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Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+

W. T. Carnall、P. R. Fields、K. Rajnak1968-11-15OpenAlex

The free-ion energy-level schemes of the Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+ aquo ions have been determined from their absorption spectra in dilute acid solution at 25°. Energy-level assignments were made by comparison with crystal spectra, and on the basis of correlations between calculated and observe…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Band-Gap Effects in the Stopping ofGe72*Atoms in Germanium

C. Chasman、K. W. Jones、H.W. Kraner 等 4 位作者1968-11-11Physical Review Letters

Measurements of the ionization losses of 10.0- to 30-keV ${\mathrm{Ge}}^{72*}$ atoms in germanium show no evidence for a cutoff for particle energies less than 23 keV, as might be expected from adiabatic arguments concerning the effect of an energy gap in germanium. The ionization loss is consistent with Lindhard's co…

Advanced Semiconductor Detectors and MaterialsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Reversible Electrical Switching Phenomena in Disordered Structures

Stanford R. Ovshinsky1968-11-11OpenAlex

A rapid and reversible transition between a highly resistive and conductive state effected by an electric field, which we have observed in various types of disordered semiconducting material, is described in detail. The switching parameters and chemical composition of a typical material are presented, and microscopic…

High-pressure geophysics and materialsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Magnetic and Crystallographic Transitions in theα−Mn2O3−Fe2O3System

R. W. Grant、S. Geller、J. A. Cape 等 4 位作者1968-11-10Physical Review

X-ray diffraction, M\"ossbauer spectroscopic, and magnetic susceptibility measurements have led to a determination of the phase diagram including magnetic phases of the system ${({\mathrm{Mn}}_{1\ensuremath{-}x}{\mathrm{Fe}}_{x})}_{2}{\mathrm{O}}_{3}$, $0\ensuremath{\le}x\ensuremath{\le}0.63$, the limit of ${\mathrm{F…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

4fn→4fn−15dSpectra of Rare-Earth Ions in Crystals

Eugene Loh1968-11-10Physical Review

The $4{f}^{n}\ensuremath{\rightarrow}4{f}^{n\ensuremath{-}1}5d$ absorption spectra of rare-earth ions, R${\mathrm{E}}^{2+}$ or R${\mathrm{E}}^{3+}$, in crystals can be fitted with energy gaps in the ground multiplets of the $4{f}^{n\ensuremath{-}1}$ core. Unlike the shielded $4{f}^{n}$ configuration, the $4{f}^{n\ensu…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesQuantum optics and atomic interactions

Radiance Lifetimes in the Resonance Series of Ar I.

G. M. Lawrence1968-11-05Physical Review

Radiative lifetimes of the six lowest-energy $J=1$ levels of Ar I have been measured using a pulsed electron technique. The wavelengths and measured lifetimes in nanoseconds are 1066.66, 8.60 \ifmmode\pm\else\textpm\fi{} 0.4; 1048.22, 2.15 \ifmmode\pm\else\textpm\fi{} 0.2; 879.95, 10.1 \ifmmode\pm\else\textpm\fi{} 0.4…

Atomic and Molecular PhysicsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Characterization of phases in the 50–60 at. % Te region of the Bi–Te system by X-ray powder diffraction patterns

R. F. Brebrick1968-11-02Journal of Applied Crystallography

Samples in the Bi–Te system containing 59.0, 58.0, 57.0, 55.0, 51.0, and 50.0 at.% Te, in addition to 5 samples within the Bi2Te3 homogeneity range, have been equilibrated near 525 or 450°C and room temperature powder diffraction patterns taken. There are now 4 known phases in the 50–60 at.% Te region. The 59.0 and 58…

High-pressure geophysics and materialsRare-earth and actinide compoundsX-ray Diffraction in Crystallography

Effect of Transverse Curvature on Skin Friction and Heat Transfer in Laminar Flows Past Slender Circular Cylinders

Tuncer Cebeci、E. R. Wogulis、R. D. Partin1968-11-01ASME Journal of Heat and Mass Transfer

Technical Briefs Effect of Transverse Curvature on Skin Friction and Heat Transfer in Laminar Flows Past Slender Circular Cylinders T. Cebeci, T. Cebeci Mechanical Engineering Department, California State College at Long Beach, Long Beach, Calif; Aerodynamics Research Group, McDonnell Douglas Corporation, Douglas Airc…

Textile materials and evaluationsHeat Transfer MechanismsSports Dynamics and Biomechanics

The relation between the spherical aberration and distortion coefficients of electron probe-forming and projector lenses

Peter Hawkes1968-11-01Journal of Physics D Applied Physics

The asymptotic spherical aberration and distortion coefficients of electron lenses always depend upon the position of the object, or the magnification, in a very simple way, and furthermore the quantities that specify the distortion are closely related to those giving the spherical aberration. These relationships are…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

The Photolysis of Polyvinylpyrrolidone in Aqueous Solutions in the Presence of Oxygen and Cupric Ions

H. H. G. Jellinek、L. C. Wang1968-11-01Journal of Macromolecular Science Part A - Chemistry

The oxidative photolysis of polyvinylpyrrolidone with light of λ = 2537 Å has been studied over a range of oxygen pressures and polymer concentrations. The results show that chain scission and cross linking take place simultaneously. In the range where cross linking is a negligible component, a mechanism based on chai…

Polymer Science and PVC

Saturation and exposure dependence of the yield stress of irradiated iron

S. B. McRickard1968-11-01Philosophical magazine

The yield stress data of irradiated Ferrovac iron are shown to be closely approximated by the expression Δ[sgrave]=A[1—exp (—Bφt)]1/2 with a saturation exposure of 2 × 1019 nvt (E > 1·45 MeV). The maximum increment in the yield stress is 25 000 p.s.i. and the volume of the defect calculated from B is 4·4 × 10−19 cm3.…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesWelding Techniques and Residual Stresses

Effect of the Phase Term in the Mutual Coherence Function on Aperture-Diffraction Patterns

Robert A. Shore1968-11-01Journal of the Optical Society of America

A method is presented for obtaining the far-field diffraction pattern of a plane aperture when the mutual coherence function of the illumination contains a quadratic phase term. The method is applied to obtain the diffraction pattern of a slit and circular aperture illuminated by an extended quasimonochromatic incoher…

Optical measurement and interference techniquesOptical Coatings and GratingsOptical Polarization and Ellipsometry

Molybdovanadophosphoric acids and their salts. II. Investigation of solution properties

Calvin J. Hallada、George A. Tsigdinos、Bruce S. Hudson1968-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdovanadophosphoric acids and their salts. II. Investigation of solution propertiesCalvin J. Hallada, George A. Tsigdinos, and B. S. HudsonCite this: J. Phys. Chem. 1968, 72, 12, 4304–4307Publication Date (Print):November 1, 1968Publication History Published online1 May…

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Novel bridged anthracene derivatives and polyesters and copolyesters therefrom

B. H. Klanderman、J. W. H. Faber1968-11-01Journal of Polymer Science Part A-1 Polymer Chemistry

Abstract 9,10‐Bis(hydroxymethyl)triptycene, 9,10‐dihydro‐9,10‐bis(hydroxymethyl)‐9,10‐ethanoanthracene, 9,10‐dihydro‐9,10‐bis(hydroxymethyl)‐9,10‐(2,3‐bicyclo[2.2.1] heptano)‐anthracene, 9,10‐dihydro‐9,10‐bis(hydroxymethyl)‐ N ‐phenyl‐9,10‐ethanoanthracene‐11,12‐dicarboximide, and 9,10‐bis(carbethoxy)triptycene have b…

Polymer crystallization and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Hysteresis in Polymers and its Relation to Strength

K. A. Grosch、J. A. C. Harwood、A. R. Payne1968-11-01Rubber Chemistry and Technology

Abstract Energy density to break measurements on a number of polymers, either partly swollen or dry, reveal that there is a simple relationship between the energy density to break and the hysteresis obtained in the first stress strain cycle taken very near to break. The hysteresis at break was varied by changing the t…

Mechanical Behavior of CompositesPolymer crystallization and propertiesMaterial Properties and Processing

The Establishment and Growth of Zinc Oxide on 74: 26 Brass

D. P. Whittle、G. C. Wood1968-11-01British Corrosion Journal

The early stages of growth of oxide films on a Cu–26 wt.-% Zn alloy and their later development into thick scales have been studied by metallography and electron probe microanalysis. Thick scales have been examined conventionally in cross-section whereas thin films, about 1000–5000 Å thick, have been examined in plan.…

ZnO doping and propertiesCorrosion Behavior and InhibitionCopper Interconnects and Reliability

Lanthanide picolinate chelate stabilities

J.E. Powell、J. W. Ingemanson1968-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLanthanide picolinate chelate stabilitiesJ. E. Powell and J. W. IngemansonCite this: Inorg. Chem. 1968, 7, 11, 2459–2461Publication Date (Print):November 1, 1968Publication History Published online1 May 2002Published inissue 1 November 1968https://pubs.acs.org/doi/10.1021/ic…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

The Oxidation of UC and UN Powder in Air

Toshihiko Ohmichi、Toshio Honda1968-11-01Journal of Nuclear Science and Technology

(1968). The Oxidation of UC and UN Powder in Air. Journal of Nuclear Science and Technology: Vol. 5, No. 11, pp. 600-602.

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

39—THE DETERMINATION OF THE LATERAL-COMPRESSION MODULUS OF FIBRES

Scott A. Morris1968-11-01Journal of the Textile Institute

An account is given of the measurement of the transverse deformation of fibres under various loads acting normal to the fibre longitudinal axis by a technique in which fibres are interleaved between glass plates in a vertical stack. Graphs of transverse load against compression are plotted for nylon, acrylic, and visc…

Textile materials and evaluationsFiber-reinforced polymer compositesMaterial Properties and Processing

Thickness Estimation of Carbon Films by Electron Microscopy of Transverse Sections and Optical Density Measurements

R. C. Moretz、H. M. Johnson、D. F. Parsons1968-11-01Journal of Applied Physics

A rapid and convenient method is described for the accurate determination of the thickness of carbon films from their optical density. A linear relationship was found between optical density and film thickness. The optical-density-thickness curve was calibrated by direct measurement of the thickness of transverse sect…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions