Muscle
Measurements have been made of the fluxes of thallous ions (Tl(+)) across the membrane of frog sartorius muscle fibers. These show that at an external concentration of 74 microM the influx is about 270 x 10(-15) moles/cm.(2) sec., while the efflux from a muscle with an internal concentration equal to the above is 5 x…